Highly Efficient Synthesis of Methyl Ethyl Ketone Oxime through Ammoximation over Ti-MOR Catalyst

doi:10.3724/SP.J.1088.2013.20860

Abstract

Abstract: The liquid-phase ammoximation of methyl ethyl ketone (MEK) to methyl ethyl ketone oxime (MEKO) with ammonia and hydrogen peroxide was conducted over MOR-type titanosilicate (Ti-MOR), which was prepared from highly dealuminated mordenite and TiCl₄ vapor by a secondary method of gas-solid phase reaction. The effects of reaction parameters on this reaction were studied systematically in a bath-type reactor. Based on the optimized reaction conditions, Ti-MOR was further employed as the catalyst for the ammoximation of MEK to MEKO in a continuous slurry reactor. This catalyst exhibited good catalytic activity and excellent MEKO selectivity in comparison to TS-1. Moreover, in terms of ketone conversion, oxime selectivity, coke resistance, and lifetime, Ti-MOR possessed the same advantages as the Ti-MWW catalyst prepared by structural rearrangement.

Key words: Ti-MOR zeolite, Ti-MWW zeolite, titanosilicate, liquid-phase ammoximation, methyl ethyl ketone, methyl ethyl ketone oxime

DING Jiang-Hong, XU Le, XU Hao, WU Hai-Hong, LIU Yue-Ming, WU Peng. Highly Efficient Synthesis of Methyl Ethyl Ketone Oxime through Ammoximation over Ti-MOR Catalyst[J]. Chinese Journal of Catalysis, 2013, 34(1): 243-250.

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