Selective hydrogenation of phenol to cyclohexanone in water over Pd catalysts supported on Amberlyst-45

doi:10.1016/S1872-2067(15)60997-4

Abstract

Abstract:

A series of Pd catalysts were prepared on different supports (Fe₂O₃, SiO₂, ZnO, MgO, Al₂O₃, carbon, and Amberlyst-45) and used in the selective hydrogenation of phenol to cyclohexanone in water. The Amberlyst-45 supported Pd catalyst (Pd/A-45) was highly active and selective under mild conditions (40-100℃, 0.2-1 MPa), giving a selectivity of cyclohexanone higher than 89% even at complete conversion of phenol. Experiments with different Pd loadings (or different particle sizes) confirmed that the formation of cyclohexanone was a structure sensitive reaction, and Pd particles of 12-14 nm on Amberlyst-45 gave better selectivity and stability.

Key words: Phenol, Hydrogenation, Cyclohexanone, Palladium, Amberlyst-45 resin, Supported catalyst

Mengsi Zhao, Juanjuan Shi, Zhaoyin Hou. Selective hydrogenation of phenol to cyclohexanone in water over Pd catalysts supported on Amberlyst-45[J]. Chinese Journal of Catalysis, 2016, 37(2): 234-239.

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URL: https://www.cjcatal.com/EN/10.1016/S1872-2067(15)60997-4

https://www.cjcatal.com/EN/Y2016/V37/I2/234

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