Preparation and Hydrodeoxygenation Properties of Ni-Co-W-B Amorphous Catalyst

doi:10.3724/SP.J.1088.2011.10639

Abstract

Abstract: Ni-Co-W-B amorphous catalysts with different Ni/Co ratios were prepared by the chemical reduction method, and their hydrodeoxygenation (HDO) activity was tested using phenol as the model compound. All the fresh catalysts showed an amorphous structure, and the electron transfer between Ni0 and B0 occurred in the Ni-Co-W-B amorphous catalysts. The thermal stability of the amorphous catalyst increased and the Ni0 content decreased with increasing Co content. The HDO of phenol on the Ni-Co-W-B amorphous catalysts proceeded through a hydrogenation-deoxygenation route, and no benzene was found in the products. When the Ni:Co atom ratio in the raw material was 2:1, the Ni-Co-W-B amorphous catalyst showed the highest HDO activity. Under the conditions of temperature 275 oC, hydrogen pressure 4.0 MPa, and reaction time 2 h, the phenol conversion and the deoxygenation rate reached 99.4% and 86.0%, respectively. The HDO activity of the Ni-Co-W-B amorphous catalysts depended on the Ni0 content, the Brönsted acidity, and the catalyst surface area.

Key words: amorphous catalyst, phenol, hydrodeoxygenation, benzene, bio-oil, clean fuel

WANG Wei-Yan, YANG Yun-Quan, LUO He-An, PENG Hui-Zuo- Zhang-Xiao-Zhe, HU Tao. Preparation and Hydrodeoxygenation Properties of Ni-Co-W-B Amorphous Catalyst[J]. Chinese Journal of Catalysis, 2011, 32(10): 1645-1650.

×
share this article

Add to citation manager EndNote|Ris|BibTeX

URL: https://www.cjcatal.com/EN/10.3724/SP.J.1088.2011.10639

https://www.cjcatal.com/EN/Y2011/V32/I10/1645

References

1Serrano-Ruiz J C, Dumesic J A. Energy Environ Sci, 2011, 4: 83
2Yang W, Sen A. ChemSusChem, 2010, 3: 597
3Vispute T P, Zhang H, Sanna A, Xiao R, Huber G W. Science, 2010, 330: 1222
4Huber G W, Iborra S, Corma A. Chem Rev, 2006, 106: 4044
5Zakzeski J, Bruijnincx P C A, Jongerius A L, Weckhuysen B M. Chem Rev, 2010, 110: 3552
6Gandarias I, Barrio V L, Requies J, Arias P L, Cambra J F, Güemez M B. Int J Hydrogen Energy, 2008, 33: 3485
7Furimsky E. Appl Catal A, 2000, 199: 147
8Yang Y, Luo H A, Tong G, Smith K J, Tye C T. Chin J Chem Eng, 2008, 16: 733
9Yang Y, Gilbert A, Xu C. Appl Catal A, 2009, 360: 242
10Romero Y, Richard F, Brunet S. Appl Catal B, 2010, 98: 213
11Ryymin E M, Honkela M L, Viljava T R, Krause A O I. Appl Catal A, 2010, 389: 114
12Whiffen V M L, Smith K J. Energy Fuels, 2010, 24: 4728
13Lin Y C, Li C L, Wan H P, Lee H T, Liu C F. Energy Fuels, 2011, 25: 890
14Dupont C, Lemeur R, Daudin A, Raybaud P. J Catal, 2011, 279: 276
15Bui V N, Laurenti D, Delichère P, Geantet C. Appl Catal B, 2011, 101: 246
16Li K, Wang R, Chen J. Energy Fuels, 2011, 25: 854
17Viljava T R, Komulainen R S, Krause A O I. Catal Today, 2000, 60: 83
18?enol O I, Ryymin E M, Viljava T R, Krause A O I. J Mol Catal A, 2007, 277: 107
19Wang W, Yang Y, Luo H, Hu T, Liu W. Catal Commun, 2011, 12: 436
20Yan N, Yuan Y, Dykeman R, Kou Y, Dyson P J. Angew Chem, Int Ed, 2010, 49: 5549
21Zhao B, Chou C J, Chen Y W. Ind Eng Chem Res, 2010, 49: 1669
22Li H, Zhang D, Li G, Xu Y, Lu Y, Li H. Chem Commun, 2010, 46: 791
23Liu S C, Liu Z, Wang Z, Wu Y, Yuan P. Chem Eng J, 2008, 139: 157
24Li H, Liu J, Xie S, Qiao M, Dai W, Li H. J Catal, 2008, 259: 104
25Pei Y, Guo P, Qiao M, Li H, Wei S, He H, Fan K. J Catal, 2007, 248: 303
26Li H, Yang H, Li H. J Catal, 2007, 251: 233
27武美霞, 李伟, 张明慧, 陶克毅. 物理化学学报 (Wu M X, Li W, Zhang M H, Tao K Y. Acta Phys-Chim Sin), 2011, 27: 953
28孙海杰, 郭伟, 周小莉, 陈志浩, 刘仲毅, 刘寿长. 催化学报 (Sun H J, Guo W, Zhou X L, Chen Zh H, Liu Zh Y, Liu Sh Ch. Chin J Catal), 2011, 32: 1
29闫洪, 李伟, 张明慧, 陶克毅. 催化学报 (Yan H, Li W, Zhang M H, Tao K Y. Chin J Catal), 2009, 30: 89
30张晔, 樊光银, 王磊, 李瑞祥, 陈华, 李贤均. 物理化学学报 (Zhang Y, Fan G Y, Wang L, Li R X, Chen H, Li X J. Acta Phys-Chim Sin), 2009, 25: 2270
31Wang W Y, Yang Y Q, Luo H A, Liu W Y. Catal Commun, 2010, 11: 803
32Wang W Y, Yang Y Q, Bao J G, Luo H A. Catal Commun, 2009, 11: 100
33Leckel D. Energy Fuels, 2007, 22: 231
34Chen L F, Chen Y W. Ind Eng Chem Res, 2006, 45: 8866
35Parks G L, Pease M L, Burns A W, Layman K A, Bussell M E, Wang X, Hanson J, Rodriguez J A. J Catal, 2007, 246: 277
36Li H, Li H, Deng J F. Catal Today, 2002, 74: 53
37Liu Y C, Chen Y W. Ind Eng Chem Res, 2006, 45: 2973
38Li H, Wu Y, Luo H, Wang M, Xu Y. J Catal, 2003, 214: 15
39Li H, Li H, Zhang J, Dai W, Qiao M. J Catal, 2007, 246: 301
40Lin M H, Zhao B, Chen Y W. Ind Eng Chem Res, 2009, 48: 7037
41Patel N, Fernandes R, Miotello A. J Catal, 2010, 271: 315
42Lu G, Li X, Qu Z, Zhao Q, Li H, Shen Y, Chen G. Chem Eng J, 2010, 159: 242
43Wang W, Yang Y, Luo H, Hu T, Liu W. React Kinet, Mechan Catal, 2011, 102: 207
44Li H, Zhang J, Li H. Catal Commun, 2007, 8: 2212
45Shen J H, Chen Y W. J Mol Catal A, 2007, 273: 265
46Suslick K S, Choe S B, Cichowlas A A, Grinstaff M W. Nature, 1991, 353: 414
47Hou Y, Wang Y, He F, Han S, Mi Z, Wu W, Min E. Mater Lett, 2004, 58: 1267
48Wu Z, Zhang M, Ge S, Zhang Z, Li W, Tao K. J Mater Chem, 2005, 15: 4928
49Chen Y W, Sasirekha N, Liu Y C. J Non-Cryst Solids, 2009, 355: 1193
50Li H, Zhao Q, Li H. J Mol Catal A, 2008, 285: 29
51Lu L, Rong Z, Du W, Ma S, Hu S. ChemCatChem, 2009, 1: 369
52Massoth F E, Politzer P, Concha M C, Murray J S, Jakowski J, Simons J. J Phys Chem B, 2006, 110: 14283

[1]	Xiaohan Wang, Han Tian, Xu Yu, Lisong Chen, Xiangzhi Cui, Jianlin Shi. Advances and insights in amorphous electrocatalyst towards water splitting [J]. Chinese Journal of Catalysis, 2023, 51(8): 5-48.
[2]	Mengistu Tulu Gonfa, Sheng Shen, Lang Chen, Biao Hu, Wei Zhou, Zhang-Jun Bai, Chak-Tong Au, Shuang-Feng Yin. Research progress on the heterogeneous photocatalytic selective oxidation of benzene to phenol [J]. Chinese Journal of Catalysis, 2023, 49(6): 16-41.
[3]	Si-Yuan Xia, Qi-Yuan Li, Shi-Nan Zhang, Dong Xu, Xiu Lin, Lu-Han Sun, Jingsan Xu, Jie-Sheng Chen, Guo-Dong Li, Xin-Hao Li. Size-dependent electronic interface effect of Pd nanocube-based heterojunctions on universally boosting phenol hydrogenation reactions [J]. Chinese Journal of Catalysis, 2023, 49(6): 180-187.
[4]	Enara Fernandez, Laura Santamaria, Irati García, Maider Amutio, Maite Artetxe, Gartzen Lopez, Javier Bilbao, Martin Olazar. Elucidating coke formation and evolution in the catalytic steam reforming of biomass pyrolysis volatiles at different fixed bed locations [J]. Chinese Journal of Catalysis, 2023, 48(5): 101-116.
[5]	Yan Zeng, Hui Wang, Huiru Yang, Chao Juan, Dan Li, Xiaodong Wen, Fan Zhang, Ji-Jun Zou, Chong Peng, Changwei Hu. Ni nanoparticle coupled surface oxygen vacancies for efficient synergistic conversion of palmitic acid into alkanes [J]. Chinese Journal of Catalysis, 2023, 47(4): 229-242.
[6]	Qinggang Liu, Junguo Ma, Chen Chen. Rational design and precise manipulation of nano-catalysts [J]. Chinese Journal of Catalysis, 2022, 43(4): 898-912.
[7]	Jun Wan, Weijie Yang, Jiaqing Liu, Kailong Sun, Lin Liu, Feng Fu. Enhancing an internal electric field by a solid solution strategy for steering bulk-charge flow and boosting photocatalytic activity of Bi₂₄O₃₁Cl_xBr_10-_x [J]. Chinese Journal of Catalysis, 2022, 43(2): 485-496.
[8]	Wenjie Tang, Juanrong Chen, Zhengliang Yin, Weichen Sheng, Fengjian Lin, Hui Xu, Shunsheng Cao. Complete removal of phenolic contaminants from bismuth-modified TiO₂ single-crystal photocatalysts [J]. Chinese Journal of Catalysis, 2021, 42(2): 347-355.
[9]	Dongdong Wang, Wanbing Gong, Jifang Zhang, Miaomiao Han, Chun Chen, Yunxia Zhang, Guozhong Wang, Haimin Zhang, Huijun Zhao. Encapsulated Ni-Co alloy nanoparticles as efficient catalyst for hydrodeoxygenation of biomass derivatives in water [J]. Chinese Journal of Catalysis, 2021, 42(11): 2027-2037.
[10]	Yuanyuan Jiang, Ruru Zhou, Huaiyuan Zhao, Boyong Ye, Yihua Long, Zhengbao Wang, Zhaoyin Hou. A highly active and stable organic-inorganic combined solid acid for the transesterification of glycerol under mild conditions [J]. Chinese Journal of Catalysis, 2021, 42(10): 1772-1781.
[11]	Yunqing Liu, Peiyu Xia, Lingyu Li, Xinyue Wang, Jiaqi Meng, Yuxin Yang, Yihang Guo. In-situ route for the graphitized carbon/TiO₂ composite photocatalysts with enhanced removal efficiency to emerging phenolic pollutants [J]. Chinese Journal of Catalysis, 2020, 41(9): 1378-1392.
[12]	Arif Ali, Chen Zhao. Ru nanoparticles supported on hydrophilic mesoporous carbon catalyzed low-temperature hydrodeoxygenation of microalgae oil to alkanes at aqueous-phase [J]. Chinese Journal of Catalysis, 2020, 41(8): 1174-1185.
[13]	Chen Zhao, Zhihua Wang, Xi Chen, Hongyu Chu, Huifen Fu, Chong-Chen Wang. Robust photocatalytic benzene degradation using mesoporous disk-like N-TiO₂ derived from MIL-125(Ti) [J]. Chinese Journal of Catalysis, 2020, 41(8): 1186-1197.
[14]	Jiangyong Liu, Jinxing Li, Rongfei Ye, Xiaodong Yan, Lixia Wang, Panming Jian. Versatile bifunctional nitrogen-doped porous carbon derived from biomass in catalytic reduction of 4-nitrophenol and oxidation of styrene [J]. Chinese Journal of Catalysis, 2020, 41(8): 1217-1229.
[15]	Zhendong Wang, Magdalena O. Cichocka, Yi Luo, Bin Zhang, Hongmin Sun, Yi Tang, Weimin Yang. Controllable direct-syntheses of delaminated MWW-type zeolites [J]. Chinese Journal of Catalysis, 2020, 41(7): 1062-1066.