Conversion of glycerol to acrolein by mesoporous sulfated zirconia-silica catalyst

doi:10.1016/S1872-2067(16)62564-0

Chinese Journal of Catalysis ›› 2017, Vol. 38 ›› Issue (3): 420-425.DOI: 10.1016/S1872-2067(16)62564-0

• Special Column on New Porous Catalytic Materials • Previous Articles Next Articles

Conversion of glycerol to acrolein by mesoporous sulfated zirconia-silica catalyst

Hirokazu Kobayashi^a, Shogo Ito^a,b, Kenji Hara^c, Atsushi Fukuoka^a

a Institute for Catalysis, Hokkaido University, Kita 21 Nishi 10, Kita-ku, Sapporo, Hokkaido 001-0021, Japan;
b Graduate School of Chemical Sciences and Engineering, Hokkaido University, Kita 13 Nishi 8, Kita-ku, Sapporo, Hokkaido 060-8628, Japan;
c School of Engineering, Tokyo University of Technology, Hachioji, Tokyo 192-0982, Japan

Received:2016-07-27 Revised:2016-09-05 Online:2017-03-18 Published:2017-03-22
Supported by:
This work was supported by Grant-in-Aid for Research Activity Start-up (KAKENHI, 21860004) and for Young Scientists (KAKENHI, 26709060) from Japan Society for the Promotion of Science (JSPS).

Abstract

Abstract:

A mesoporous sulfated zirconia-silica catalyst bearing only Brønsted acid sites converted glycerol to acrolein in 81% yield with 82% selectivity. Space time yield as high as 9.0 mmol h^-1 g_cat^-1 was achieved even at a low reaction temperature of 523 K. The catalytic activity and selectivity were higher than those of typical sulfated zirconia. It is proposed that the milder acidity due to dilution of zirconium species by silica and large pore size for faster diffusion contributed towards the better catalytic performance.

Key words: Acrolein, Glycerol, Mesopore, Sulfated zirconia

Hirokazu Kobayashi, Shogo Ito, Kenji Hara, Atsushi Fukuoka. Conversion of glycerol to acrolein by mesoporous sulfated zirconia-silica catalyst[J]. Chinese Journal of Catalysis, 2017, 38(3): 420-425.

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Conversion of glycerol to acrolein by mesoporous sulfated zirconia-silica catalyst

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