Low Temperature CO Oxidation on Ni-Promoted CuO-CeO2 Catalysts

doi:10.1016/S1872-2067(11)60468-3

Abstract

Abstract: A series of Ce₂₀Cu₅Ni_yO_x catalysts for CO oxidation at low temperature were prepared and characterized by N₂ adsorption, X-ray diffraction, temperature-program reduction by H₂, X-ray photoelectron spectroscopy (XPS), and Raman spectroscopy. Ce₂₀Cu₅Ni_0.4O_x exhibited the highest catalytic activity. The addition of NiO increased the amount of copper ions doped into the CeO₂ matrix and gave more oxygen vacancies in ceria by the formation of a Ni-O-Ce solid solution. XPS results showed that large quantities of Cu⁺, Ce³⁺, and lattice oxygenexisted in the fresh Ce₂₀Cu₅Ni_0.4O_xcatalyst. Cu⁺ ions in the catalyst can easily migrate to the ceria lattice to form a Cu-O-Ce solid solution, which enhanced the release of the lattice oxygen of the oxides under a reducing atmosphere. The high catalytic activity of Ce₂₀Cu₅Ni_0.4O_xis due to the promoter giving increased amounts of Cu⁺ in the catalyst and the formation of solid solutions of both Cu-O-Ce and Ni-O-Ce.

Key words: copper, cerium, carbon monoxide, oxidation, nickel, solid solution

CHEN Guo-Xing, LI Qiao-Ling, WEI Yu-Cai, FANG Wei-Ping, YANG Yi-Quan. Low Temperature CO Oxidation on Ni-Promoted CuO-CeO2 Catalysts[J]. Chinese Journal of Catalysis, 2013, 34(2): 322-329.

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URL: https://www.cjcatal.com/EN/10.1016/S1872-2067(11)60468-3

https://www.cjcatal.com/EN/Y2013/V34/I2/322

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