Pt supported on octahedral Fe3O4 microcrystals as a catalyst for removal of formaldehyde under ambient conditions

doi:10.1016/S1872-2067(18)63082-7

Abstract

Abstract:

Several catalysts comprising Pt supported on octahedral Fe₃O₄ (Pt/Fe₃O₄) were prepared by a facile method involving co-precipitation followed by thermal treatment at different temperatures. A variety of characterization results revealed that this preparation process afforded highly crystalline octahedral Fe₃O₄ with a uniform distribution of Pt nanoparticles on its surface. The thermal-treatment temperature significantly influenced the redox properties of the Pt/Fe₃O₄ catalysts. All the Pt/Fe₃O₄ catalysts were found to be catalytically active and stable for the oxidation of low-concentration formaldehyde (HCHO) with oxygen. The catalyst prepared by thermal treatment at 80℃ (labelled Pt/Fe₃O₄-80) exhibited the highest catalytic activity, efficiently converting HCHO to CO₂ and H₂O under ambient temperature and moisture conditions. The excellent performance of Pt/Fe₃O₄-80 was mainly attributed to beneficial interactions between the Pt and Fe species that result in the formation a higher density of active interface sites (e.g., Pt-O-FeO_x and Pt-OH-FeO_x). The introduction of water vapor improves the catalytic activity of the Pt/Fe₃O₄ catalysts as it participates in a water-assisted dissociation process.

Key words: Octahedral Fe₃O₄, Pt nanoparticles, Interfacial interaction, Catalytic oxidation, Formaldehyde

Weiyi Cui, Dan Xue, Naidi Tan, Bin Zheng, Mingjun Jia, Wenxiang Zhang. Pt supported on octahedral Fe₃O₄ microcrystals as a catalyst for removal of formaldehyde under ambient conditions[J]. Chinese Journal of Catalysis, 2018, 39(9): 1534-1542.

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URL: https://www.cjcatal.com/EN/10.1016/S1872-2067(18)63082-7

https://www.cjcatal.com/EN/Y2018/V39/I9/1534

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Pt supported on octahedral Fe₃O₄ microcrystals as a catalyst for removal of formaldehyde under ambient conditions

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