Catalytic performance of different types of iron zeolites in N2O decomposition

doi:10.1016/S1872-2067(12)60555-5

Abstract

Abstract:

A series of Fe/zeolites (ZSM-35, ZSM-5, beta, and mordenite) samples with Fe/Al molar ratios of 0.33 were prepared using a solid-state ion-exchange method. A combination of ultraviolet-visible diffuse reflectance, in-situ Fourier-transform infrared, and in-situ visible Raman spectroscopic techniques, with a transient response method, was used to investigate the influence of the zeolite framework on the catalytic properties of the Fe/zeolites in N₂O decomposition. The results show that the catalytic activity of the Fe/zeolites-HT (HT denotes high-temperature treatment) samples is in the order Fe/ZSM-35-HT > Fe/beta-HT > Fe/ZSM-5-HT > Fe/mordenite-HT. There is a linear relationship between the rate of N₂O decomposition and the concentration of binuclear iron sites. This indicates that binuclear iron sites are the active sites for N₂O decomposition. A correlation between the formation of binuclear iron sites and Fe ion distribution among the cationic sites is proposed. Two Fe(II) cations located in two adjacent six-membered rings in a 10-membered ring channel (α sites) or in two neighboring six-membered rings in an eight-membered ring channel (β sites) of Fe/ZSM-35 are favorable for the formation of active binuclear iron sites. Similar structure can also be formed in two adjacent six-membered rings in polymorphs A and B of beta zeolite or in the six-membered rings at the intersection of the straight and sinusoidal channels of the ZSM-5 framework. For the Fe/mordenite-HT sample, most of the iron species are present as isolated iron cations, so it has the lowest activity in N₂O decomposition.

Key words: Iron, Zeolite, Nitrous oxide decomposition, Raman spectroscopy

WANG Junying, XIA Haian, JU Xiaohua, FAN Fengtao, FENG Zhaochi, LI Can. Catalytic performance of different types of iron zeolites in N₂O decomposition[J]. Chinese Journal of Catalysis, 2013, 34(5): 876-888.

×
share this article

Add to citation manager EndNote|Ris|BibTeX

URL: https://www.cjcatal.com/EN/10.1016/S1872-2067(12)60555-5

https://www.cjcatal.com/EN/Y2013/V34/I5/876

References

[1] Pérez-Ramírez J, Kapteijn F, Schöffel K, Moulijn J A. Appl Catal B, 2003, 44: 117

[2] Pérez-Ramírez J, Kapteijn F, Mul G, Xu X, Moulijn J A. Catal Today, 2002, 76: 55

[3] Parmon V N, Panov G I, Uriarte A, Noskov A S. Catal Today, 2005, 100: 115

[4] Hansen N, Heyden A, Bell A T, Keil F J. J Catal, 2007, 248: 213

[5] Pirngruber G D, Roy P K, Prins R. J Catal, 2007, 246: 147

[6] Roy P K, Prins R, Pirngruber G D. Appl Catal B, 2008, 80: 226

[7] ?ygarden A H, Pérez-Ramírez J. Appl Catal B, 2006, 65: 163

[8] Kaucký D, Sobalík Z, Schwarze M, Vondrová A, Wichterlová B. J Catal, 2006, 238: 293

[9] Jíša K, Nováková J, Schwarze M, Vondrová A, Sklenák S, Sobalik Z. J Catal, 2009, 262: 27

[10] Sklenák S, Andrikopoulos P C, Boekfa B, Jansang B, Nováková J, Benco L, Bucko T, Hafner J, D?de?ek J, Sobalík Z. J Catal, 2010, 272: 262

[11] Pantu P, Boekfa B, Sunpetch B, Limtrakul J. Chem Eng Commun, 2008, 195: 1477

[12] Pérez-Ramírez J, Groen J C, Brückner A, Kumar M S, Bentrup U, Debbagh M N, Villaescusa L A. J Catal, 2005, 232: 318

[13] Melián-Cabrera I, Mentruit C, Pieterse J A Z, van den Brink R W, Mul G, Kapteijn F, Moulijn J A. Catal Commun, 2005, 6: 301

[14] Xia H A, Sun K Q, Fan F T, Sun K J, Su W G, Feng Zh Ch, Ying P L, Li C. J Catal, 2008, 259: 269

[15] D?de?ek J, Kaucký D, Wichterlová B. Microporous Mesoporous Mater, 2000, 35-36: 483

[16] Sobalík Z, D?de?ek J, Kaucký D, Wichterlová B, Drozdová L, Prins R. J Catal, 2000, 194: 330

[17] D?de?ek J, ?apek L, Kaucký D, Sobalík Z, Wichterlová B. J Catal, 2002, 211: 198

[18] Drozdová L, Prins R, D?de?ek J, Sobalík Z, Wichterlová B. J Phys Chem B, 2002, 106: 2240

[19] D?de?ek J, Wichterlová B. J Phys Chem B, 1999, 103: 1462

[20] Attfield M P, Weigel S J, Cheetham A K. J Catal, 1997, 170: 227

[21] Dalconi M C, Cruciani G, Alberti A, Ciambelli P, Rapacciuolo M T. Microporous Mesoporous Mater, 2000, 39: 423

[22] Sun K Q, Xia H A, Feng Zh Ch, van Santen R, Hensen E J M, Li C. J Catal, 2008, 254: 383

[23] Wang J Y, Li G N, Ju X H, Xia H A, Fan F T, Wang J H, Feng Zh Ch, Li C. J Catal, 2013, 301: 77

[24] Kumar M S, Schwidder M, Grünert W, Brückner A. J Catal, 2004, 227: 384

[25] Pérez-Ramírez J. J Catal, 2004, 227: 512

[26] Pérez-Ramírez J, Kumar M S, Brückner A. J Catal, 2004, 223: 13

[27] Pérez-Ramírez J, Mul G, Kapteijn F, Moulijn J A, Overweg A R, Doménech A, Ribera A, Arends I W C E. J Catal, 2002, 207: 113

[28] Bordiga S, Buzzoni R, Geobaldo F, Lamberti C, Giamello E, Zecchina A, Leofanti G, Petrini G, Tozzola G, Vlaic G. J Catal, 1996, 158: 486

[29] Hadjiivanov K, Ivanova E, Kefirov R, Janas J, Plesniar A, Dzwigaj S, Che M. Microporous Mesoporous Mater, 2010, 131: 1

[30] Hensen E J M, Zhu Q, van Santen R A. J Catal, 2003, 220: 260

[31] Long J L, Zhang Z Zh, Ding Zh X, Ruan R Sh, Li Zh H, Wang X X. J Phys Chem C, 2010, 114: 15713

[32] Lobree L J, Hwang I-C, Reimer J A, Bell A T. Catal Lett, 1999, 63: 233

[33] Yuranov I, Bulushev D A, Renken A, Kiwi-Minsker L. Appl Catal A, 2007, 319: 128

[34] Xia H A, Sun K Q, Sun K J, Feng Zh Ch, Li W X, Li C. J Phys Chem C, 2008, 112: 9001

[35] Li C, Xiong G, Xin Q, Liu J K, Ying P L, Feng Zh Ch, Li J, Yang W B, Wang Y Zh, Wang G R, Liu X Y, Lin M, Wang X Q, Min E Z. Angew Chem, Int Ed, 1999, 38: 2220

[36] Fan F T, Xu Q, Xia H A, Sun K J, Feng Zh Ch, Li C. Chin J Catal (范峰滔, 徐倩, 夏海岸, 孙科举, 冯兆池, 李灿. 催化学报), 2009, 30: 717

[37] Nosheen S, Galasso F, Suib S L. Sci Adv Mater, 2009, 1: 31

[38] Twu J, Dutta P K, Kresge C T. J Phys Chem, 1991, 95: 5267

[39] Dutta P K, Rao K M, Park J Y. J Phys Chem, 1991, 95: 6654

[40] Fan F T, Feng Zh Ch, Li C. Acc Chem Res, 2010, 43: 378

[41] Yu Y, Xiong G, Li C, Xiao F-Sh. Microporous Mesoporous Mater, 2001, 46: 23

[42] de Faria D L A, Venaüncio Silva S, de Oliveira M T. J Raman Spectrosc, 1997, 28: 873

[43] Tosheva L, Mihailova B, Valtchev V, Sterte J. Microporous Mesoporous Mater, 2001, 48: 31

[44] Lewandowska A E, Banares M A, Tielens F, Che M, Dzwigaj S. J Phys Chem C, 2010, 114: 19771

[45] Dutta P K, Rao K M, Park J Y. Langmuir, 1992, 8: 722

[46] Suzuki Y, Wakihara T, Itabashi K, Ogura M, Okubo T. Top Catal, 2009, 52: 67

[47] Mihailova B, Valtchev V, Mintova S, Faust A-C, Petkov N, Bein T. Phys Chem Chem Phys, 2005, 7: 2756

[48] Majano G, Mintova S, Ovsitser O, Mihailova B, Bein T. Microporous Mesoporous Mater, 2005, 80: 227

[49] Fan F T, Sun K J, Feng Zh Ch, Xia H A, Han B, Lian Y X, Ying P L, Li C. Chem Eur J, 2009, 15: 3268

[50] D?dec?k J, Kaucký D, Wichterlová B. Top Catal, 2002, 18: 283

[51] Kaucký D, Vondrová A, D?dec?k J, Wichterlová B. J Catal, 2000, 194: 318

[52] Kapteijn F, Rodriguez-Mirasol J, Moulijn J A. Appl Catal B, 1996, 9: 25

[53] D?dec?k J, Kaucký D, Wichterlová B, Gonsiorová O. Phys Chem Chem Phys, 2002, 4: 5406

Catalytic performance of different types of iron zeolites in N₂O decomposition

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

[1]	Lu Cheng, Xuning Chen, P. Hu, Xiao-Ming Cao. Advantages and limitations of hydrogen peroxide for direct oxidation of methane to methanol at mono-copper active sites in Cu-exchanged zeolites [J]. Chinese Journal of Catalysis, 2023, 51(8): 135-144.
[2]	Liyuan Gong, Ying Wang, Jie Liu, Xian Wang, Yang Li, Shuai Hou, Zhijian Wu, Zhao Jin, Changpeng Liu, Wei Xing, Junjie Ge. Reshaping the coordination and electronic structure of single atom sites on the right branch of ORR volcano plot [J]. Chinese Journal of Catalysis, 2023, 50(7): 352-360.
[3]	Keshia Saradima Indriadi, Peijie Han, Shipeng Ding, Bingqing Yao, Shinya Furukawa, Qian He, Ning Yan. Highly dispersed Pt boosts active Fe_xN formation in ammonia decomposition [J]. Chinese Journal of Catalysis, 2023, 50(7): 297-305.
[4]	Jianxin Feng, Xuan Li, Yucheng Luo, Zhifang Su, Maoling Zhong, Baolan Yu, Jianying Shi. Microenvironment regulation of Ru(bda)L₂ catalyst incorporated in metal-organic framework for effective photo-driven water oxidation [J]. Chinese Journal of Catalysis, 2023, 48(5): 127-136.
[5]	Changcheng Wei, Wenna Zhang, Kuo Yang, Xiu Bai, Shutao Xu, Jinzhe Li, Zhongmin Liu. An efficient way to use CO₂ as chemical feedstock by coupling with alkanes [J]. Chinese Journal of Catalysis, 2023, 47(4): 138-149.
[6]	Han-Jun Ai, Fengqian Zhao, Xiao-Feng Wu. SET or TET? Iron-catalyzed aminocarbonylation of unactivated alkyl halides with amines, amides, and indoles via a substrate dependent mechanism [J]. Chinese Journal of Catalysis, 2023, 47(4): 121-128.
[7]	Duozheng Ma, Xiangcheng Li, Chuang Liu, Caroline Versluis, Yingchun Ye, Zhendong Wang, Eelco T. C. Vogt, Bert M. Weckhuysen, Weimin Yang. SCM-36 zeolite nanosheets applied in the production of renewable p-xylene from ethylene and 2,5-dimethylfuran [J]. Chinese Journal of Catalysis, 2023, 47(4): 200-213.
[8]	Runze Liu, Xue Shao, Chang Wang, Weili Dai, Naijia Guan. Reaction mechanism of methanol-to-hydrocarbons conversion: Fundamental and application [J]. Chinese Journal of Catalysis, 2023, 47(4): 67-92.
[9]	Long Jiao, Hai-Long Jiang. Metal-organic frameworks for catalysis: Fundamentals and future prospects [J]. Chinese Journal of Catalysis, 2023, 45(2): 1-5.
[10]	Longkang Zhang, Yue Ma, Changcheng Liu, Zhipeng Wan, Chengwei Zhai, Xin Wang, Hao Xu, Yejun Guan, Peng Wu. Demetallation and reduction induced ultra-dispersed PtZn alloy confined in zeolite for propane dehydrogenation [J]. Chinese Journal of Catalysis, 2023, 55(12): 241-252.
[11]	Peerapol Pornsetmetakul, Ferdy J. A. G. Coumans, Rim C. J. van de Poll, Anna Liutkova, Duangkamon Suttipat, Brahim Mezari, Chularat Wattanakit, Emiel J. M. Hensen. Post-synthesis metal (Sn, Zr, Hf) modification of BEA zeolite: Combined Lewis and Brønsted acidity for cascade catalysis [J]. Chinese Journal of Catalysis, 2023, 55(12): 200-215.
[12]	Yuxuan Lu, Liu Yang, Yimin Jiang, Zhenran Yuan, Shuangyin Wang, Yuqin Zou. Engineering a localized electrostatic environment to enhance hydroxyl activating for electrocatalytic biomass conversion [J]. Chinese Journal of Catalysis, 2023, 53(10): 153-160.
[13]	Shenyu Shen, Qingfeng Guo, Tiantian Wu, Yaqiong Su. The dynamic behaviors of heterogeneous interfaces in electrocatalytic CO₂ reduction [J]. Chinese Journal of Catalysis, 2023, 53(10): 52-71.
[14]	Qixian Xie, Dan Ren, Lichen Bai, Rile Ge, Wenhui Zhou, Lu Bai, Wei Xie, Junhu Wang, Michael Grätzel, Jingshan Luo. Investigation of nickel iron layered double hydroxide for water oxidation in different pH electrolytes [J]. Chinese Journal of Catalysis, 2023, 44(1): 127-138.
[15]	Xue Bai, Zhiyao Duan, Bing Nan, Liming Wang, Tianmi Tang, Jingqi Guan. Unveiling the active sites of ultrathin Co-Fe layered double hydroxides for the oxygen evolution reaction [J]. Chinese Journal of Catalysis, 2022, 43(8): 2240-2248.