Effects of composite oxide supports on catalytic performance of Ni-based catalysts for CO methanation

doi:10.1016/S1872-2067(11)60485-3

Abstract

Abstract: Metal-oxide-modified NiO/Al₂O₃ catalysts for methanation of CO were prepared using a modified grinding-mixing method and characterized using X-ray diffraction, transmission electron microscopy, N₂ adsorption-desorption isotherms, temperature-programmed reduction by H₂, temperature-programmed desorption by H₂, Raman spectroscopy, and X-ray photoelectron spectroscopy. The results show that the activity of an MgO-modified NiO/Al₂O₃ catalyst is better than those of NiO/ZrO₂-Al₂O₃ and NiO/SiO₂-Al₂O₃ in the reaction temperature range 300–700 °C. The incorporation of a metal oxide into NiO/Al₂O₃ was found to weaken Ni–Al interactions, leading to generation of large numbers of active Ni species, and this was confirmed to be responsible for the improvement in the performances of the catalysts in the methanation reaction.

Key words: carbon monoxide, methanation, nickel-based catalyst, syngas, mixed oxide support

ZHANG Han, DONG Yun-Yun, FANG Wei-Ping, LIAN Yi-Xin. Effects of composite oxide supports on catalytic performance of Ni-based catalysts for CO methanation[J]. Chinese Journal of Catalysis, 2013, 34(2): 330-335.

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URL: https://www.cjcatal.com/EN/10.1016/S1872-2067(11)60485-3

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