Methanol-to-olefin induction reaction over SAPO-34

doi:10.1016/S1872-2067(15)61110-X

Abstract

Abstract:

The methanol-to-olefin induction reaction over the SAPO-34 was performed using a fluidized-bed system. We found that the whole induction period could be divided into three reaction stages. Further investigation of the reaction kinetics revealed that this induction reaction behavior was different from that over H-ZSM-5 catalyst. Compared with the H-ZSM-5, the generation of initial active centers is easier over SAPO-34 because of its limited diffusivity and the spatial confinement effect of the cages. However, the autocatalysis reaction stage is difficult over SAPO-34 because of the continuous formation of inactive methyladamantanes.

Key words: Methanol-to-olefin, Activation energy, SAPO-34, Hydrocarbon pool, Induction period

You Zhou, Liang Qi, Yingxu Wei, Cuiyu Yuan, Mozhi Zhang, Zhongmin Liu. Methanol-to-olefin induction reaction over SAPO-34[J]. Chinese Journal of Catalysis, 2016, 37(9): 1496-1501.

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URL: https://www.cjcatal.com/EN/10.1016/S1872-2067(15)61110-X

https://www.cjcatal.com/EN/Y2016/V37/I9/1496

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