C(sp2)-H/O-H cross-dehydrogenative coupling of quinoxalin-2(1H)-ones with alcohols under visible-light photoredox catalysis

doi:10.1016/S1872-2067(19)63526-6

Abstract

Abstract: An efficient and practical route to various 3-alkoxylquinoxalin-2(1H)-ones through visible-light photocatalytic C(sp²)-H/O-H cross-dehydrogenation coupling of quinoxalin-2(1H)-ones and alcohols, employing ambient air as an oxidant at room temperature under metal-free conditions, was developed.

Key words: Quinoxalin-2(1H)-ones, Alcohols, Visible-light photoredox catalysis, Cross-dehydrogenative coupling, Metal free reaction

Long-Yong Xie, Yi-Shu Liu, Hong-Ru Ding, Shao-Feng Gong, Jia-Xi Tan, Jun-Yi He, Zhong Cao, Wei-Min He. C(sp²)-H/O-H cross-dehydrogenative coupling of quinoxalin-2(1H)-ones with alcohols under visible-light photoredox catalysis[J]. Chinese Journal of Catalysis, 2020, 41(8): 1168-1173.

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URL: https://www.cjcatal.com/EN/10.1016/S1872-2067(19)63526-6

https://www.cjcatal.com/EN/Y2020/V41/I8/1168

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C(sp²)-H/O-H cross-dehydrogenative coupling of quinoxalin-2(1H)-ones with alcohols under visible-light photoredox catalysis

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