Efficient production of 5-hydroxymethylfurfural from hexoses using solid acid SO42-/In2O3-ATP in a biphasic system

doi:10.1016/S1872-2067(15)61096-8

Chinese Journal of Catalysis ›› 2016, Vol. 37 ›› Issue (8): 1362-1368.DOI: 10.1016/S1872-2067(15)61096-8

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Efficient production of 5-hydroxymethylfurfural from hexoses using solid acid SO₄^2-/In₂O₃-ATP in a biphasic system

Yue Shen^a, Yuru Kang^b, Jiankui Sun^a, Chao Wang^a, Bo Wang^a, Feng Xu^a, Runcang Sun^a

a. Beijing Key Laboratory of Lignocellulosic Chemistry, College of Materials Science and Technology, Beijing Forestry University, Beijing 100083, China;
b. Xuyi R&D Center for Application of Attapulgite Clay, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, Gansu, China

Received:2016-02-19 Revised:2016-03-25 Online:2016-07-29 Published:2016-08-01
Contact: Bo Wang, Runcang Sun
Supported by:
This work was supported by the Fundamental Research Funds for the Central Universities (TD2011-11, BLYJ201519), Beijing Higher Education Young Elite Teacher Project (YETP0765), National Natural Science Foundation of China (31170556), New Century Excellent Talents in University (NCET-13-0671), and State Forestry Administration of China (201204803).

Abstract

Abstract:

A natural attapulgite (ATP)-based catalyst, sulfated In₂O₃-ATP (SO₄^2-/In₂O₃-ATP), was obtained by an impregnation-calcination method and was used to efficiently and selectively produce the useful platform chemical 5-hydroxymethylfurfural (HMF) from hexoses. Some important reaction parameters were studied, revealing that Lewis and Brönsted acid sites on SO₄^2-/In₂O₃-ATP catalyze glucose isomerization and fructose dehydration. The yields of HMF from glucose and fructose were 40.2% and 46.2%, respectively, using the optimal conditions of 180 ℃ for 60 min with 10 wt% of solid acid catalyst in a mixture of γ-valerolactone-water (9:1).

Key words: Solid acid catalyst, Attapulgite, 5-Hydroxylmethylfurfural, Biphasic system, Fructose dehydration, Glucose isomerization

Yue Shen, Yuru Kang, Jiankui Sun, Chao Wang, Bo Wang, Feng Xu, Runcang Sun. Efficient production of 5-hydroxymethylfurfural from hexoses using solid acid SO₄^2-/In₂O₃-ATP in a biphasic system[J]. Chinese Journal of Catalysis, 2016, 37(8): 1362-1368.

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Efficient production of 5-hydroxymethylfurfural from hexoses using solid acid SO₄^2-/In₂O₃-ATP in a biphasic system

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