Ultra-deep oxidative desulfurization of fuel with H2O2 catalyzed by phosphomolybdic acid supported on silica

doi:10.1016/S1872-2067(16)62558-5

Abstract

Abstract:

A highly active catalyst of phosphomolybdic acid (HPMo) was prepared and applied in the catalytic oxidative desulfurization (CODS) system. The catalyst was characterized by FT-IR, XRD, XPS and superconducting NMR. The influences of m(catalyst)/m(oil), V(H₂O₂)/V(oil), reaction temperature and reaction time on the fractional conversion of benzothiophene (BT) and dibenzothiophene (DBT) were investigated. GC-MS and micro-coulometric methods were employed to investigate the reaction. The catalyst has high desulfurization activity in the removal of BT and DBT under mild conditions. The recycling experiments indicated that DBT and BT removal could still reach 95.2% and 95.7% after 10 cycles.

Key words: Mesoporous silica, Phosphomolybdic acid, Oxidative desulfurization, Benzothiophene, Dibenzothiophene

Yongsheng Tian, Guanghui Wang, Juan Long, Jiawei Cui, Wei Jin, Danlin Zeng. Ultra-deep oxidative desulfurization of fuel with H₂O₂ catalyzed by phosphomolybdic acid supported on silica[J]. Chinese Journal of Catalysis, 2016, 37(12): 2098-2105.

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URL: https://www.cjcatal.com/EN/10.1016/S1872-2067(16)62558-5

https://www.cjcatal.com/EN/Y2016/V37/I12/2098

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Ultra-deep oxidative desulfurization of fuel with H₂O₂ catalyzed by phosphomolybdic acid supported on silica

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