Pd/C-catalyzed ligand-free and aerobic Suzuki reaction in water

doi:10.1016/S1872-2067(12)60754-2

Abstract

Abstract:

A general and efficient catalytic system for Pd/C-catalyzed ligand-free aerobic Suzuki cross-coupling reactions was developed. The reaction tolerated a wide range of aryl bromides with a hydrophilic group or a hydrophobic group without any additives in water. Moreover, the catalytic system was successfully extended to the cross-couplings of heteroaryl halides with various arylboronic acids. The Pd/C catalyst could be reused three times without significant loss of catalytic activity.

Key words: Suzuki reaction, Palladium, Carbon, Ligand-free, Diisopropylamine, Biaryl

Xiaofeng Rao, Chun Liu, Yixia Zhang, Zhanming Gao, Zilin Jin. Pd/C-catalyzed ligand-free and aerobic Suzuki reaction in water[J]. Chinese Journal of Catalysis, 2014, 35(3): 357-361.

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URL: https://www.cjcatal.com/EN/10.1016/S1872-2067(12)60754-2

https://www.cjcatal.com/EN/Y2014/V35/I3/357

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