Sodium-treated sepiolite-supported transition metal (Cu, Fe, Ni, Mn, or Co) catalysts for HCHO oxidation

doi:10.1016/S1872-2067(20)63599-9

Abstract

Abstract: Sodium-treated sepiolite (NaSep)-supported transition metal catalysts (TM/NaSep; TM=Cu, Fe, Ni, Mn, and Co) were synthesized via a rotary evaporation method. Physicochemical properties of the as-synthesized samples were characterized by means of various techniques, and their catalytic activities for HCHO (0.2%) oxidation were evaluated. Among the samples, Cu/NaSep exhibited superior performance, and complete HCHO conversion was achieved at 100℃ (GHSV=240000 mL/(g·h)). Additionally, the sample retained good catalytic activity during a 42 h stability test. A number of factors, including elevated acidity, the abundance of oxygen species, and favorable low-temperature reducibility, were responsible for the excellent catalytic activity of Cu/NaSep. According to the results of the in-situ DRIFTS characterization, the HCHO oxidation mechanism was as follows:(i) HCHO was rapidly decomposed into dioxymethylene (DOM) species on the Cu/NaSep surface; (ii) DOM was then immediately converted to formate species; (iii) the resultant formate species were further oxidized to carbonates; (iv) the carbonate species were eventually converted to CO₂ and H₂O.

Key words: Sodium-treated sepiolite, Transition metal loading, Supported transition metal catalyst, Volatile organic compound, HCHO oxidation

Ning Dong, Qing Ye, Mengyue Chen, Shuiyuan Cheng, Tianfang Kang, Hongxing Dai. Sodium-treated sepiolite-supported transition metal (Cu, Fe, Ni, Mn, or Co) catalysts for HCHO oxidation[J]. Chinese Journal of Catalysis, 2020, 41(11): 1734-1744.

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https://www.cjcatal.com/EN/Y2020/V41/I11/1734

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