Highly active and stable porous polymer heterogenous catalysts for decomposition of formic acid to produce H2

doi:10.1016/S1872-2067(19)63275-4

Chinese Journal of Catalysis ›› 2019, Vol. 40 ›› Issue (2): 147-151.DOI: 10.1016/S1872-2067(19)63275-4

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Highly active and stable porous polymer heterogenous catalysts for decomposition of formic acid to produce H₂

Yan Zhang^a,b, Yuan Lyu^a, Yuqing Wang^a,b, Cunyao Li^a, Miao Jiang^a, Yunjie Ding^a,c

a Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning, China;
b University of Chinese Academy of Sciences, Beijing 100049, China;
c State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning, China

Received:2018-10-08 Revised:2018-12-09 Online:2019-02-28 Published:2019-01-11
Contact: S1872-2067(19)63275-4
Supported by:
This work was supported by the National Key R&D Program of China (2017YFB0602203, 2017YFB0602501), and the Strategic Priority Research Program of the Chinese Academy of Sciences (XDA21020300, XDB17020400).

Abstract

Abstract:

Formic acid (FA) has attracted extensive attention as a hydrogen storage material. Here, we develop two heterogeneous catalysts based on porous organic polymers (POPs). After loading the Ru species, the catalyst bearing the triphenylphosphine ligand showed excellent performance in terms of activity and stability for the decomposition of FA to produce hydrogen.

Key words: Heterogeneous, Porous organic polymer, Formic acid, Decomposition, Hydrogen

Yan Zhang, Yuan Lyu, Yuqing Wang, Cunyao Li, Miao Jiang, Yunjie Ding. Highly active and stable porous polymer heterogenous catalysts for decomposition of formic acid to produce H₂[J]. Chinese Journal of Catalysis, 2019, 40(2): 147-151.

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Highly active and stable porous polymer heterogenous catalysts for decomposition of formic acid to produce H₂

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