Selective oxidation of glycerol with oxygen in base-free solution over N-doped-carbon-supported Sb@PtSb2 hybrid

doi:10.1016/S1872-2067(19)63476-5

Abstract

Abstract: Selective oxidation of glycerol with molecular oxygen in base-free aqueous solutions has become a hot topic, as the rapidly increasing production of biodiesel is creating a surplus of glycerol. In this work, an N-doped-carbon-supported core-shell structured Sb@PtSb₂ hybrid catalyst was prepared via a facile synthesis route, in which a mixture of glucose, melamine, and SbCl₃ (Sb-NC) was pyrolyzed, then impregnated with Pt by immersion in an aqueous solution of H₂PtCl₆, and further treated in hydrogen flow. Characterization of the catalyst products indicated that introducing SbCl₃ can increase the surface area of the binary glucose + melamine pyrolyzed support (NC), and Sb@PtSb₂ hybrids could be formed on the surface of an Sb-NC support during hydrogen treatment at 700℃. It was found that the Sb@PtSb₂/NC catalyst was more active for the selective oxidation of glycerol in a base-free aqueous solution than Sb-free NC-supported Pt (Pt/NC). Further characterization also indicated that the promising performance of Sb@PtSb₂/NC might be attributed to its enhanced oxygen activation.

Key words: Glycerol, Oxidation, Base-free solution, Sb@PtSb₂, Alloy

Lihua Yang, Tianqu He, Chujun Lai, Ping Chen, Zhaoyin Hou. Selective oxidation of glycerol with oxygen in base-free solution over N-doped-carbon-supported Sb@PtSb₂ hybrid[J]. Chinese Journal of Catalysis, 2020, 41(3): 494-502.

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URL: https://www.cjcatal.com/EN/10.1016/S1872-2067(19)63476-5

https://www.cjcatal.com/EN/Y2020/V41/I3/494

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Selective oxidation of glycerol with oxygen in base-free solution over N-doped-carbon-supported Sb@PtSb₂ hybrid

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