Synthesis and characterization of PMoV/Fe3O4/g-C3N4 from melamine: An industrial green nanocatalyst for deep oxidative desulfurization

doi:10.1016/S1872-2067(16)62548-2

Abstract

Abstract:

A facile approach to the preparation of a novel magnetically separable H₅PMo₁₀V₂O₄₀/Fe₃O₄/g-C₃N₄ (PMoV/Fe₃O₄/g-C₃N₄) nanocomposite by chemical impregnation is demonstrated. The prepared nanocomposite was characterized and its acidity was measured by potentiometric titration. PMoV/Fe₃O₄/g-C₃N₄ showed high catalytic activity in the selective oxidative desulfurization of sulfides to their corresponding sulfoxides or sulfones. The catalytic oxidation of a dibenzothiophene (DBT)-containing model oil and that of real oil were also studied under optimized conditions. In addition, the effects of various nitrogen compounds, as well as the use of one- and two-ring aromatic hydrocarbons as co-solvents, on the catalytic removal of sulfur from DBT were investigated. The catalyst was easily separated and could be recovered from the reaction mixture by using an external magnetic field. Additionally, the remaining reactants could be separated from the products by simple decantation if an appropriate solvent was chosen for the extraction. The advantages of this nanocatalyst are its high catalytic activity and reusability; it can be used at least four times without considerable loss of activity.

Key words: Graphitic carbon nitride, Nanocomposite, Melamine, Heteropoly acid, Oxidative desulfurization, Oil

Ezzat Rafiee, Maryam Khodayari. Synthesis and characterization of PMoV/Fe₃O₄/g-C₃N₄from melamine: An industrial green nanocatalyst for deep oxidative desulfurization[J]. Chinese Journal of Catalysis, 2017, 38(3): 458-468.

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URL: https://www.cjcatal.com/EN/10.1016/S1872-2067(16)62548-2

https://www.cjcatal.com/EN/Y2017/V38/I3/458

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Synthesis and characterization of PMoV/Fe₃O₄/g-C₃N₄from melamine: An industrial green nanocatalyst for deep oxidative desulfurization

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