Nanocoating of magnetic cores with sulfonic acid functionalized shells for the catalytic dehydration of fructose to 5-hydroxymethylfurfural

doi:10.1016/S1872-2067(12)60739-6

Abstract

Abstract:

A magnetically recyclable acid catalyst composed of an Fe₃O₄ core and sulfonic acid functionalized silica shell has been prepared using the reverse microemulsion method. The Fe₃O₄ core was coated with a phenyl modified silica shell nanolayer, and the phenyl groups were subsequently sulfonated to generate a solid sulfonic acid catalyst. The resulting acid catalyst showed higher activity than the conventional A-15 catalyst and comparable activity to several homogeneous sulfonic acid catalysts for the dehydration of fructose to 5-hydroxymethylfurfural (HMF). This process gave a fructose conversion of 99% with an HMF yield of 82% following 3 h in dimethylsulfoxide at 110 ℃. Furthermore, the catalyst could be magnetically separated and recycled several times without losing its activity.

Key words: Magnetic particle, Nanocatalyst, Fructose dehydration, 5-Hydroxymethylfurfural, Sulfonic acid

Xiaochen Zhang, Min Wang, Yehong Wang, Chaofeng Zhang, Zhe Zhang, Feng Wang, Jie Xu. Nanocoating of magnetic cores with sulfonic acid functionalized shells for the catalytic dehydration of fructose to 5-hydroxymethylfurfural[J]. Chinese Journal of Catalysis, 2014, 35(5): 703-708.

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URL: https://www.cjcatal.com/EN/10.1016/S1872-2067(12)60739-6

https://www.cjcatal.com/EN/Y2014/V35/I5/703

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