A novel process of ozone catalytic oxidation for low concentration formaldehyde removal

doi:10.1016/S1872-2067(17)62890-0

Chinese Journal of Catalysis ›› 2017, Vol. 38 ›› Issue (10): 1759-1769.DOI: 10.1016/S1872-2067(17)62890-0

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A novel process of ozone catalytic oxidation for low concentration formaldehyde removal

Bin Zhu^a,b,c, XiaoSong Li^b,c, Peng Sun^b,c, JingLin Liu^b,c, XiaoYuan Ma^b,c, Xiaobing Zhu^b,c, AiMin Zhu^b,c

a. Collaborative Innovation Center for Vessel Pollution Monitoring and Control, Dalian Maritime University, Dalian 116026, Liaoning, China;
b. Laboratory of Plasma Physical Chemistry, Dalian University of Technology, Dalian 116024, Liaoning, China;
c. Center for Hydrogen Energy & Environmental Catalysis, Dalian University of Technology, Dalian 116024, Liaoning, China

Received:2017-06-02 Revised:2017-07-19 Online:2017-10-18 Published:2017-10-28
Contact: 10.1016/S1872-2067(17)62890-0
Supported by:
This work was supported by the National Natural Science Foundation of China (21673030) and the Higher Education Development Fund (for Collaborative Innovation Center) of Liaoning Province, China (20110217004).

Abstract

Abstract:

To reduce energy costs, minimize secondary pollution from undecomposed ozone, and improve the efficiency of ozone use, a novel process of cycled storage-ozone catalytic oxidation (OZCO) was employed to remove formaldehyde (HCHO) at low concentrations in air. We applied Al₂O₃-supported manganese oxide (MnO_x) catalysts to this process, and examined the HCHO adsorption capacity and OZCO performance over the MnO_x catalysts. Owing to the high dispersion of MnO_x and low oxidation state of manganese, the MnO_x/Al₂O₃ catalysts with a manganese acetate precursor and 10%-Mn loading showed good performance in both storage and OZCO stages. The presence of H₂O led to a decrease of the HCHO adsorption capacity owing to competitive adsorption between moisture and HCHO at the storage stage; however, high relative humidity (RH) favored complete conversion of stored HCHO to CO₂ at the OZCO stage and contributed to an excellent carbon balance. Four low concentration HCHO storage-OZCO cycles with a long HCHO storage period and relatively short OZCO period were successfully performed over the selected MnO_x/Al₂O₃ catalyst at room temperature and a RH of 50%, demonstrating that the proposed storage-OZCO process is an economical, reliable, and promising technique for indoor air purification.

Key words: Formaldehyde removal, Storage, Ozone, Catalytic oxidation, Manganese oxide catalyst

Bin Zhu, XiaoSong Li, Peng Sun, JingLin Liu, XiaoYuan Ma, Xiaobing Zhu, AiMin Zhu. A novel process of ozone catalytic oxidation for low concentration formaldehyde removal[J]. Chinese Journal of Catalysis, 2017, 38(10): 1759-1769.

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A novel process of ozone catalytic oxidation for low concentration formaldehyde removal

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