Aqueous asymmetric aldol reaction catalyzed by nanomagnetic solid acid SO42-/Zr(OH)4-Fe3O4

doi:10.1016/S1872-2067(14)60222-9

Abstract

Abstract:

Magnetic solid acid catalysts SO₄^2-/Zr(OH)₄-Fe₃O₄ were prepared using magnetic Fe₃O₄ nanoparticles, ZrOCl₂·8H₂O, and sulfuric acid as starting materials in the calcination temperature range 110-650 ℃. The properties of the magnetic solid acid, such as loaded SO₄^2- content, acid distribution, surface morphology, and porous structure, were characterized. In the aqueous asymmetric aldol reaction of various benzaldehydes with strong electron-withdrawing groups (R=NO₂ and CN), good to excellent catalytic performance (83%-100% yield, 86.0%-95.6% ee anti, and anti/syn=88-96/12-4) was achieved. These nanomagnetic solid acids can be quantitatively recycled from the reaction mixture using an external magnet and reused five times without significant loss of catalytic activity.

Key words: Solid acid catalyst, Magnetism, Aldol reaction, Asymmetric catalysis, Aqueous phase

Tao Wu, Jingwei Wan, Xuebing Ma . Aqueous asymmetric aldol reaction catalyzed by nanomagnetic solid acid SO₄^2-/Zr(OH)₄-Fe₃O₄[J]. Chinese Journal of Catalysis, 2015, 36(3): 425-431.

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Aqueous asymmetric aldol reaction catalyzed by nanomagnetic solid acid SO₄^2-/Zr(OH)₄-Fe₃O₄

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