Enhancement of catalytic activity by homo-dispersing S2O82--Fe2O3 nanoparticles on SBA-15 through ultrasonic adsorption

doi:10.1016/S1872-2067(17)63007-9

Abstract

Abstract:

Mesoporous superacids S₂O₈^2--Fe₂O₃/SBA-15 (SFS) with active nanoparticles are prepared by ultrasonic adsorption method. This method is adopted to ensure a homo-dispersed nanoparticle active phase, large specific surface area and many acidic sites. Compared with bulk S₂O₈^2--Fe₂O₃, Brönsted acid catalysts and other reported catalysts, SFS with an Fe₂O₃ loading of 30% (SFS-30) exhibits an outstanding activity in the probe reaction of alcoholysis of styrene oxide by methanol with 100% yield. Moreover, SFS-30 also shows a more excellent catalytic performance than bulk S₂O₈^2--Fe₂O₃ towards the alcoholysis of other ROHs (R=C₂H₅-C₄H₉). Lewis and Brönsted acid sites on the SFS-30 surfaces are confirmed by pyridine adsorbed infrared spectra. The highly efficient catalytic activity of SFS-30 may be attributed to the synergistic effect from the nano-effect of S₂O₈^2--Fe₂O₃ nanoparticles and the mesostructure of SBA-15. Finally, SFS-30 shows a good catalytic reusability, providing an 84.1% yield after seven catalytic cycles.

Key words: Mesoporous superacid, Nanoparticle, Nano effect, S₂O₈^2--Fe₂O₃/SBA-15, Acidic site, Ultrasonic adsorption, Alcoholysis

Qingyan Chu, Jing Chen, Wenhua Hou, Haoxuan Yu, Ping Wang, Rui Liu, Guangliang Song, Hongjun Zhu, Pingping Zhao. Enhancement of catalytic activity by homo-dispersing S₂O₈^2--Fe₂O₃ nanoparticles on SBA-15 through ultrasonic adsorption[J]. Chinese Journal of Catalysis, 2018, 39(5): 955-963.

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References

[1] X. Z. Liang, Chem. Eng. J., 2015, 264, 251-257.
[2] Q. Zhao, S. M. Meng, J. L. Wang, Z. P. Li, J. H. Liu, Y. Guo, Ceram. Int., 2014, 40, 16183-16187.
[3] L. Qin, G. L. Zhang, Z. Fan, Y. J. Wu, X. W. Guo, M. Liu, Chem. Eng. J., 2014, 244, 296-306.
[4] G. D. Yadav, S. B. Kamble, Appl. Catal. A, 2012, 433, 265-274.
[5] Z. K. Zhao, J. F. Ran, Appl. Catal. A, 2015, 503, 77-83.
[6] W. Li, K. B. Chi, H. Liu, H. J. Ma, W. Qu, C. X. Wang, G. Lv, Z. J. Tian, Appl. Catal. A, 2017, 537, 59-65.
[7] Y. Fang, Y. Li, Q. Zhang, X. F. Sun, H. X. Fan, N. Xu, L. Gang, Carbohyd. Polym., 2015, 131, 9-14.
[8] L. Gu, X. Chen, Y. Zhou, Q. L. Zhu, H. F. Huang, H. F. Lu, Chin. J. Catal., 2017, 38, 607-615.
[9] F. H. Alhassan, U. Rashid, Y. H. Taufiq-Yap, Fuel, 2015, 142, 38-45.
[10] H. J. Li, H. L. Song, L. W. Chen, C.G. Xia, Appl. Catal. B, 2015, 165, 466-476.
[11] M. Dastkhoon, M. Ghaedi, A. Asfaram, A. Goudarzi, S. M. Mohammadi, S. B. Wang, Ultrason Sonochem., 2017, 37, 94-105.
[12] R. Y. Li, F. P. Xiao, S. Amirkhanian, Z. P. You, J. Huang, Constr. Build. Mater., 2017, 143, 633-648.
[13] R. R. Retamal Marín, F. Babick, M. Stintz, Powder Technol., 2017, 318, 451-458.
[14] F. Z. El Berrichi, C. Pham-Huu, L. Cherif, B. Louis, M. J. Ledoux, Catal. Commun., 2011, 12, 790-793.
[15] M. Zare, Z. Moradi-Shoeili, F. Ashouri, M. Bagherzadeh, Catal. Commun., 2017, 88, 9-12.
[16] R. J. Kalbasi, M. Kolahdoozan, K. Shahabian, F. Zamani, Catal. Commun., 2010, 11, 1109-1115.
[17] Y. Qin, Z. P. Qu, C. Dong, N. Huang, Chin. J. Catal., 2017, 38, 1603-1612.
[18] H. J. Shen, X. Y. Wu, D. H. Jiang, X. N. Li, J. Ni, Chin. J. Catal., 2017, 38, 1597-1602.
[19] K. N. Tayade, L. Y. Wang, S. S. Shang, W. Dai, M. Mishra, S. Gao, Chin. J. Catal., 2017, 38, 758-766.
[20] Z. C. Miao, H. L. Song, H. H. Zhao, L. L. Xu, L. J. Chou, Catal. Sci. Technol., 2014, 4, 838-850.
[21] O. V. Manoilova, R. Olindo, C. O. Areán, J. A. Lercher, Catal. Com-mun., 2007, 8, 865-870.
[22] P. F. Chen, M. X. Du, H. Lei, Y. Wang, G. L. Zhang, F. B. Zhang, X. B. Fan, Catal. Commun., 2012, 18, 47-50.
[23] J. X. Wang, H. Pan, A. Q. Wang, X. Y. Tian, X. L. Wu, Y. Q. Wang, Catal. Commun., 2015, 62, 29-33.
[24] H. Song, L. L. Zhao, N. Wang, Chin. J. Chem. Eng., 2016, 25, 74-78.
[25] G. P. Fan, M. Shen, Z. Zhang, F. R. Jia, J. Rare Earth, 2009, 27, 437-442.
[26] H. Song, L. L. Zhao, N. Wang, F. Li, Appl. Catal. A, 2016, 526, 37-44.
[27] Y. J. Wu, L. Qin, G. L. Zhang, L. Chen, X. W. Guo, M. Liu, Ind. Eng. Chem. Res., 2013, 52, 16698-16708.
[28] B. B. Chang, J. Fu, Y. L. Tian, X. P. Dong, Appl. Catal. A, 2012, 437, 149-154.
[29] W. J. Ding, W. S. Zhu, J. Xiong, Y. Lei, A. M. Wei, Z. Ming, H. M. Li, Chem. Eng. J., 2015, 266, 213-221.
[30] P. M. Rao, A. Wolfson, S. Kababya, S. Vega, M. V. Landau, J. Catal., 2005, 232, 210-225.
[31] S. C. Laha, P. Mukherjee, S. R. Sainkar, R. Kumar, J. Catal., 2002, 207, 213-223.
[32] S. G. Wang, K. K. Wang, C. Dai, H. Z. Shi, J. L. Li, Chem. Eng. J., 2015, 262, 897-903.
[33] P. Shukla, W. B. Shao, H. Q. Sun, H. M. Ang, M. Tadé, Chem. Eng. J., 2010, 164, 255-260.
[34] K. S. W. Sing, D. H. Ererett, R. A. W. Haul, L. Moscou, R. A. Pierotti, J. Rouquerol, T. Siemieniewska, Pure Appl. Chem., 1985, 57, 603-619.
[35] V. Krishna, G. Naresh, V. V. Kumar, R. Sarkari, A. H. Padmasri, A. Venugopal, Appl. Catal. B, 2016, 193, 58-66.
[36] S. Garg, K. Soni, G. M. Kumaran, R. Bal, K. Gora-Marek, J. K. Gupta, L. D. Sharma, G. Murali Dhar, Catal. Today, 2009, 141, 125-129.
[37] S. A. Taghavi, M. Moghadam, I. Mohammadpoor-Baltork, S. Tangestaninejad, V. Mirkhani, A. R. Khosropour, V. Ahmadi, Polyhedron, 2011, 30, 2244-2252.
[38] Y. H. Kang, X. D. Liu, N. Yan, Y. Jiang, X. Q. Liu, L. B. Sun, J. R. Li, J. Am. Chem. Soc., 2016, 138, 6099-6102.
[39] G. D. Yadav, S. Singh, Tetrahedron Lett., 2014, 55, 3979-3983.
[40] A. Dhakshinamoorthy, M. Alvaro, H. Garcia, Chem. Eur. J., 2010, 16, 8530-8536.
[41] L. H. Zhang, C. H. Hu, W. G. Mei, J. F. Zhang, L. Y. Cheng, N. H. Xue, W. P. Ding, J. Chen, W. H. Hou, Appl. Surf. Sci., 2015, 357, 1951-1957.
[42] S. S. Shinde, M. S. Said, T. B. Surwase, P. Kumar, Tetrahedron Lett., 2015, 56, 5916-5919.

Enhancement of catalytic activity by homo-dispersing S₂O₈^2--Fe₂O₃ nanoparticles on SBA-15 through ultrasonic adsorption

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