Green and efficient epoxidation of methyl oleate over hierarchical TS-1

doi:10.1016/S1872-2067(18)63014-1

Abstract

Abstract:

The epoxidation of methyl oleate (MO) was conducted in the presence of aqueous H₂O₂ as the oxidant and hierarchical TS-1 (HTS-1) as the catalyst; the catalyst was synthesized using polyquaternium-6 as the mesopore template. The effects of various parameters, i.e., H₂O₂/C=C molar ratio, oxidant concentration, amount of the catalyst, reaction temperature, and time, were systematically studied. Furthermore, response surface methodology (RSM) was used to optimize the conditions to maximize the yield of epoxy MO and to evaluate the significance and interplay of the factors affecting the epoxy MO production. The H₂O₂/C=C molar ratio and catalyst amount were the determining factors for MO epoxidation, wherein the maximum yield of epoxy MO reached 94.9% over HTS-1 under the optimal conditions.

Key words: Hierarchical TS-1, Methyl oleate epoxidation, Hydrogen peroxide, Green oxidation, Response surface methodology, Reaction optimization

Yue Wei, Gang Li, Qiang Lü, Chuanying Cheng, Hongchen Guo. Green and efficient epoxidation of methyl oleate over hierarchical TS-1[J]. Chinese Journal of Catalysis, 2018, 39(5): 964-972.

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URL: https://www.cjcatal.com/EN/10.1016/S1872-2067(18)63014-1

https://www.cjcatal.com/EN/Y2018/V39/I5/964

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