Selective hydrogenation of benzene to cyclohexene over nanocomposite Ru-Mn/ZrO2 catalysts

doi:10.1016/S1872-2067(11)60489-0

Abstract

Abstract:

A series of Ru-Mn catalysts with different Mn contents were prepared by coprecipitation, and their catalytic performance, using nanoscale ZrO₂ as a dispersant, for the selective hydrogenation of benzene to cyclohexene was investigated. The catalysts were characterized using X-ray diffraction, transmission electron microscopy, N₂ physisorption, X-ray fluorescence, atomic absorption spectroscopy, and Auger electron spectroscopy. The results confirmed that the Mn existed as Mn₃O₄ on the Ru surface. The Mn₃O₄ reacted with ZnSO₄ to form an insoluble [Zn(OH)₂]₃(ZnSO₄)(H₂O)₃ salt, which was readily chemisorbed on the Ru surface. This chemisorbed salt played a key role in improving the cyclohexene selectivity over the Ru catalyst. The cyclohexene yield of 61.3% was obtained over the Ru-Mn catalyst with the optimum Mn content of 5.4%. This catalyst had good stability and excellent reusability.

Key words: Benzene, Selective hydrogenation, Cyclohexene, Ruthenium, Manganese, Zirconia, Zinc

SUN Haijie, JIANG Houbing, LI Shuaihui, WANG Hongxia, PAN Yajie, DONG Yingying, LIU Shouchang, LIU Zhongyi. Selective hydrogenation of benzene to cyclohexene over nanocomposite Ru-Mn/ZrO₂ catalysts[J]. Chinese Journal of Catalysis, 2013, 34(4): 684-694.

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URL: https://www.cjcatal.com/EN/10.1016/S1872-2067(11)60489-0

https://www.cjcatal.com/EN/Y2013/V34/I4/684

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Selective hydrogenation of benzene to cyclohexene over nanocomposite Ru-Mn/ZrO₂ catalysts

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