Silica gel-supported TEMPO with adsorbed NOx for selective oxidation of alcohols under mild conditions

doi:10.1016/S1872-2067(12)60657-3

Abstract

Abstract:

A column padding silica gel was used to support 2,2,6,6-tetramethylpiperdine-1-oxyl (TEMPO) and to adsorb NO_x to provide an oxidant system for the selective oxidation of alcohols. A wide range of alcohols were oxidized to the corresponding aldehydes and ketones with high selectivities and conversions using this heterogeneous catalyst under mild conditions.

Key words: Silica, 2,2,6,6-tetramethylpiperdine-1-oxyl, Nitrogen oxide, Heterogeneous catalysis, Alcohol oxidation

Hua Zhang, Luoling Fu, Hongmin Zhong. Silica gel-supported TEMPO with adsorbed NO_x for selective oxidation of alcohols under mild conditions[J]. Chinese Journal of Catalysis, 2013, 34(10): 1848-1854.

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Silica gel-supported TEMPO with adsorbed NO_x for selective oxidation of alcohols under mild conditions

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