Support effect of the supported ceria-based catalysts during NH3-SCR reaction

Chinese Journal of Catalysis ›› 2017, Vol. 38 ›› Issue (8): 1423-1430.

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Support effect of the supported ceria-based catalysts during NH₃-SCR reaction

Xiaojiang Yao^a,b,c, Li Chen^c,d, Tingting Kong^a,c, Shimin Ding^a, Qiong Luo^c, Fumo Yang^a,b,c,d

a Collaborative Innovation Center for Green Development in Wuling Mountain Areas, Yangtze Normal University, Chongqing 408100, China;
b Center for Excellence in Regional Atmospheric Environment, Institute of Urban Environment, Chinese Academy of Sciences, Xiamen 361021, Fujian, China;
c Research Center for Atmospheric Environment, Chongqing Institute of Green and Intelligent Technology, Chinese Academy of Sciences, Chongqing 400714, China;
d School of Urban Construction and Environmental Engineering, Chongqing University, Chongqing 400045, China

Received:2017-05-15 Revised:2017-06-07 Online:2017-08-18 Published:2017-08-04
Supported by:
This work was supported by the National Natural Science Foundation of China (21507130), the Chongqing Science and Technology Commission (cstc2016jcyjA0070, cstc2014pt-gc20002, cstc2014yykfC20003, cstckjcxljrc13), and the Open Project Program of Chongqing Key Laboratory of Catalysis and Functional Organic Molecules from Chongqing Technology and Business University (1456029).

Abstract

Abstract:

To investigate how the physicochemical properties and NH₃-selective catalytic reduction (NH₃-SCR) performance of supported ceria-based catalysts are influenced as a function of support type, a series of CeO₂/SiO₂, CeO₂/γ-Al₂O₃, CeO₂/ZrO₂, and CeO₂/TiO₂ catalysts were prepared. The physicochemical properties were probed by means of X-ray diffraction, Raman spectroscopy, Brunauer-Emmett-Teller surface area measurements, X-ray photoelectron spectroscopy, H₂-temperature programmed reduction, and NH₃-temperature programmed desorption. Furthermore, the supported ceria-based catalysts' catalytic performance and H₂O + SO₂ tolerance were evaluated by the NH₃-SCR model reaction. The results indicate that out of the supported ceria-based catalysts studied, the CeO₂/γ-Al₂O₃ catalyst exhibits the highest catalytic activity as a result of having a high relative Ce³⁺/Ce⁴⁺ ratio, optimum reduction behavior, and the largest total acid site concentration. Finally, the CeO₂/γ-Al₂O₃ catalyst also presents excellent H₂O + SO₂ tolerance during the NH₃-SCR process.

Key words: Support effect, Supported ceria-based catalyst, Reduction behavior, Surface acidity, Ammonia-selective catalytic reduction

Xiaojiang Yao, Li Chen, Tingting Kong, Shimin Ding, Qiong Luo, Fumo Yang. Support effect of the supported ceria-based catalysts during NH₃-SCR reaction[J]. Chinese Journal of Catalysis, 2017, 38(8): 1423-1430.

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References

[1] J. X. Chen, Y. X. Chen, M. J. Zhou, Z. W. Huang, J. Y. Gao, Z. Ma, J. M. Chen, X. F. Tang, Environ. Sci. Technol., 2017, 51, 473-478.
[2] C. Paolucci, A. A. Verma, S. A. Bates, V. F. Kispersky, J. T. Miller, R. Gounder, W. N. Delgass, F. H. Ribeiro, W. F. Schneider, Angew. Chem. Int. Ed., 2014, 53, 11828-11833.
[3] X. J. Yao, K. L. Ma, W. X. Zou, S. G. He, J. B. An, F. M. Yang, L. Dong, Chin. J. Catal., 2017, 38, 146-159.
[4] C. X. Liu, L. Chen, J. H. Li, L. Ma, H. Arandiyan, Y. Du, J. Y. Xu, J. M. Hao, Environ. Sci. Technol., 2012, 46, 6182-6189.
[5] X. J. Yao, T. T. Kong, S. H. Yu, L. L. Li, F. M. Yang, L. Dong, Appl. Surf. Sci., 2017, 402, 208-217.
[6] S. T. Choo, Y. G. Lee, I. S. Nam, S. W. Ham, J. B. Lee, Appl. Catal. A, 2000, 200, 177-188.
[7] Y. Peng, W. Z. Si, X. Li, J. J. Chen, J. H. Li, J. Crittenden, J. M. Hao, Environ. Sci. Technol., 2016, 50, 9576-9582.
[8] X. J. Yao, L. Zhang, L. L. Li, L. C. Liu, Y. Cao, X. Dong, F. Gao, Y. Deng, C. J. Tang, Z. Chen, L. Dong, Y. Chen, Appl. Catal. B, 2014, 150-151, 315-329.
[9] X. Li, J. H. Li, Y. Peng, H. Z. Chang, T. Zhang, S. Zhao, W. Z. Si, J. M. Hao, Appl. Catal. B, 2016, 184, 246-257.
[10] B. Li, Z. Y. Ren, Z. X. Ma, X. D. Huang, F. Liu, X. B. Zhang, H. S. Yang, Catal. Sci. Technol., 2016, 6, 1719-1725.
[11] L. J. Yan, Y. Y. Liu, H. Hu, H. R. Li, L. Y. Shi, D. S. Zhang, Chem-CatChem, 2016, 8, 2267-2278.
[12] W. P. Shan, F. D. Liu, Y. B. Yu, H. He, Chin. J. Catal., 2014, 35, 1251-1259.
[13] Z. M. Liu, Y. X. Liu, B. H. Chen, T. L. Zhu, L. L. Ma, Catal. Sci. Technol., 2016, 6, 6688-6696.
[14] P. W. Selwood, Adv. Catal., 1951, 2, 27-106.
[15] X. J. Yao, F. Gao, L. Dong, Chin. J. Catal., 2013, 34, 1975-1985.
[16] L. Dong, X. J. Yao, Y. Chen, Chin. J. Catal., 2013, 34, 851-864.
[17] S. M. Lee, K. H. Park, S. C. Hong, Chem. Eng. J., 2012, 195-196, 323-331.
[18] P. Maitarad, J. Han, D. Zhang, L. Shi, S. Namuangruk, T. Rungrotmongkol, J. Phys. Chem. C, 2014, 118, 9612-9620.
[19] G. Busca, L. Lietti, G. Ramis, F. Berti, Appl. Catal. B, 1998, 18, 1-36.
[20] X. J. Yao, R. D. Zhao, L. Chen, J. Du, C. Y. Tao, F. M. Yang, L. Dong, Appl. Catal. B, 2017, 208, 82-93.
[21] J. H. Li, H. Z. Chang, L. Ma, J. M. Hao, R. T. Yang, Catal. Today, 2011, 175, 147-156.
[22] H. Huang, Q. G. Dai, X. Y. Wang, Appl. Catal. B, 2014, 158-159, 96-105.
[23] X. J. Yao, C. J. Tang, Z. Y. Ji, Y. Dai, Y. Cao, F. Gao, L. Dong, Y. Chen, Catal. Sci. Technol., 2013, 3, 688-698.
[24] M. J. Li, Z. C. Feng, G. Xiong, P. L. Ying, Q. Xin, C. Li, J. Phys. Chem. B, 2001, 105, 8107-8111.
[25] Q. Yu, X. J. Yao, H. L. Zhang, F. Gao, L. Dong, Appl. Catal. A., 2012, 423-424, 42-51.
[26] M. Aslam, M. T. Qamar, M. T. Soomro, I. M. I. Ismail, N. Salah, T. Almeelbi, M. A. Gondal, A. Hameed, Appl. Catal. B, 2016, 180, 391-402.
[27] C. A. Chagas, E. F. de Souza, R. L. Manfro, S. M. Landi, M. M. V. M. Souza, M. Schmal, Appl. Catal. B, 2016, 182, 257-265.
[28] H. Huang, Y. F. Gu, J. Zhao, X. Y. Wang, J. Catal., 2015, 326, 54-68.
[29] D. Li, Q. Yu, S. S. Li, H. Q. Wan, L. J. Liu, L. Qi, B. Liu, F. Gao, L. Dong, Y. Chen, Chem. Eur. J., 2011, 17, 5668-5679.
[30] X. J. Yao, Y. Xiong, W. X. Zou, L. Zhang, S. G. Wu, X. Dong, F. Gao, Y. Deng, C. J. Tang, Z. Chen, L. Dong, Y. Chen, Appl. Catal. B, 2014, 144, 152-165.
[31] L. J. Liu, Y. Cao, W. J. Sun, Z. J. Yao, B. Liu, F. Gao, L. Dong, Catal. Today, 2011, 175, 48-54.
[32] C. Fang, D. S. Zhang, S. X. Cai, L. Zhang, L. Huang, H. R. Li, P. Maitarad, L. Y. Shi, R. H. Gao, J. P. Zhang, Nanoscale, 2013, 5, 9199-9207.
[33] W. S. Hu, Y. H. Zhang, S. J. Liu, C. H. Zheng, X. Gao, I. Nova, E. Tron-coni, Appl. Catal. B., 2017, 206, 449-460.
[34] S. Han, Q. Ye, S. Y. Cheng, T. F. Kang, H. X. Dai, Catal. Sci. Technol., 2017, 7, 703-717.

Support effect of the supported ceria-based catalysts during NH₃-SCR reaction

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