Preparation and Application of Nanometer Materials Supported Ruthenium Catalysts

doi:10.3724/SP.J.1088.2012.11046

Abstract

Abstract: Ru-based catalysts have many unique properties, especially under mild conditions such as law temperature and pressure. The recent developments of preparation methods and application of nanometer materials supported ruthenium catalysts were reviewed. The effects of support materials, precursors, and ruthenium nanometer particles on the performance of ruthenium catalysts were briefly summarized. Then the new preparation techniques and new progress of traditional preparation techniques were introduced systematically, and the shortages of some methods were discussed. Finally, the important application areas and catalytic performance of Ru-based supported catalysts were discussed. The development trends of Ru-based catalysts were also proposed.

Key words: nanometer material, ruthenium, supported catalyst, preparation method, application

WANG Zi-Qing, ZHANG Liu-Ming, LIN Jian-Xin, WANG Rong, WEI Ke-Mei. Preparation and Application of Nanometer Materials Supported Ruthenium Catalysts[J]. Chinese Journal of Catalysis, 2012, 33(3): 377-388.

References

1 吴松, 熊晓东, 王胜国. 稀有金属 (Wu S, Xiong X D, Wang Sh G. Chin J Rare Metal), 2007, 31: 237
2 Drozdzak R, AlPaert B, Ledoux N, Dragutan I, Dragutan V, Verpoort F. Coord Chem Rev, 2005, 249: 3055
3 石先莹, 韩晓燕, 马文娟, 魏俊发. 有机化学 (Shi X Y, Han X Y, Ma W J, Wei J F. Chin J Org Chem), 2011, 31: 297
4 李蕊琼, 傅尧, 刘磊, 郭庆祥. 有机化学 (Li R Q, Fu Y, Liu L, Guo Q X. Chin J Org Chem), 2004, 24: 1004
5 Hronec M, Cvengrošová Z, Králik M, Palma G, Corain B. J Mol Catal A, 1996, 105: 25
6 党靖雅, 陈凤香, 韩会景, 贺小华, 张以群, 谢美然. 高分子学报 (Dang J Y, Chen F X, Han H J, He X H, Zhang Y Q, Xie M R. Acta Polym Sin), 2008, (4): 342
7 王丽华, 陈守正, 廖代伟, 蔡启瑞. 化学进展 (Wang L H, Chen Sh Zh, Liao D W, Cai Q R. Progr Chem), 1999, 11: 472
8 林炳裕, 王榕, 林建新, 杜书伟, 魏可镁. 化学进展 (Lin B Y, Wang R, Lin J X, Du Sh W, Wei K M. Progr Chem), 2007, 19: 1662
9 张留明, 林建新, 倪军, 林炳裕, 王榕, 魏可镁. 化学进展 (Zhang L M, Lin J X, Ni J, Lin B Y, Wang R, Wei K M. Progr Chem), 2011, 23: 2225
10 代小平, 余长春, 沈师孔. 化学进展 (Dai X P, Yu Ch Ch, Shen Sh K. Progr Chem), 2000, 12: 268
11 王野, 康金灿, 张庆红. 石油化工 (Wang Y, Kang J C, Zhang Q H. Petrochem Technol), 2009, 38: 1255
12 李德宝, 马玉刚, 齐会杰, 李文怀, 孙予罕, 钟炳. 化学进展 (Li D B, Ma Y G, Qi H J, Li W H, Sun Y H, Zhong B. Progr Chem), 2004, 16: 584
13 Kluson P, Cerveny L. Appl Catal A, 1995, 128: 13
14 路芳, 刘菁, 徐杰. 化学进展 (Lu F, Liu J, Xu J. Progr Chem), 2003, 15: 338
15 刘全生, 张前程, 马文平, 何润霞, 寇丽杰, 牟占军. 化学进展 (Liu Q Sh, Zhang Q Ch, Ma W P, He R X, Kou L J, Mou Zh J. Progr Chem), 2005, 17: 389
16 华金铭, 郑起, 林性贻, 魏可镁. 分子催化 (Hua J M, Zheng Q, Lin X Y, Wei K M. J Mol Catal (China)), 2004, 18: 68
17 陈章淼, 陈清林, 刘吉, 纪红兵. 天然气化工 (Chen Zh M, Chen Q L, Liu J, Ji H B. Natur Gas Chem Ind), 2007, 32: 48
18 Haukka M, Venäläinen T, Kallinen M, Pakkanen T A. J Mol Catal A, 1998, 136: 127
19 Murata S, Aika K-I. J Catal, 1992, 136: 110
20 Ragaini V, Carli R, Bianchi C L, Lorenzetti D, Vergani G. Appl Catal A, 1996, 139: 17
21 Lin B Y, Wang R, Lin J X, Ni J, Wei K M. Catal Commun, 2011, 12: 1452
22 Lin B Y, Wang R, Lin J X, Ni J, Wei K M. Catal Lett, 2011, 141: 1557
23 Zhong Z H, Aika K. Inorg Chim Acta, 1998, 280: 183
24 王秀云, 王榕, 倪军, 林建新, 魏可镁. 催化学报 (Wang X Y, Wang R, Ni J, Lin J X, Wei K M. Chin J Catal), 2010, 31: 1452
25 Ni J, Wang R, Lin J X, Wei K M. Catal Lett, 2008, 126: 134
26 倪军, 王榕, 林建新, 魏可镁. 催化学报 (Ni J, Wang R, Lin J X, Wei K M. Chin J Catal), 2009, 30: 185
27 Yin Sh F, Zhang Q H, Xu B Q, Zhu W X, Ng C F, Au C T. J Catal, 2004, 224: 384
28 Yin Sh F, Xu B Q, Zhu W X, Ng C F, Zhou X P, Au C T. Catal Today, 2004, 93-95: 27
29 Yin S F, Xu B Q, Wang S J, Ng C F, Au C T. Catal Lett, 2004, 96: 113
30 Zhang J, Xu H Y, Jin X L, Ge Q J, Li W Zh. Appl Catal A, 2005, 290: 87
31 Ferreira-Aparicio P, Marquez-Alvarez C, Radriguez-Ramos I, Schuurman Y, Guerrero-Ruiz A, Mirodatos C. J Catal, 1999, 184: 202
32 Bradford M C J, Vannice M A. J Catal, 1999, 183: 69
33 Aika K, Takano T, Murata S. J Catal, 1992 ,136: 126
34 Aika K, Ohya A, Ozaki A, Inoue Y, Yasumori I. J Catal, 1985, 92: 305
35 Kowalczyk Z, Sto?ecki K, Raróg-Pilecka W, Mi?kiewicz E, Wilczkowska E, Karpiński Z. Appl Catal A, 2008, 342: 35
36 Yang X L, Zhang W Q, Xia Ch G, Xiong X M, Mu X Y, Hu B. Catal Commun, 2010, 11: 867
37 徐春凤, 欧阳亮, 张佳, 周斌, 李瑛, 刘化章. 催化学报 (Xu Ch F, Ouyang L, Zhang J, Zhou B, Li Y, Liu H Zh. Chin J Catal), 2010, 31: 677
38 Zheng Y, Zheng Y, Li Zh H, Yu H Y, Wang R, Wei K M. J Mol Catal A, 2009, 301: 79
39 Jacobsen C J H, Dahl S, Hansen P L, Törnqvist E, Jensen L, Topsöe H, Prip D V, Möenshaug P B, Chorkendorff I. J Mol Catal A, 2000, 163: 19
40 徐三魁, 王向宇, 梁丽珍. 稀有金属材料与工程 (Xu S K, Wang X Y, Liang L Zh. Rare Metal Mater Eng), 2007, 36: 1063
41 吴跃东, 郭海兵, 万颖, 王明辉, 李和兴. 催化学报 (Wu Y D, Guo H B, Wan Y, Wang M H, Li H X. Chin J Catal), 2004, 25: 533
42 Wu Sh, Chen J X, Zheng X F, Zeng H Sh, Zheng C M, Guan N J. Chem Commun, 2003: 2488
43 Okal J, Zawadzki M, Kepinski L, Krajczyk L, Tylus W. Appl Catal A, 2007, 319: 202
44 Xu Q Ch, Lin J D, Fu X Zh, Liao D W. Catal Commun, 2008, 9: 1214
45 Miyazaki A, Balint I, Aika K, Nakano Y. J Catal, 2001, 204: 364
46 Li X K, Ji W J, Zhao J, Wang Sh J, Au C T. J Catal, 2005, 236: 181
47 Lin B Y, Wang R, Lin J X, Du Sh W, Yu X J, Wei K M. Catal Commun, 2007, 8: 1838
48 许彬彬. [硕士学位论文]. 武汉: 中南民族大学 (Xu B B. [MS Dissertation]. Wuhan: South-Central Univ), 2007
49 Zou Y C, Huang Y M, Li X, Liu H L. Int J Hydrogen En-ergy, 2011, 36: 4315
50 Luo X J, Wang R, Ni J, Lin J X, Lin B Y, Wei K M. Catal Lett, 2009, 133: 382
51 霍超, 夏庆华, 骆燕, 杨霞珍, 刘化章. 催化学报 (Huo Ch, Xiao Q H, Luo Y, Yang X Zh, Liu H Zh. Chin J Catal), 2009, 30: 537
52 霍超, 夏庆华, 杨霞珍, 骆燕, 刘化章. 催化学报 (Huo Ch, Xiao Q H, Yang X Zh, Luo Y, Liu H Zh. Chin J Catal), 2009, 30: 218
53 Zhang L M, Lin J X, Ni J, Wang R, Wei K M. Catal Commun, 2011, 15: 23
54 张留明, 林建新, 王榕, 魏可镁. 物理化学学报 (Zhang L M, Lin J X, Wang R, Wei K M. Acta Phys-Chim Sin), 2011, 27: 2646
55 林建新, 张留明, 倪军, 王榕, 魏可镁. 化学学报 (Lin J X, Zhang L M, Ni J, Wang R, Wei K M. Acta Chim Sin), 2011, accepted and to be published
56 王榕, 魏可镁, 林建新, 俞秀金, 倪军, 林炳裕, 瞿胜, 谢峰, 莫崇望 (Wang R, Wei K M, Lin J X, Yu X J, Ni J, Lin B Y, Qu Sh, Xie F, Mo Ch W). CN 101 362 080. 2009
57 韩文锋, 刘化章, 朱虹, 岑亚青, 柴海芳 (Han W F, Liu H Zh, Zhu H, Cen Y Q, Chai H F). CN 101 053 834. 2007
58 Su F B, Lü L, Lee F Y, Liu T, Cooper A I, Zhao X S. J Am Chem Soc, 2007, 129: 14213
59 Li L, Zhu Z H, Lu G Q, Yan Z F, Qiao S Z. Carbon, 2007, 45: 11
60 朱剑, 付启勇, 杜玉扣, 华南平, 杨平. 燃料化学学报 (Zhu J, Fu Q Y, Du Y K, Hua N P, Yang P. J Fuel Chem Technol), 2010, 38: 230
61 Mendes M J, Santos O A A, Jordão E, Silva A M. Appl Catal A, 2001, 217: 253
62 郭晓勇, 华南平, 杜玉扣, 杨平. 催化学报 (Guo X Y, Hua N P, Du Y K, Yang P. Chin J Catal), 2007, 28: 137
63 Moggi P, Predieri G, Maione A. Catal Lett, 2002, 79: 7
64 Iwamoto J, Itoh M, Kajita Y, Saito M, Machida K I. Catal Commun, 2007, 8: 941
65 霍超, 夏庆华, 潘美华, 杨霞珍, 骆燕, 刘化章. 催化学报 (Huo Ch, Xia Q H, Pan M H, Yang X Zh, Luo Y, Liu H Zh. Chin J Catal), 2011, 32: 315
66 Gheno S M, Damyanova S, Riguetto B A, Marques C M P, Leite C A P, Bueno J M C. J Mol Catal A, 2003, 198: 263
67 Kumar N, Mäki-Arvela P, Hajek J, Salmi T, Murzin D Yu, Heikkilä T, Laine E, Laukkanen P, Vägrynen J. Microporous Mesoporous Mater, 2004, 69: 173
68 周丽梅, 付海燕, 李强, 陈华, 李瑞祥, 李贤均. 催化学报 (Zhou L M, Fu H Y, Li Q, Chen H, Li R X, Li X J. Chin J Catal), 2010, 30: 695
69 Song Zh, Cai T H, Hanson J C, Rodriguez J A, Hrbek J. J Am Chem Soc, 2004, 126: 8576
70 Bielawa H, Hinrichsen O, Birkner A, Muhler M. Angew Chem, Int Ed, 2001, 40: 1061
71 Liang Ch H, Narkhede V, ABmann J, Muhler M. Stud Surf Sci Catal, 2006, 162: 473
72 梁长海. 见: 第十三届全国青年催化学术会议论文集. 昆明 (Liang Ch H. In: The Praceedings of 13th National Youth Conference on Catalysis. Kunming), 2011. 11
73 于凤文, 计建炳, 霍超, 韩文锋, 李小年, 刘化章. 催化学报 (Yu F W, Ji J B, Huo Ch, Han W F, Li X N, Liu H Zh. Chin J Catal), 2005, 26: 485
74 于凤文, 计建炳, 霍超, 韩文锋, 李小年, 刘化章. 催化学报 (Yu F W, Ji J B, Huo Ch, Han W F, Li X N, Liu H Zh. Chin J Catal), 2006, 27: 511
75 霍超, 晏刚, 郑遗凡, 于凤文, 刘化章. 催化学报 (Huo Ch, Yan G, Zheng Y F, Yu F W, Liu H Zh. Chin J Catal), 2007, 28: 484
76 霍超, 张学辉, 夏庆华, 杨霞珍, 骆燕, 刘化章. 催化学报 (Huo Ch, Zhang X H, Xia Q H, Yang X Z, Luo Y, Liu H Zh. Chin J Catal ), 2010, 31: 360
77 Xu Q Ch, Lin J D, Li J, Fu X Zh, Liang Y, Liao D W. Catal Commun , 2007, 8: 1881
78 杨晓敏. [博士学位论文]. 大连: 大连理工大学 (Yang X M. [PhD Dissertation]. Dalian: Dalian Univ Technol), 2010
79 Yang X M, Wang X N, Qiu J Sh. Appl Catal A, 2010, 382: 131
80 Du J Q, Zhang Y, Tian T, Yan Sh Ch, Wang H T. Mater Res Bull, 2009, 44: 1347
81 Su F B, Lee F Y, Lü L, Liu J J, Tian X N, Zhao X S. Adv Funct Mater, 2007, 17: 1926
82 Gao P, Wang A Q, Wang X D, Zhang T. Catal Lett, 2008, 125: 289
83 Ji Zh H, Liang Sh G, Jiang Y B, Li H, Liu Zh M, Zhao T. Carbon, 2009, 47: 2194
84 Wang W, Ran R, Shao Z P. Int J Hydrogen Energy, 2011, 36: 755
85 Li Y, Pan C G, Han W F, Chai H F, Liu H Zh. Catal Today, 2011, 174: 97
86 霍超, 刘化章, 宴刚 (Huo Ch, Liu H Zh, Yan G). CN 101 053 835. 2007
87 Zhong Zh H, Aika K. Chem Commun, 1997: 1223
88 Zhong Zh H, Aika K. J Catal, 1998, 173: 535
89 Rossetti I, Pernicone N, Forni L. Appl Catal A, 2001, 208: 271
90 祝一锋. [博士学位论文]. 杭州: 浙江工业大学 (Zhu Y F. [PhD Dissertation]. Hangzhou: Zhejiang Univ Technol), 2005
91 Balandin A A, Vasyunina N A, Barysheva G S, Chepigo S V. Izv Akad Nauk SSSR, Ser Khim, 1957: 392
92 Sharkov V I. Chem Ing Tech, 1963, 35: 494
93 刘密, 邓卫平, 张庆红, 王野. 见: 第十三届全国青年催化学术会议论文集. 昆明. (Liu M, Deng W P, Zhang Q H, Wang Y. In: The Proceedings of 13th National Youth Con-ference on Catalysis. Kunming), 2011. 100
94 da-Silva J W, Cobo A J G. Appl Catal A, 2003, 252: 9
95 Zonetti P C, Landers R, Cobo A J G. Appl Surf Sci, 2008, 254: 6849
96 Rodrigues M F F, Cobo A J G. Catal Today, 2010, 149: 321
97 Fontana J, Vignado C, Jordão E, Carvalho W A. Chem Eng J, 2010, 165: 336
98 Agnelli M, Kolb M, Mirodatos C. J Catal, 1994, 148: 9
99 Jr Portugal U L, Marques C M P, Araujo E C C, Morales E V, Giotto M V, Bueno J M C. Appl Catal A, 2000, 193: 173
100 Kowalczyk Z, Sto?ecki K, Raróg-Pilecka W, Mi?kiewicz E, Wilczkowska E, Karpiński Z. Appl Catal A, 2008, 342: 35
101 康丽琼. [硕士学位论文]. 天津: 天津大学 (Kang L Q. [MS Dissertation]. Tianjin: Tianjin Univ), 2010
102 Schulz H. Appl Catal A, 1999, 186: 3
103 Simonetti D A, Rass-Hansen J, Kunkes E L, Soares R R, Dumesic J A. Green Chem, 2007, 9: 1073
104 Okabe K, Murata K, Nakanishi M, Ogi T, Nurunnabi M, Liu Y Y. Catal Lett, 2009, 128: 171
105 Murata K, Okaba K, Inabe K,Takahara I, Liu Y Y. Catal Lett, 2009, 128: 343
106 Xiong H F, Zhang Y H, Wang Sh G, Liew K Y, Li J L. J Phys Chem C, 2008, 112: 9706
107 Kang J C, Zhang Sh L, Zhang Q H, Wang Y. Angew Chem, Int Ed, 2009, 48: 2565
108 Zhang Q H, Kang J C, Wang Y. ChemCatChem, 2010, 2: 1030
109 成康, 康金灿, 华卫琦, 楼银川, 张庆红, 王野. 见: 第十三届全国青年催化学术会议论文集. 昆明 (Cheng K, Kang J C, Hua W Q, Lou Y C, Zhang Q H, Wang Y. In: The Proceedings of 13th National Youth Conference on Catalysis. Kunming), 2011. 89
110 Tsubaki N, Sun Sh L, Fujimoto K. J Catal, 2001, 199: 236
111 Iglesia E. Appl Catal A, 1997, 161: 59
112 Li J L, Jacobs G, Zhang Y Q, Das T, Davis B H. Appl Catal A, 2002, 223: 195
113 高海燕, 相宏伟, 李永旺. 催化学报 (Gao H Y, Xiang H W, Li Y W. Chin J Catal), 2010, 31: 307
114 Basińska A, Domka F. Catal Lett, 1993, 17: 327
115 Basińska A, Domka F. Catal Lett, 1993, 22: 327
116 Utaka T, Okanishi T, Takeguchi T, Kikuchi R, Eguchi K. Appl Catal A, 2003, 245: 343
117 Basińska A, Domka F. Catal Lett, 1997, 43: 59
118 Basińska A, Nowacki A, Domka F. React Kinet Catal Lett, 1999, 66: 3
119 Basińska A, Domka F. Appl Catal A, 1999, 179: 241
120 Gatica J M, Chen X W, Zerrad S, Vidal H, Ali A B. Catal Today, 2011, doi:10.1016/j.cattod.2011.05.020
121 Werner S, Szesni N, Bittermann A, Schneider M J, Harter P, Häumann M, Wasserscheid P. Appl Catal A, 2010, 377: 70
122 Kikuchi E, Tanaka S, Yamazaki Y, Morita Y. Bull Jpn Petrol Inst, 1974, 16: 95
123 Crisafulli C, Scirè S, Maggiore R, Minicò S, Galvagno S. Catal Lett, 1999, 59: 21
124 Ashcroft A T, Cheethan A K, Green M K H, Vernon P D F. Nature, 1991, 352: 225
125 Balint I, Miyazaki A, Aika K. J Catal, 2003, 220: 74
126 Muhammad Y, Lu Y Zh, Shen Ch, Li Ch X. Energy Convers Manage, 2011, 52: 1364
127 Brown H C, Brown C A. J Am Chem Soc, 1962, 84: 1493
128 Crisafulli C, Scire S, Salanitri M, Zito R, Calamia S. Int J Hydrogen Energy, 2011, 36: 3817
129 Rachiero G P, Demirci U B , Miele P. Catal Today, 2011, 170: 85
130 Dai H B, Kang X D, Wang P. Int J Hydrogen Energy, 2010, 35: 10317
131 Yin Sh F, Xu B Q, Wang Sh J, Au C T. Appl Catal A, 2006, 301: 202
132 Dutta P K, Vaidyalingam A S. Microporous Mesoporous Mater, 2003, 62: 107
133 Namioka T, Saito A, Inoue Y, Park Y, Min T, Roh S, Yoshikawa K. Appl Energy, 2011, 88: 2019
134 王胜, 高典楠, 张纯希, 袁中山, 张朋, 王树东. 化学进展 (Wang Sh, Gao D N, Zhang Ch X, Yang Zh Sh, Zhang P, Wang Sh D. Progr Chem), 2008, 20: 789
135 Okal J, Zawadzki M. Appl Catal B, 2009, 89: 22
136 Okal J, Zawadzki M. Catal Lett, 2009, 132: 225
137 Okal J, Zawadzki M, Tylus W. Appl Catal B, 2011, 101: 548
138 Mitsui T, Matsui T, Kikuchi R, Eguchi K. Top Catal, 2009, 52: 464
139 Kamiuchi N, Mitsui T, Muroyama H, Matsui T, Kikuchi R, Eguchi K. Appl Catal B, 2010, 97: 120.
140 Wang J B, Zhu W P, Yang Sh X, Wang W, Zhou Y R. Appl Catal B, 2008, 78: 30
141 Beziat J C, Besson M, Gallezot P, Durecu S. Ind Eng Chem Res, 1999, 38: 1310
142 Wang X F, Zeng H C. Appl Catal B, 1998, 17: 89.
143 Wang Y, Jacobi K, Schöne W D, Ertl G. J Phys Chem B, 2005, 109: 7883
144 Li L D, Qu L L, Cheng J, Li J J, Hao Zh P. Appl Catal B, 2009, 88: 224
145 López N, Gomez-Segura J, Marín R P, Perez-Ramírez J. J Catal, 2008, 255: 29
146 Dhakad M, Rayalu S, Subrt J, Bakardjieva S, Mitsuhashi T, Haneda H, Devotta S, Labhsetwar N. Curr Sci, 2007, 92: 1125
147 Aouad S, Saab E, Abi-Aad E, Aboukaïs A. Kinet Catal, 2007, 48: 835
148 Aouad S, Saab E, Abi-Aad E, Aboukaïs A. Catal Today, 2007, 119: 273
149 Aouad S, Abi-Aad E, Aboukaïs A. Appl Catal B, 2009, 88: 249
150 Kobayashi H, Komanoya T, Hara K, Fukuoka A. ChemSusChem, 2010, 3: 440
151 Chang Y F, McCarty J G, Wachsman E D. Appl Catal B, 1995, 6: 21
152 Labhsetwar N, Minamino H, Mukherjee M, Mitsuhashi T, Rayalu S, Dhakad M, Haneda H, Subrt J, Devotta S. J Mol Catal A, 2007, 261: 213

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[13]	Guojun Lan, Yaping Zhou, Hangjia Shen, Haodong Tang, Ying Li. Formation mechanism of highly dispersed semi-embedded ruthenium nanoparticles in porous carbon matrix determined by in situ temperature-programmed infrared spectroscopy [J]. Chinese Journal of Catalysis, 2018, 39(1): 146-156.
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[15]	Li Wang, Hongkai Xie, Xingdan Wang, Guizhen Zhang, Yanglong Guo, Yun Guo, Guanzhong Lu. Preparation of LaMnO₃ for catalytic combustion of vinyl chloride [J]. Chinese Journal of Catalysis, 2017, 38(8): 1406-1412.