Nature of active phase of VOx catalysts supported on SiBeta for direct dehydrogenation of propane to propylene

doi:10.1016/S1872-2067(19)63444-3

Abstract

Abstract: The VO_x catalysts supported on dealuminated Beta zeolite (SiBeta) with varying V loadings (from 0.5 to 10 wt%) are prepared and tested for their catalytic activities in the reaction of direct dehydrogenation of propane to propylene (PDH). It is characterized that the VSiBeta catalysts possess different kinds of vanadium species on the SiBeta support, including monomeric or isolated VO_x species at a low V loading, and polynuclear VO_x species in different polymerization degrees at higher V loadings. The 3VSiBeta catalyst (V loading is 3 wt%), containing isolated VO_x species in monolayer, shows around 40% of propane conversion with 90% of propylene selectivity (reaction conditions:600 ℃, 4000 mL g^-1 h^-1) which are comparable to VSiBeta catalysts with higher V loadings. The catalytic activity exhibits a good linear relationship with the amount of generated acidic sites, which are derived from the interaction sites between VO_x species and SiBeta support, and keeps stable after several regeneration cycles. Thus, as the VO_x species directly contact with SiBeta support via V-O-Si bonds, a reactivity enhancement can be achieved. While, the initial valence state of V does not seem to influence the catalytic performance. Moreover, the aggregation degree of VO_x species determines the propylene selectivity and deactivation rate, both of which increase as raising the V loading amount.

Key words: Propane dehydrogenation, Propylene, VO_x species, SiBeta support, Active sites

Chong Chen, Minglei Sun, Zhongpan Hu, Yuping Liu, Shoumin Zhang, Zhong-Yong Yuan. Nature of active phase of VO_x catalysts supported on SiBeta for direct dehydrogenation of propane to propylene[J]. Chinese Journal of Catalysis, 2020, 41(2): 276-285.

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URL: https://www.cjcatal.com/EN/10.1016/S1872-2067(19)63444-3

https://www.cjcatal.com/EN/Y2020/V41/I2/276

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Nature of active phase of VO_x catalysts supported on SiBeta for direct dehydrogenation of propane to propylene

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