Preparation of LaXCoO3 (X = Mg, Ca, Sr, Ce) catalysts and their performance for steam reforming of ethanol to hydrogen

doi:10.1016/S1872-2067(14)60182-0

Abstract

Abstract:

Perovskite nanocomposite catalysts LaXCoO₃ (X = Mg, Ca, Sr, or Ce; n(La):n(X) = 3:2) have been prepared by a citric acid-complexing method and used for steam reforming of ethanol (SRE), leading to hydrogen generation. The samples were characterized by X-ray diffraction, infrared spectroscopy, scanning electron microscopy, X-ray photoelectron spectroscopy, N₂ adsorption-desorption, and H₂ temperature-programmed reduction. The effects of elemental substitution in the LaCoO₃ perovskite were studied, and the catalytic performance and primary stability of the hydrogen production from SRE were investigated. In the highly substituted samples, only the Ce-doped sample was isolated as the pure perovskite phase. The presence of a Co₃O₄ phase in the Ca-doped or Sr-doped samples was beneficial for the reduction of the active Co component, while Sr-doped or Ce-doped samples showed good activity and stability. The sample incorporating Sr demonstrated better catalytic performance than those of other samples.

Key words: Citric acid-complexing method, Perovskite, Cobalt, Composite catalyst, Ethanol steam reforming, Hydrogen

Fei Ma, Zhenwu Ding, Wei Chu, Shixiong Hao, Tao Qi. Preparation of LaXCoO₃ (X = Mg, Ca, Sr, Ce) catalysts and their performance for steam reforming of ethanol to hydrogen[J]. Chinese Journal of Catalysis, 2014, 35(10): 1768-1778.

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References

[1] Tong D G, Chu W, Wu P, Gu G F, Zhang L. J Mater Chem A, 2013, 1: 358
[2] Liu Q H, Liao L W, Liu Z L, Dong X F. J Energy Chem, 2013, 22: 665
[3] Fishtik I, Alexander A, Datta R, Geana D. Int J Hydrogen Energy, 2000, 25: 31
[4] Vizcaíno A J, Carrero A, Calles J A. Catal Today, 2009, 146: 63
[5] Sun J, Wu F, Qiu X P, Wang F, Hao S J, Liu Y. Chin J Catal (孙杰, 吴锋, 邱新平, 王芳, 郝少军, 刘媛. 催化学报), 2004, 25: 551
[6] Zhang L F, Liu J, Li W, Guo C L, Zhang J L. J Nat Gas Chem, 2009, 18: 55
[7] Ma F, Chu W, Huang L H, Yu X P, Wu Y Y. Chin J Catal (马飞, 储伟, 黄利宏, 余晓鹏, 吴永永. 催化学报), 2011, 32: 970
[8] Pereira E B, Homs N, Martí S, Fierro J L G, de la Piscina P R. J Catal, 2008, 257: 206
[9] Birot A, Epron F, Descorme C, Duprez D. Appl Catal B, 2008, 79: 17
[10] Cai W J, Wang F G, Zhan E S, Van Veen A C, Mirodatos C, Shen W J. J Catal, 2008, 257: 96
[11] He L, Wu Q, Li T M. Nat Gas Chem Ind (何飗, 吴倩, 李佟茗. 天然气化工(Cl化学与化工)), 2010, 35(5): 5
[12] Vizcaíno A J, Carrero A, Calles J A. Int J Hydrogen Energy, 2007, 32: 1450
[13] Frusteri F, Freni S, Spadaro L, Chiodo V, Bonura G, Donato S, Cavallaro S. Catal Commun, 2004, 5: 611
[14] Pang X J, Chen Y Z, Dai R Q, Cui P. Chin J Catal (庞潇健, 陈亚中, 代瑞旗, 崔鹏. 催化学报), 2012, 33: 281
[15] Peng D Q, Liu N, Wang Y H. Chem Engineer (彭得群, 刘宁, 王玉和. 化学工程师), 2008, (1): 7
[16] Petrovic S, Pakic V, Jovanovic D M, Baricevic A T. Appl Catal B, 2006, 66: 249
[17] Balamurugan S, Xu M, Takayama-Muromachi E. J Solid State Chem, 2005, 178: 3431
[18] Hejtmanek J, Jirak Z, Knizek K, Marysko M, Veverka M, Autret C. J Magn Magn Mater, 2008, 320: e92
[19] Murthy P S R, Priolkar K R, Bhobe P A, Das A, Sarode P R, Nigam A K. J Magn Magn Mater, 2011, 323: 822
[20] Magalh?es R N S H, Toniolo F S, da Silva V T, Schmal M. Appl Catal A, 2010, 388: 216
[21] Cui M S, Li M L, Zhang S L, Long Z Q, Cui D L, Huang X W. Chin J Nonferrous Metal (崔梅生, 李明来, 张顺利, 龙志奇, 崔大立, 黄小卫. 中国有色金属学报), 2004, 14: 1580
[22] Leontiou A A, Ladavos A K, Armatas G S, Trikalitis P N, Pomonis P T. Appl Catal A, 2004, 263: 227
[23] Sey? B, Baghalha M, Kazemian H. Chem Eng J, 2009, 148: 306
[24] Bedel L, Roger A C, Rehspringer J L, Zimmermann Y, Kiennemann A. J Catal, 2005, 235: 279
[25] Ding R R, Li C, Wang L J, Hu R S. Appl Catal A, 2013, 464-465: 261
[26] Han X, Yu Y B, He H, Zhao J J. J Energy Chem, 2013, 22: 861
[27] Sun Y, Hla S S, Dffy G J, Cousins A J, French D, Morpeth L D, Edwards J H, Roberts D G. Int J Hydrogen Energy, 2011, 36: 79
[28] Nakamoto K. Infrared and Raman Spectra of Inorganic and Coordination Compounds, Part B, Applications in Coordination, Organometallic, and Bioinorganic Chemistry. 6th Ed. New York: John Wiley & Sons, 2009. 110
[29] Rao G V S, Rao C N R, Ferraro J R. Appl Spectrosc, 1970, 24: 436
[30] Choi D H, Shim I B, Kim C S, Shaterian M. J Magn Magn Mater, 2008, 320: e575
[31] Salavati-Niasari M, Khansari A, Davar F. Inorg Chim Acta, 2009, 362: 4937
[32] Sharma Y, Sharma N, Subba Rao G V, Chowdari B V R. Solid State Ionics, 2008, 179: 587
[33] Stelmachowski P, Maniak G, Kaczmarczyk J, Zasada F, Piskorz W, Kotarba A, Sojka Z. Appl Catal B, 2014, 146: 105
[34] Hyman M P, Vohs J M. Surf Sci, 2011, 605: 383

Preparation of LaXCoO₃ (X = Mg, Ca, Sr, Ce) catalysts and their performance for steam reforming of ethanol to hydrogen

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