1,3,5-Tris(hydrogensulfato) Benzene: A New and Efficient Catalyst for Synthesis of 4,4'-(arylmethylene)bis(1H-pyrazol-5-ol) Derivatives

doi:10.1016/S1872-2067(11)60477-4

Abstract

Abstract: 1,3,5-Tris(hydrogensulfato) benzene (THSB) was easily prepared by the reaction between phloroglucinol and chlorosulfonic acid in dichloromethaneat room temperature. This compound was then used as an efficient catalyst for the synthesis of 4,4'-(arylmethylene)bis(1H-pyrazol-5-ols) through the condensation reactions of 1-phenyl-3-methylpyrazol-5-one with several different aromatic aldehydes in ethanol at 75 °C. The present methodology offers several advantages over existing methodologies, such as excellent yields, simple procedure, easy work-up and ecofriendly reaction conditions.

Key words: 1,3,5-tris(hydrogensulfato) benzene, aromatic aldehydes, 1-phenyl-3-methylpyrazol-5-one, 4,4'-(arylmethylene)bis(1H-pyrazol-5-ols), ethanol, multicomponent reaction

Zahed KARIMI-JABERI, Baharak POOLADIAN, Masoud MORADI, Ehsan GHASEMI. 1,3,5-Tris(hydrogensulfato) Benzene: A New and Efficient Catalyst for Synthesis of 4,4'-(arylmethylene)bis(1H-pyrazol-5-ol) Derivatives[J]. Chinese Journal of Catalysis, 2012, 33(12): 1945-1949.

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