Preparation of MnCo/MCM-41 catalysts with high performance for chlorobenzene combustion

doi:10.1016/S1872-2067(17)62950-4

Abstract

Abstract:

MCM-41 was synthesized by a soft template technique. The specific surface area and pore volume of the MCM-41 were 805.9 m²/g and 0.795 cm³/g, respectively. MCM-41-supported manganese and cobalt oxide catalysts were prepared by an impregnation method. The energy dispersive X-ray spectroscopy clearly confirmed the existence of Mn, Co, and O, which indicated the successful loading of the active components on the surface of MCM-41. The structure and function of the catalysts were changed by modulating the molar ratio of manganese to cobalt. The 10%MnCo(6:1)/MCM-41 (Mn/Co molar ratio is 6:1) catalyst displayed the best catalytic activity according to the activity evaluation experiments, and chlorobenzene (1000 ppm) was totally decomposed at 270℃. The high activity correlated with a high dispersion of the oxides and was attributed to the exposure of more active sites, which was demonstrated by X-ray diffraction and high-resolution transmission electron microscopy. The strong interactions between MnO₂, Co₃O₄, MnCoO_x, and MCM-41 indicated that cobalt promoted the redox cycles of the manganese system. The bimetal-oxide-based catalyst showed better catalytic activity than that of the single metal oxide catalysts, which was further confirmed by H₂ temperature-programmed reduction. Chlorobenzene temperature-programmed desorption results showed that 10%MnCo(6:1)/MCM-41 had higher adsorption strength for chlorobenzene than that of single metal catalysts. And stronger adsorption was beneficial for combustion of chlorobenzene. Furthermore, 10%MnCo(6:1)/MCM-41 was not deactivated during a continuous reaction for 1000 h at 260℃ and displayed good resistance to water and benzene, which indicated that the catalyst could be used in a wide range of applications.

Key words: MCM-41, Mn/Co, Catalytic combustion, Chlorobenzene, Characterization

Zhen Cheng, Jingrong Li, Peng Yang, Shufeng Zuo. Preparation of MnCo/MCM-41 catalysts with high performance for chlorobenzene combustion[J]. Chinese Journal of Catalysis, 2018, 39(4): 849-856.

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URL: https://www.cjcatal.com/EN/10.1016/S1872-2067(17)62950-4

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References

[1] L. Zhang, Y. X. Peng, J. Zhang, L. Chen, X. J. Meng, F. S. Xiao, Chin. J. Catal., 2016, 37, 800-809.
[2] Y. X. Liu, J. G. Deng, S. H. Xie, Z. W. Wang, H. X. Dai, Chin. J. Catal., 2016, 37, 1193-1205.
[3] J. W. Kan, B. Li, L. Li, X. J. Wang, Y. W. Chen, S. M. Zhu, S. B. Shen, Chem. Ind. Eng. Progr., 2016, 35, 499-505.
[4] S. F. Zuo, M. L. Ding, J. Tong, L. C. Feng, C. Z. Qi, Appl. Clay Sci., 2015, 105-106, 118-123.
[5] V. H. Vu, J. Belkouch, A. Ould-Dris, B. Taouk, J. Hazard. Mater., 2009, 169, 758-765.
[6] M. Nikoorazm, F. Ghorbani, A. Ghorbani-Choghamarani, Z. Erfani, Chin. J. Catal., 2017, 38, 1413-1422.
[7] Y. Han, F. S. Xiao, Chin. J. Catal., 2003, 24, 149-158.
[8] M. H. Yuan, C. C. Chang, C. Y. Chang, W. C. Liao, W. K. Tu, J. Y. Tseng, D. R. Ji, J. L. Shie, Y. H. Chen, J. Taiwan Inst. Chem. Eng., 2015, 53, 52-57.
[9] S. Pitkäaho, L. Matejova, S. Ojala, J. Gaalova, R. L. Keiski, Appl. Catal. B, 2012, 113-114, 150-159.
[10] Z. E Assal, S. Ojala, S. Pitkäaho, L. Pirault-Roy, B. Darif, J. D. Com-parot, M. Bensitel, R. L. Keiski, R. Brahmi, Chem. Eng. J., 2017, 313, 1010-1022.
[11] J. D. Liu, T. T. Zhang, A. P. Jia, M. F. Luo, J. Q. Lu, Appl. Surf. Sci., 2016, 369, 58-66.
[12] C. H. Zhang, C. Wang, W. C. Hua, Y. L. Guo, G. Z. Lu, S. Gil, A. Giroir-Fendler, Appl. Catal. B, 2016, 186, 173-183.
[13] W. Wang, Q. Zhu, Q. G. Dai, X. Y. Wang, Chem. Eng. J., 2017, 307, 1037-1046.
[14] S. Cao, H. Q. Wang, F. X. Yu, M. P. Shi, S. Chen, X. L. Weng, Y. Liu, Z. B. Wu, J. Colloid Interf. Sci., 2016, 463, 233-241.
[15] W. Deng, Q. G. Dai, Y. J. Lao, B. B. Shi, X. Y. Wang, Appl. Catal. B, 2016, 181, 848-861.
[16] L. Wang, H. K. Xie, X. D. Wang, G. Z. Zhang, Y. L. Guo, Y. Guo, G. Z. Lu, Chin. J. Catal., 2017, 38, 1406-1412.
[17] P. Yang, J. R. Li, S. F. Zuo, Chem. Eng. Sci., 2017, 162, 218-226.
[18] Y. Yan, L. Wang, H. P. Zhang, X. Y. Zhang, Sep. Purif. Technol., 2017, 175, 213-221.
[19] P. Yang, S. S. Yang, Z. N. Shi, Z. H. Meng, R. X. Zhou, Appl. Catal. B, 2015, 162, 227-235.
[20] P. Yang, S. F. Zuo, R. X. Zhou, Chem. Eng. J., 2017, 323, 160-170.
[21] Q. Q. Huang, Z. H. Meng, R. X. Zhou, Appl. Catal. B, 2012, 115-116, 179-189.
[22] Q. Q. Huang, X. M. Xue, R. X. Zhou, J. Mol. Catal. A, 2011, 344, 74-82.
[23] P. Yang, X. M. Xue, Z. H. Meng, R. X. Zhou, Chem. Eng. J., 2013, 234, 203-210.
[24] Q. Q. Huang, X. M. Xue, R. X. Zhou, J. Hazard. Mater., 2010, 183, 694-700.
[25] M. Wu, X. Y. Wang, Q. G. Dai, Y. X. Gu, D. Li, Catal. Today, 2010, 158, 336-342.
[26] C. H. Xu, C. Q. Liu, Y. Zhong, X. Z. Yang, J. Y. Liu, Y. C. Yang, Z. X. Ye, Chin. Chem. Lett., 2008, 19, 1387-1390.
[27] A. Z. Abdullah, M. Z. Abu Bakar, S. Bhatia, J. Hazard. Mater., 2006, 129, 39-49.
[28] D. Li, Y. Zheng, X. Y. Wang, Appl. Catal. A, 2008, 340, 33-41.
[29] X. Y. Wang, Q. G. Dai, Y. Zheng, Chin. J. Catal., 2006, 27, 468-470.
[30] J. L. Zhao, G. Qian, F. Y. Li, J. Zhu, S. F. Ji, L. Li, Chin. J. Catal., 2012, 33, 771-776.
[31] T. A. Konovalova, Y. L. Gao, R. Schad, L. D. Kispert, C. A. Saylor, L. C. Brunel, J. Phys. Chem. B, 2001, 105, 7459-7464.
[32] J. R. Li, S. F. Zuo, P. Yang, C. Z. Qi, Mater., 2017, 10, 949.
[33] J. W. Kan, L. Deng, B. Li, Q. Huang, S. M. Zhu, S. B. Shen, Y. W. Chen, Appl. Catal. A, 2017, 530, 21-29.
[34] M. Wu, X. Y. Wang, Q. G. Dai, D. Li, Catal. Commun., 2010, 11, 1022-1025.
[35] M. Wu, X. Y. Wang, Q. G. Dai, Y. X. Gu, D. Li, Catal. Today, 2010, 158, 336-342.
[36] S. F. Zuo, P. Yang, X. Q. Wang, ACS Omega, 2017, 2, 5179-5186.
[37] W. Zhao, J. Cheng, L. N. Wang, J. L. Chu, J. K. Qu, Y. H. Liu, S. H. Li, H. Zhang, J. C. Wang, Z. P. Hao, T. Qi, Appl. Catal. B, 2012, 127, 246-254.
[38] G. L. Zhou, X. L. He, S. Liu, H. M. Xie, M. Fu, J. Ind. Eng. Chem., 2015, 21, 932-941.
[39] T. Cai, H. Huang, W. Deng, Q. G. Dai, W. Liu, X. Y. Wang, Appl. Catal. B, 2015, 166-167, 393-405.
[40] G. L. Zhou, X. L. He, S. Liu, H. M. Xie, M. Fu, J. Ind. Eng. Chem., 2014, 5, 21, 932-941.
[41] D. A. Aguilera, A. Perez, R. Molina, S. Moreno, Appl. Catal. B, 2011, 104, 144-150.