Ordered mesoporous manganese oxide as catalyst for hydrogen peroxide oxidation of norfloxacin in water

doi:10.1016/S1872-2067(11)60492-0

Chinese Journal of Catalysis

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Ordered mesoporous manganese oxide as catalyst for hydrogen peroxide oxidation of norfloxacin in water

SUI Minghao, SHE Lei, SHENG Li, WEI Jinjie, ZHANG Lingdian, HUANG Shuhang

State Key Laboratory of Pollution Control and Resource Reuse, School of Environmental Science and Engineering, Tongji University, Shanghai 200092, China

Received:2012-08-31 Revised:2012-11-22 Online:2013-04-02 Published:2013-04-03
Supported by:
This work was supported by the National Natural Science Foundation of China (50708067, 51078281, 51278351), Foundation for the Author of National Excellent Doctoral Dissertation of China (2007B48), the National Science and Technology Major Project (2012ZX07408001), and the Fundamental Research Funds for the Central Universities (0400219192).

Abstract

Abstract:

Ordered mesoporous manganese oxide (om-MnO_x) was prepared and used in oxidation by hydrogen peroxide of norfloxacin (NFX). The om-MnO_x was prepared using a hard template method. The catalytic activity of om-MnO_x was investigated by evaluating the changes in degradation efficiency and antibacterial activity of NFX. om-MnO_x exhibited significant catalytic activity for the degradation of NFX in water by hydrogen peroxide. Lower pH conditions favored the catalytic activity of om-MnO_x/hydrogen peroxide. The presence of om-MnO_x achieved a greater reduction in the antibacterial ability of NFX than that was obtained with hydrogen peroxide alone. The inhibiting effect of t-butanol indicated that om-MnO_x enhanced the generation of hydroxyl radicals. Byproducts from NFX were detected during the om-MnO_x-catalyzed hydrogen peroxide process, and possible reaction pathways were proposed.

Key words: Ordered mesoporous material, Manganese oxide, Hydrogen peroxide, Oxidation, Norfloxacin

SUI Minghao, SHE Lei, SHENG Li, WEI Jinjie, ZHANG Lingdian, HUANG Shuhang. Ordered mesoporous manganese oxide as catalyst for hydrogen peroxide oxidation of norfloxacin in water[J]. Chinese Journal of Catalysis, DOI: 10.1016/S1872-2067(11)60492-0.

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Ordered mesoporous manganese oxide as catalyst for hydrogen peroxide oxidation of norfloxacin in water

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