Synthesis, characterization, and catalytic performance of La0.6Sr0.4NixCo1-xO3 perovskite catalysts in dry reforming of coke oven gas

doi:10.1016/S1872-2067(14)60303-X

Abstract

Abstract:

The dry reforming of coke oven gas (COG) to produce syngas was performed over La_0.6Sr_0.4Ni_xCo_1-xO₃ catalysts in a fixed-bed reactor at 800 ℃. These perovskite-type oxides were synthesized using a sol-gel method and characterized using X-ray diffraction (XRD), N₂ adsorption-desorption, temperature-programmed reduction of H₂, scanning electron microscopy, transmission electron microscopy, and thermogravimetry-differential scanning calorimetry. XRD results showed that the La_0.6Sr_0.4Ni_xCo_1-xO₃ perovskite-type oxides formed quaternary solid solutions. The effects of the degree of Ni substitution (x) and the catalyst calcination temperature on the dry reforming of COG were investigated. XRD analysis of the tested catalysts showed the formation of Ni⁰, Co⁰, and La₂O₂CO₃, of which the latter is the main active phase responsible for the high activity and stability, and the suppression of coke formation under severe reaction conditions. COG rich in H₂ can also reduce the formation of carbon deposits by inhibiting CH₄ decomposition.

Key words: Syngas, Catalytic activity, Perovskite, Dry reforming, Coke oven gas, Carbon deposit

Qiuhua Zhu, Hongwei Cheng, Xingli Zou, Xionggang Lu, Qian Xu, Zhongfu Zhou. Synthesis, characterization, and catalytic performance of La_0.6Sr_0.4Ni_xCo_1-xO₃ perovskite catalysts in dry reforming of coke oven gas[J]. Chinese Journal of Catalysis, 2015, 36(7): 915-924.

×
share this article

Add to citation manager EndNote|Ris|BibTeX

URL: https://www.cjcatal.com/EN/10.1016/S1872-2067(14)60303-X

https://www.cjcatal.com/EN/Y2015/V36/I7/915

References

[1] Domínguez A, Fernández Y, Fidalgo B, Pis J J, Menéndez J A. Energy Fuels, 2007, 21: 2066
[2] Zahedinezhad M, Rowshanzamir S, Eikani M H. Int J Hydrogen Energy, 2009, 34: 1292
[3] Bernudez J M, Ferrera-Lorenzo N, Luque S, Arenillas A, Menendez J A. Fuel Process Technol, 2013, 115: 215
[4] Tao W, Cheng H W, Zhu Q H, Lu X G, Ding W Z. Appl Mech Mater, 2013, 394: 270
[5] Modesto M, Nebra S A. Appl Therm Eng, 2009, 29: 2127
[6] Suttiumporn K, Maneerung T, Kathiraser Y, Kawi S. Int J Hydrogen Energy, 2012, 37: 11195
[7] Wang Q, Luo J, Zhong Z, Borgna A. Energy Environ Sci, 2011, 4: 42
[8] Song C S. Catal Today, 2002, 77: 17
[9] Ni M, Leung D Y C, Leung M K H, Sumathy K. Fuel Process Technol, 2006, 87: 461
[10] Turpeinen E, Raudaskoski R, Pongracz E, Keiski R L. Int J Hydrogen Energy, 2008, 33: 6635
[11] Bermudez J M, Fidalgo B, Arenillas A, Menendez J A. Fuel, 2010, 89: 2897
[12] Yang Z B, Ding W Z, Zhang Y W, Lu X G, Zhang Y W, Shen P J. Int J Hydrogen Energy, 2010, 35: 6239
[13] Shen J, Wang Z Z, Yang H W, Yao R S. Energy Fuels, 2007, 21: 3588
[14] Joseck F, Wang M, Wu Y. Int J Hydrogen Energy, 2008, 33: 1445
[15] Cheng H W, Lu X G, Hu D H, Zhang Y F, Ding W Z, Zhao H L. Int J Hydrogen Energy, 2011, 36: 528
[16] Matos J, Diaz K, Carcia V, Cordero T C, Brito J L. Catal Lett, 2006, 109: 163
[17] Pompeo F, Gazzoli D, Nichio N N. Int J Hydrogen Energy, 2009, 34: 2260
[18] Hirose T, Ozawa Y, Nagai M. Chin J Catal (催化学报), 2011, 32: 771
[19] Bartholomew C H. Catal Rev Sci Eng, 1982, 24: 67
[20] Goldwasser M R, Rivas M E, Pietri E, Perez-Zurita M J, Cubeiro M L, Grivobal-Constant A, Leclerq G. J Mol Catal A, 2005, 228: 325
[21] Moradi G R, Khosravian F, Kahmanzadeh M. Chin J Catal (催化学报), 2012, 33: 797
[22] Echchahed B, Kaliaguine S, Alamdari H. Int J Chem React Eng, 2006, 4: A29
[23] Valderrama G, Kiennemann A, Goldwasser M R. Catal Today, 2008, 133: 142
[24] Sutthiumporn K, Kawi S. Int J Hydrogen Energy, 2011, 36: 14435
[25] Li Q M, Zhu X F, He X F, Cong Y, Yang W S. J Membr Sci, 2011, 367: 134
[26] Luo H X, Jiang H Q, Efimov K, Caro J, Wang H H. AIChE J, 2011, 57: 2738
[27] Zhang Y W, Cheng H W, Lu X G, Ding W Z, Zhou G Z. Rare Metals, 2009, 28: 582
[28] Cheng H W, Zhang Y W, Lu X G, Ding W Z, Li Q. Energy Fuels, 2009, 23: 414
[29] Tao W, Cheng H W, Yao W L, Lu X G, Zhu Q H, Li G S, Zhou Z F. Int J Hydrogen Energy, 2014, 39: 18650
[30] Guo J Z, Hou Z Y, Gao J, Zheng X M. Energy Fuels, 2008, 22: 1444
[31] Roh H S, Jun K W, Dong W S, Chang J S, Park S E, Joe Y I. J Mol Catal A, 2002, 181: 137
[32] Bedel L, Roger A C, Estournes C, Kiennemann A. Catal Today, 2003, 85: 207
[33] Valderrama G, Kiennemann A, Goldwasser M R. J Power Sources, 2010, 195: 1765
[34] Sokolov S, Kondratenko E V, Pohl M M, Barkschat A, Rodemerk U. Appl Catal B, 2012, 113-114: 19
[35] Zhang Z L, Verykios X E. Appl Catal A, 1996, 138: 109
[36] Zhang Z L, Verykios X E, Macdonald S M, Affrossman S. J Phys Chem, 1996, 100: 744
[37] Orera A, Larraz G, Sanjuán M L. J Eur Ceram Soc, 2013, 33: 2103
[38] Fierro J L G, Tascon J M D, Tejuca L G. J Catal, 1985, 93: 83
[39] Sierra Gallego G, Mondragon F, Barrault J, Tatibouet J M, Batiot-Duperyrat C. Appl Catal A, 2006, 311: 164
[40] Duprez D, Demiccheli M C, Marecot P, Barbier J, Ferretti O A, Ponzi E N. J Catal, 1990, 124: 324
[41] Valderrama G, Navarro C U, Goldwasser M R. J Power Sources, 2013, 234: 31
[42] Cheng H W, Feng S H, Tao W, Lu X G, Yao W L, Li G S, Zhou Z F. Int J Hydrogen Energy, 2014, 39: 12604
[43] Tsyganok A I, Tsunoda T, Hamakawa S, Suzuki K, Takehira K, Hayakawa T. J Catal, 2003, 213: 191
[44] Slagtern A, Schuurman Y, Leclercq C, Verykios X, Mirodatos C. J Catal, 1997, 172: 118
[45] Rynkowski J M, Paryjczak T, Lenik M. Appl Catal A, 1995, 126: 257
[46] Hou Z Y, Yokota O, Tanaka T, Yashima T. Catal Lett, 2003, 89: 121

Synthesis, characterization, and catalytic performance of La_0.6Sr_0.4Ni_xCo_1-xO₃ perovskite catalysts in dry reforming of coke oven gas

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

[1]	Yuannan Wang, Lina Wang, Kexin Zhang, Jingyao Xu, Qiannan Wu, Zhoubing Xie, Wei An, Xiao Liang, Xiaoxin Zou. Electrocatalytic water splitting over perovskite oxide catalysts [J]. Chinese Journal of Catalysis, 2023, 50(7): 109-125.
[2]	Peigong Liu, Tiejun Lin, Lei Guo, Xiaozhe Liu, Kun Gong, Taizhen Yao, Yunlei An, Liangshu Zhong. Tuning cobalt carbide wettability environment for Fischer-Tropsch to olefins with high carbon efficiency [J]. Chinese Journal of Catalysis, 2023, 48(5): 150-163.
[3]	Zhuogen Li, Qadeer Ul Hassan, Weibin Zhang, Lujun Zhu, Jianzhi Gao, Xianjin Shi, Yu Huang, Peng Liu, Gangqiang Zhu. Promotion of dual-reaction pathway in CO₂ reduction over Pt⁰/SrTiO_3‒_δ: Experimental and theoretical verification [J]. Chinese Journal of Catalysis, 2023, 46(3): 113-124.
[4]	Diab khalafallah, Yunxiang Zhang, Hao Wang, Jong-Min Lee, Qinfang Zhang. Energy-saving electrochemical hydrogen production via co-generative strategies in hybrid water electrolysis: Recent advances and perspectives [J]. Chinese Journal of Catalysis, 2023, 55(12): 44-115.
[5]	Yu Wang, Jaime Gallego, Wei Wang, Phillip Timmer, Min Ding, Alexander Spriewald Luciano, Tim Weber, Lorena Glatthaar, Yanglong Guo, Bernd M. Smarsly, Herbert Over. Unveiling the self-activation of exsolved LaFe_0.9Ru_0.1O₃ perovskite during the catalytic total oxidation of propane [J]. Chinese Journal of Catalysis, 2023, 54(11): 250-264.
[6]	Zhechen Fan, Hao Wan, Hao Yu, Junjie Ge. Rational design of Fe-M-N-C based dual-atom catalysts for oxygen reduction electrocatalysis [J]. Chinese Journal of Catalysis, 2023, 54(11): 56-87.
[7]	Yiming Lei, Jinhua Ye, Jordi García-Antón, Huimin Liu. Recent advances in the built-in electric-field-assisted photocatalytic dry reforming of methane [J]. Chinese Journal of Catalysis, 2023, 53(10): 72-101.
[8]	Yu Shang, Yunxuan Ding, Peili Zhang, Mei Wang, Yufei Jia, Yunlong Xu, Yaqing Li, Ke Fan, Licheng Sun. Pyrrolic N or pyridinic N: The active center of N-doped carbon for CO₂ reduction [J]. Chinese Journal of Catalysis, 2022, 43(9): 2405-2413.
[9]	Yanfei Zhang, Hong Wang, Yan Liu, Can Li. Aromatic bromination with hydrogen production on organic-inorganic hybrid perovskite-based photocatalysts under visible light irradiation [J]. Chinese Journal of Catalysis, 2022, 43(7): 1805-1811.
[10]	Yingjie Zhou, Tianfu Liu, Yuefeng Song, Houfu Lv, Qingxue Liu, Na Ta, Xiaomin Zhang, Guoxiong Wang. Highly dispersed nickel species on iron-based perovskite for CO₂ electrolysis in solid oxide electrolysis cell [J]. Chinese Journal of Catalysis, 2022, 43(7): 1710-1718.
[11]	Xiaoqin Han, Jiachang Zuo, Danlu Wen, Youzhu Yuan. Toluene methylation with syngas to para-xylene by bifunctional ZnZrO_x-HZSM-5 catalysts [J]. Chinese Journal of Catalysis, 2022, 43(4): 1156-1164.
[12]	Qi Zhang, Hui Chen, Lan Yang, Xiao Liang, Lei Shi, Qing Feng, Yongcun Zou, Guo-Dong Li, Xiaoxin Zou. Non-catalytic, instant iridium (Ir) leaching: A non-negligible aspect in identifying Ir-based perovskite oxygen-evolving electrocatalysts [J]. Chinese Journal of Catalysis, 2022, 43(3): 885-893.
[13]	Zhaopeng Liu, Youming Ni, Zhongpan Hu, Yi Fu, Xudong Fang, Qike Jiang, Zhiyang Chen, Wenliang Zhu, Zhongmin Liu. Insights into effects of ZrO₂ crystal phase on syngas-to-olefin conversion over ZnO/ZrO₂ and SAPO-34 composite catalysts [J]. Chinese Journal of Catalysis, 2022, 43(3): 877-884.
[14]	Zhiyang Chen, Youming Ni, Fuli Wen, Ziqiao Zhou, Wenliang Zhu, Zhongmin Liu. The carboxylates formed on oxides promoting the aromatization in syngas conversion over composite catalysts [J]. Chinese Journal of Catalysis, 2021, 42(5): 835-843.
[15]	Dan Yang, Yan Zhu. Evolution of catalytic activity driven by structural fusion of icosahedral gold cluster cores [J]. Chinese Journal of Catalysis, 2021, 42(2): 245-250.