Synergistic effect on Au-Pd bimetallic catalyst during oxidation of benzyl alcohol to sodium benzoate

doi:10.1016/S1872-2067(14)60159-5

Abstract

Abstract:

A series of AuPd/CeO₂ bimetallic catalysts with different Au/Pd molar ratios were investigated and their catalytic performance in the oxidation of benzyl alcohol to sodium benzoate and benzoic acid under solvent-free conditions was studied. The supported catalysts were characterized by X-ray diffraction, UV-Vis diffuse reflectance spectroscopy, transmission electron microscopy, and X-ray photoelectron spectroscopy. The Au-Pd nanoparticles were successfully deposited onto CeO₂ as a homogeneous alloy. The activity of the bimetallic catalysts was superior to that of the corresponding monometallic catalysts. This improvement was attributed to the synergistic effect between Au and Pd. The catalyst with an Au/Pd molar ratio of 3/1 showed the best catalytic performance (the yield of benzoic acid reached 92%), and it could be easily recovered and reused for more than seven successive reactions without significant loss of activity.

Key words: Gold, Palladium, Ceria, Bimetallic catalyst, Benzyl alcohol, Catalytic oxidation, Benzoate

Zhaoyan Zhang, Ying Wang, Xian Li, Wei-Lin Dai. Synergistic effect on Au-Pd bimetallic catalyst during oxidation of benzyl alcohol to sodium benzoate[J]. Chinese Journal of Catalysis, 2014, 35(11): 1846-1857.

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URL: https://www.cjcatal.com/EN/10.1016/S1872-2067(14)60159-5

https://www.cjcatal.com/EN/Y2014/V35/I11/1846

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