Rhodium (III)-catalyzed selective access to isoindolinones via formal[4+1]annulation of arylamides and propargyl alcohols

Abstract

Abstract:

A mild and efficient oxidative synthesis of isoindolinones has been realized by Rh(Ⅲ)-catalyzed C-H activation of benzamides and[4 + 1] coupling with propargyl alcohols. This coupling system proceeds with broad substrate scope and mild conditions and provides a new approach to access the useful skeleton of γ-lactams with a stereogenic center.

Key words: Rhodium, C-H activation, [4+1]annulation, Propargyl alcohol, Isoindolinones

Youwei Xu, Fen Wang, Songjie Yu, Xingwei Li. Rhodium (III)-catalyzed selective access to isoindolinones via formal[4+1]annulation of arylamides and propargyl alcohols[J]. Chinese Journal of Catalysis, 2017, 38(8): 1390-1398.

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