Coking on micrometer- and nanometer-sized mordenite during dimethyl ether carbonylation to methyl acetate

doi:10.1016/S1872-2067(12)60607-X

Abstract

Abstract: As compared to conventional micrometer-sized mordenite particles, nanometer-sized mordenite gave a much higher activity and better stability in dimethyl ether carbonylation to methyl acetate by suppressing the deposition of hard coke. A structural analysis revealed that intra-crystalline diffusion limitation of the reactants and products to and from the active sites inside the channels was greatly decreased by reducing the zeolite size to the nanometer size.

Key words: H-mordenite, Dimethyl ether, Carbonylation, Crystal size, Coking

Huifu Xue, Xiumin Huang, Evert Ditzel, Ensheng Zhan, Meng Ma, Wenjie Shen. Coking on micrometer- and nanometer-sized mordenite during dimethyl ether carbonylation to methyl acetate[J]. Chinese Journal of Catalysis, 2013, 34(8): 1496-1503.

×
share this article

Add to citation manager EndNote|Ris|BibTeX

URL: https://www.cjcatal.com/EN/10.1016/S1872-2067(12)60607-X

https://www.cjcatal.com/EN/Y2013/V34/I8/1496

References

[1] San X G, Zhang Y, Shen W J, Tsubaki N. Energy Fuels, 2009, 23: 2843

[2] Li X G, San X G, Zhang Y, Ichii T, Meng M, Tan Y S, Tsubaki N. ChemSusChem, 2010, 3: 1192

[3] Zhang Y, San X G, Tsubaki N, Tan Y S, Chen J F. Ind Eng Chem Res, 2010, 49: 5485

[4] Cheung P, Bhan A, Sunley G J, Iglesia E. Angew Chem Int Ed, 2006, 45: 1617

[5] Blasco T, Boronat M, Concepción P, Corma A, Law D, Vidal-Moya J A. Angew Chem Int Ed, 2007, 46: 3938

[6] Cheung P, Bhan A, Sunley G J, Law D J, Iglesia E. J Catal, 2007, 245: 110

[7] Bhan A, Allian A D, Sunley G J, Law D J, Iglesia E. J Am Chem Soc, 2007, 129: 4919

[8] Boronat M, Martinez-Sanchez C, Law D, Corma A. J Am Chem Soc, 2008, 130: 16316

[9] Armitage G G, Sunley J G. EP Patent 2174713 A1. 2010

[10] Ditzel E J, Law D J, Sunley J G. WO Patent 2010067043 A1. 2010

[11] Ditzel E J, Law D J, Roberts M S. US Patent 20100130771 A1. 2010

[12] Liu J L, Xue H F, Huang X M, Wu P H, Huang S J, Liu S B, Shen W J. Chin J Catal (刘俊龙,薛会福,黄秀敏,吴培豪,黄信炅,刘尚斌,申文杰. 催化学报), 2010, 31: 729

[13] Liu J L, Xue H F, Huang X M, Li Y, Shen W J. Catal Lett, 2010, 139: 33

[14] Boronat M, Martinez C, Corma A. Phys Chem Chem Phys, 2011, 13: 2603

[15] Sano T, Wakabayashi S, Oumi Y, Uozumi T. Microporous Mesoporous Mater, 2001, 46: 67

[16] Christensen C H, Schmidt I, Christensen C H. Catal Commun, 2004, 5: 543

[17] Perez-Ramirez J, Christensen C H, Egeblad K, Christensen C H, Groen J C. Chem Soc Rev, 2008, 37: 2530

[18] Holm M S, Taarning E, Egeblad K, Christensen C H. Catal Today, 2011, 168: 3

[19] Magnoux P, Rabeharitsara A, Cerqueira H S. Appl Catal A, 2006, 304: 142

[20] Ji X F, Qin Z F, Dong M, Wang G F, Dou T, Wang J G. Catal Lett, 2007, 117: 171

[21] Choi M, Na K, Kim J, Sakamoto Y, Terasaki O, Ryoo R. Nature, 2009, 461: 246

[22] Mochizuki H, Yokoi T, Imai H, Watanabe R, Namba S, Kondo J N, Tatsumi T. Microporous Mesoporous Mater, 2011, 145: 165

[23] Tago T, Konno H, Sakamoto M, Nakasaka Y, Masuda T. Appl Catal A, 2011, 403: 183

[24] Rownaghi A A, Rezaei F, Stante M, Hedlund J. Appl Catal B, 2012, 119-120: 56

[25] Tago T, Konno H, Nakasaka Y, Masuda T. Catal Surv Asia, 2012, 16: 148

[26] Jang H-G, Min H-K, Lee J K, Hong S B, Seo G. Appl Catal A, 2012, 437: 120

[27] Rownaghi A A, Rezaei F, Hedlund J. Chem Eng J, 2012, 191: 528

[28] Guisnet M, Costa L, Ribeiro F R. J Mol Catal A, 2009, 305: 69

[29] Lee S H, Lee D K, Shin C H, Paik W C, Lee W M, Hong S B. J Catal, 2000, 196: 158

[30] Massiot D, Fayon F, Capron M, King I, Le Calve S, Alonso B, Durand J O, Bujoli B, Gan Z H, Hoatson G. Magn Reson Chem, 2002, 40: 70

[31] Ma D, Wang D Z, Su L L, Shu Y Y, Xu Y D, Bao X H. J Catal, 2002, 208: 260

[32] Barras J, Klinowski J, McComb D W. J Chem Soc, Faraday Trans, 1994, 90: 3719

[33] Bagnasco G. J Catal, 1996, 159: 249

[34] Katada N, Niwa M. Catal Surv Asia, 2004, 8: 161

[35] Levenspiel O. J Catal, 1972, 25: 265

[36] Yao S D, Gu L J, Sun C Y, Li J, Shen W J. Ind Eng Chem Res, 2009, 48: 713

[37] Guisnet M, Magnoux P. Appl Catal A, 2001, 212: 83

[38] Palumbo L, Bonino F, Beato P, Bjorgen M, Zecchina A, Bordiga S. J Phys Chem C, 2008, 112: 9710

[39] Rownaghi A A, Rezaei F, Hedlund J. Microporous Mesoporous Mater, 2012, 151: 26