Nanosized molecular sieves as petroleum refining and petrochemical catalysts

doi:10.1016/S1872-2067(11)60462-2

Abstract

Abstract: Nanosized ZSM-5 was synthesized and used for straight run gasoline reforming. Nanosized β was synthesized and used for the alkylation of benzene and ethylene in ethylbenzene production. Nanosized titanosilicate molecular sieve with a hollow structure (HTS) was synthesized and used for the oximation of cyclohexanone. Nanosized silicalite-1 was synthesized and used for the gas phase Beckmann rearrangement of cyclohexanone oxime in caprolactam production. Recent progress in the synthesis and application of nanosized ZSM-5, β, TS-1, and silicalite-1 were reviewed. The catalyst lifetimes were prolonged when nanosized molecular sieves were used as petroleum refining and petrochemical catalysts.

Key words: nanosized zeolite, ZSM-5, β, titanosilicate, silicalite-1, gasoline reforming, ethylbenzene, caprolactam

MU Xu-Hong, WANG Dian-Zhong, WANG Yong-Rui, LIN Min, CHENG Shi-Biao, SHU Xing-Tian. Nanosized molecular sieves as petroleum refining and petrochemical catalysts[J]. Chinese Journal of Catalysis, 2013, 34(1): 69-79.

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URL: https://www.cjcatal.com/EN/10.1016/S1872-2067(11)60462-2

https://www.cjcatal.com/EN/Y2013/V34/I1/69

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