Carbon dioxide-expanded ethanol-assisted synthesis of carbon-based metal composites and their catalytic and electrochemical performance in lithium-ion batteries

doi:10.1016/S1872-2067(15)61024-5

Abstract

Abstract:

Highly dispersed metals, metal oxides and their composites on substrates have received considerable interest in catalysis and lithium-ion batteries, because of their superior properties compared with their single-component counterparts. In this review, we introduce the properties of supercritical carbon dioxide (scCO₂) expanded ethanol, such as low viscosity, near-zero surface tension and high diffusivity. We discuss the deposition procedure and formation mechanism of carbon-based composites in scCO₂-expanded ethanol. This method has been used to fabricate several carbon-based composites, such as metal and metal oxide composites deposited on zero-dimensional colloidal carbon, one-dimensional carbon nanotubes, two-dimensional graphene, and three-dimensional hierarchical porous carbon. These materials and their performance as anodic materials for lithium-ion batteries will also be reviewed.

Key words: CO₂-expanded ethanol, Carbon, Metal oxide, Catalysis, Electrochemistry

Lingyan Wang, Linhai Zhuo, Fengyu Zhao. Carbon dioxide-expanded ethanol-assisted synthesis of carbon-based metal composites and their catalytic and electrochemical performance in lithium-ion batteries[J]. Chinese Journal of Catalysis, 2016, 37(2): 218-226.

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URL: https://www.cjcatal.com/EN/10.1016/S1872-2067(15)61024-5

https://www.cjcatal.com/EN/Y2016/V37/I2/218

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