Phosphorus Ligand Modified Rh/SiO2 Catalyst for Hydroformylation of Methyl-3-pentenoate

Chinese Journal of Catalysis ›› 2008, Vol. 29 ›› Issue (12): 1193-1195.

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Phosphorus Ligand Modified Rh/SiO2 Catalyst for Hydroformylation of Methyl-3-pentenoate

LI Xianming1,3, DING Yunjie1,2*, JIAO Guiping1,3, LI Jingwei1,3, YAN Li1, ZHU Hejun1

1 Dalian Institute of Chemical Physics, The Chinese Academy of Sciences, Dalian 116023, Liaoning, China; 2 State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, The Chinese Academy of Sciences, Dalian 116023, Liaoning, China; 3 Graduate University of Chinese Academy of Sciences, Beijing 100049, China

Received:2008-12-25 Online:2008-12-25 Published:2012-09-20

Abstract

Abstract: A phosphorus ligand-modified Rh/SiO2 catalyst (L-Rh/SiO2) has been develop ed for hydroformylation of internal olefins to linear aldehydes. This catalyst h as high activity and regioselectivity and can be separated easily by filtratio n after reaction in an autoclave. Moreover, the electronic and steric effects of phosphorus ligands on the catalytic performance of the L-Rh/SiO2 catalyst ha ve been investigated.

Key words: hydroformylation, heterogeneous catalyst, internal olefin, electronic effect, steric effect

LI Xianming;DING Yunjie;*;JIAO Guiping;LI Jingwei;YAN Li;ZHU Hejun. Phosphorus Ligand Modified Rh/SiO2 Catalyst for Hydroformylation of Methyl-3-pentenoate[J]. Chinese Journal of Catalysis, 2008, 29(12): 1193-1195.

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Phosphorus Ligand Modified Rh/SiO2 Catalyst for Hydroformylation of Methyl-3-pentenoate

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