Synthesis of ZSM-5 Zeolite by Vapor-Phase Method and Performance of Its Mo-Based Catalyst for Methane Dehydroaromatization

doi:10.3724/SP.J.1088.2012.20309

Abstract

Abstract: ZSM-5 zeolite was prepared from the amorphous SiO₂:Al₂O₃:TPAOH:Na₂O system in H₂O vapor phase. The obtained samples were characterized by X-ray diffraction, Fourier transform infrared spectroscopy, scanning electron microscopy, etc. Compared with the hydrothermal method, using the vapor-phase method could easily synthesize ZSM-5 zeolite with uniform particle size. The particle size was between 150 and 250 nm. It also showed a better catalytic performance with CH₄ conversion as high as 17.5% and better life time.

Key words: vapor-phase method, ZSM-5 zeolite, methane, molybdenum-based catalyst, dehydroaromatization

WANG Di-Yong, WANG Jin-Qu, YANG Jian-Hua, LU Jin-Ming, YIN De-Hong, ZHANG Yan. Synthesis of ZSM-5 Zeolite by Vapor-Phase Method and Performance of Its Mo-Based Catalyst for Methane Dehydroaromatization[J]. Chinese Journal of Catalysis, 2012, 33(8): 1383-1388.

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