Zirconium triflate grafted on SBA-15 as a highly efficient solid acid catalyst for ring opening of epoxides by amines and alcohols

doi:10.1016/S1872-2067(17)62794-3

Abstract

Abstract:

Metal (Al, Ti, Zr) triflate grafted mesoporous SBA-15 (AlTf/S, TiTf/S, ZrTf/S) samples were synthesized as inexpensive solid acid materials by a simple one-pot-two-step synthesis methodology. These materials were characterized by X-ray diffraction, N₂-sorption, thermogravimetric analysis, Fourier transform infrared spectroscopy (FT-IR), in-situ pyridine FT-IR spectroscopy, and elemental analysis. ZrTf/S was found to be a highly efficient and reusable solid acid catalyst for ring opening of epoxides with amines and alcohols and produced β-amino alcohols and β-alkoxy alcohols respectively under ambient reaction conditions. The ZrTf/S catalyst showed the highest activity, which was attributed to its high acidity compared with that of the Ti and Al containing samples.

Key words: Epoxide ring opening, Acid catalysis, Metal triflate, Grafted catalyst, Mesoporous silica

Kamlesh N.Tayade, Lianyue Wang, Sensen Shang, Wen Dai, Manish Mishra, Shuang Gao. Zirconium triflate grafted on SBA-15 as a highly efficient solid acid catalyst for ring opening of epoxides by amines and alcohols[J]. Chinese Journal of Catalysis, 2017, 38(4): 758-766.

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URL: https://www.cjcatal.com/EN/10.1016/S1872-2067(17)62794-3

https://www.cjcatal.com/EN/Y2017/V38/I4/758

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