Rh catalysts supported on knitting aryl network polymers for the hydroformylation of higher olefins

doi:10.1016/S1872-2067(14)60068-1

Abstract

Abstract:

Rh catalysts supported on knitting aryl network polymers (Rh/KAPs) were prepared for the hydroformylation of higher olefins. Rh catalysts supported on triphenylphosphine-benzene-base polymers (Rh/KAPs-1) showed higher activity for the higher olefins than Rh/SiO₂ catalysts. Fourier transform infrared spectroscopy, thermogravimetry, N₂ adsorption-desorption, X-ray diffraction, transmission electron microscopy, ¹³C NMR, and ³¹P NMR showed that the Rh/KAPs-1 catalysts have high thermal stability, high surface area, hierarchical porosity, highly dispersed Rh nanoparticles, and in situ formed homogeneous active species during the reaction.

Key words: Triphenylphosphine, Knitting aryl network polymer, Rhodium, Heterogeneous catalyst, Hydroformylation of higher olefins

Miao Jiang, Yunjie Ding, Li Yan, Xiangen Song, Ronghe Lin. Rh catalysts supported on knitting aryl network polymers for the hydroformylation of higher olefins[J]. Chinese Journal of Catalysis, 2014, 35(9): 1456-1464.

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URL: https://www.cjcatal.com/EN/10.1016/S1872-2067(14)60068-1

https://www.cjcatal.com/EN/Y2014/V35/I9/1456

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