Synthesis of Mixed Alcohols from CO Hydrogenation over Iron and Nickel Metal Phosphide Catalysts

doi:10.1016/S1872-2067(11)60460-9

Abstract

Abstract: A series of silica supported iron and nickel metal phosphides with different molar ratios of P to metal were synthesized by the temperature programmed reduction method. Their catalytic performance for CO hydrogenation in a fixed bed reactor was tested with the conditions of 553 K, 5.0 MPa, and H₂:CO = 2 (molar ratio). With the FeP_x/SiO₂catalysts (x denotes the molar ratio of P to metal), the product was a mixture of oxygenates containing methanol as the major component. With the NiP_x/SiO₂ samples, the liquid product was mainly methanol. The Fe₂P, Fe₃P, Ni, Ni₂P, Ni₃P, and Ni₁₂P₅ phases were stable during CO hydrogenation, while most of the metallic Fe phase transformed into iron carbide.

Key words: carbon monoxide hydrogenation, oxygenates, metal phosphides, silica, iron phosphide, nickel phosphide

SONG Xian-Gen, DING Yun-Jie, CHEN Wei-Miao, DONG Wen-Da, PEI Yan-Peng, ZANG Juan, YAN Li, Lü Yuan. Synthesis of Mixed Alcohols from CO Hydrogenation over Iron and Nickel Metal Phosphide Catalysts[J]. Chinese Journal of Catalysis, 2012, 33(12): 1938-1944.

×
share this article

Add to citation manager EndNote|Ris|BibTeX

URL: https://www.cjcatal.com/EN/10.1016/S1872-2067(11)60460-9

https://www.cjcatal.com/EN/Y2012/V33/I12/1938

References

1 Subramani V, Gangwal S K. Energy Fuels, 2008, 22: 814
2 Burch R, Hayes M J. J Catal, 1997, 165: 249
3 Yin H M, Ding Y J, Luo H Y, Yan L, Wang T, Lin L W. En-ergy Fuels, 2003, 17: 1401
4 Haider M A, Gogate M R, Davis R J. J Catal, 2009, 261: 9
5 Tien-Thao N, Zahedi-Niaki M H, Alamdari H, Kaliaguine S. Appl Catal A, 2007, 326: 152
6 Chu W, Kieffer R, Kiennemann A, Hindermann J P. Appl Catal A, 1995, 121: 95
7 Tien-Thao N, Zahedi-Niaki M H, Alamdari H, Kaliaguine S. J Catal, 2007, 245: 348
8 Jiao G, Ding Y, Zhu H, Li X, Li J, Lin R, Dong W, Gong L, Pei Y, Lu Y. Appl Catal A, 2009, 364: 137
9 Fang Y Z, Liu Y, Zhang L H. Appl Catal A, 2011, 397: 183
10 Wu X M, Guo Y Y, Zhou J M, Lin G D, Dong X, Zhang H B. Appl Catal A, 2008, 340: 87
11 Zhao L H, Fang K G, Jiang D, Li D B, Sun Y H. Catal Today, 2010, 158: 490
12 Surisetty V R, Dalai A K, Kozinski J. Appl Catal A, 2010, 381: 282
13 Oyama S T. J Catal, 2003, 216: 343
14 Zuzaniuk V, Prins R. J Catal, 2003, 219: 85
15 Sawhill S J, Layman K A, Vanwyk D R, Engelhard M H, Wang C M, Bussell M E. J Catal, 2005, 231: 300
16 Burns A W, Gaudette A F, Bussell M E. J Catal, 2008, 260: 262
17 Li K, Wang R, Chen J X. Energy Fuels, 2011, 25: 854
18 黄金花, 陈吉祥. 催化学报 (Huang J H, Chen J X. Chin J Catal), 2012, 33: 790
19 Zaman S, Smith K. Catal Commun, 2009, 10: 468
20 Zaman S F, Smith K J. Appl Catal A, 2010, 378: 59
21 Zaman S F, Smith K J. Catal Today, 2011, 171: 266
22 Hayashi H, Chen L Z, Tago T, Kishida M, Wakabayashi K. Appl Catal A, 2002, 231: 81
23 Zhang H J, Ma H F, Zhang H T, Ying W Y, Fang D Y. Catal Lett, 2012, 142: 131
24 Nagaraju P, Srilakshmi C, Pasha N, Lingaiah N, Suryanarayana I, Prasad P S S. Appl Catal A, 2008, 334: 10
25 Nagaraju P, Lingaiah N, Balaraju A, Prasad P S S. Appl Catal A, 2008, 339: 99
26 Oyama S T, Wang X, Lee Y K, Bando K, Requejo F G. J Catal, 2002, 210: 207
27 Rodriguez J A, Hanson J C, Frenkel A I, Kim J Y, Perez M. J Am Chem Soc, 2002, 124: 346
28 Liu X G, Chen J X, Zhang J Y. Catal Commun, 2007, 8: 1905
29 Chen J X, Chen Y, Yang Q, Li K L, Yao C C. Catal Commun, 2010, 11: 571
30 OBrien R J, Xu L G, Spicer R L, Davis B H. Energy Fuels, 1996, 10: 921
31 Cheng J, Hu P, Ellis P, French S, Kelly G, Lok C M. J Phys Chem C, 2010, 114: 1085
32 Ojeda M, Rojas S, Garcia-Garcia F J, Granados M L, Terreros P, Fierro J L G. Catal Commun, 2004, 5: 703
33 Jablonski J M, Potoczna-Petru D, Okal J, Krajczyk L. React Kinet Catal Lett, 1995, 54: 15
34 Schoubye P. J Catal, 1969, 14: 238

[1]	Duozheng Ma, Xiangcheng Li, Chuang Liu, Caroline Versluis, Yingchun Ye, Zhendong Wang, Eelco T. C. Vogt, Bert M. Weckhuysen, Weimin Yang. SCM-36 zeolite nanosheets applied in the production of renewable p-xylene from ethylene and 2,5-dimethylfuran [J]. Chinese Journal of Catalysis, 2023, 47(4): 200-213.
[2]	Wenhao Cui, Dali Zhu, Juan Tan, Nan Chen, Dong Fan, Juan Wang, Jingfeng Han, Linying Wang, Peng Tian, Zhongmin Liu. Synthesis of mesoporous high-silica zeolite Y and their catalytic cracking performance [J]. Chinese Journal of Catalysis, 2022, 43(7): 1945-1954.
[3]	Bo Zhou, Mengyu Li, Yingying Li, Yanbo Liu, Yuxuan Lu, Wei Li, Yujie Wu, Jia Huo, Yanyong Wang, Li Tao, Shuangyin Wang. Cobalt-regulation-induced dual active sites in Ni₂P for hydrazine electrooxidation [J]. Chinese Journal of Catalysis, 2022, 43(4): 1131-1138.
[4]	Jinpeng Yin, Xin Jin, Hao Xu, Yejun Guan, Rusi Peng, Li Chen, Jingang Jiang, Peng Wu. Structured binder-free MWW-type titanosilicate with Si-rich shell for selective and durable propylene epoxidation [J]. Chinese Journal of Catalysis, 2021, 42(9): 1561-1575.
[5]	Huimin Luan, Chi Lei, Ye Ma, Qinming Wu, Longfeng Zhu, Hao Xu, Shichao Han, Qiuyan Zhu, Xiaolong Liu, Xiangju Meng, Feng-Shou Xiao. Alcohol-assisted synthesis of high-silica zeolites in the absence of organic structure-directing agents [J]. Chinese Journal of Catalysis, 2021, 42(4): 563-570.
[6]	Jinghua Xu, Ruifeng Wang, Yaru Zhang, Lin Li, Wenjun Yan, Junying Wang, Guodong Liu, Xiong Su, Yanqiang Huang, Tao Zhang. Identification of the structure of Ni active sites for ethylene oligomerization on an amorphous silica-alumina supported nickel catalyst [J]. Chinese Journal of Catalysis, 2021, 42(12): 2181-2188.
[7]	Wenli Yu, Yuxiao Gao, Zhi Chen, Ying Zhao, Zexing Wu, Lei Wang. Strategies on improving the electrocatalytic hydrogen evolution performances of metal phosphides [J]. Chinese Journal of Catalysis, 2021, 42(11): 1876-1902.
[8]	Chengbin Li, He Li, Chunzhi Li, Xiaomin Ren, Qihua Yang. One-pot synthesis of mesosilica/nano covalent organic polymer composites and their synergistic effect in photocatalysis [J]. Chinese Journal of Catalysis, 2021, 42(10): 1821-1830.
[9]	Hao Xu, Wenwen Tian, Liping Xu, Xin Jin, Teng Xue, Li Chen, Mingyuan He, Peng Wu. Crossed intergrowth triggered TS-2 microsphere: Formation mechanism, modification and catalytic performance [J]. Chinese Journal of Catalysis, 2020, 41(7): 1109-1117.
[10]	Zengtian Chen, Yuxue Xiao, Chao Zhang, Zaihui Fu, Ting Huang, Qingfeng Li, Yuanxiong Yao, Shutao Xu, Xiaoli Pan, Wenhao Luo, Changzhi Li. Fabrication of a solid superacid with temperature-regulated silica-isolated biochar nanosheets [J]. Chinese Journal of Catalysis, 2020, 41(4): 698-709.
[11]	XU Hao, WU Peng. Recent Progress of Metallosilicate Catalysts in Environment-Friendly Selective Oxidation Reactions [J]. Chinese Journal of Catalysis, 2019, 40(s1): 51-56.
[12]	Ruqun Guan, Xiaoming Zhang, Fangfang Chang, Nan Xue, Hengquan Yang. Incorporation of flexible ionic polymers into a Lewis acid-functionalized mesoporous silica for cooperative conversion of CO₂ to cyclic carbonates [J]. Chinese Journal of Catalysis, 2019, 40(12): 1874-1883.
[13]	D. J. Segobia, A. F. Trasarti, C. R. Apesteguía. Effect of the catalyst preparation method on the performance of Ni-supported catalysts for the synthesis of saturated amines from nitrile hydrogenation [J]. Chinese Journal of Catalysis, 2019, 40(11): 1693-1703.
[14]	Siqian Zhang, Yingjie Qian, Wha-Seung Ahn. Catalytic dehydrogenation of formic acid over palladium nanoparticles immobilized on fibrous mesoporous silica KCC-1 [J]. Chinese Journal of Catalysis, 2019, 40(11): 1704-1712.
[15]	D. Delgado, A. Fernández-Arroyo, N. La Salvia, M. E. Domine, Jose M. López Nieto. Reflux-synthesized bulk and diluted W-Nb-O mixed oxide bronzes for the valorization of short-chain oxygenates aqueous mixtures [J]. Chinese Journal of Catalysis, 2019, 40(11): 1778-1787.