AgAuPd/meso-Co3O4:High-performance catalysts for methanol oxidation

doi:10.1016/S1872-2067(18)63205-X

Abstract

Abstract:

The meso-Co₃O₄ and Ag_xAu_yPd/meso-Co₃O₄ catalysts were prepared using the KIT-6-templating and polyvinyl alcohol-protected NaBH₄ reduction methods, respectively. Various techniques were used to characterize physicochemical properties of these materials. Catalytic performance of the samples was evaluated for methanol combustion. The cubically crystallized Co₃O₄ support displayed a three-dimensionally ordered mesoporous structure. The supported noble metal nanoparticles (NPs) possessed a surface area of 115-125 m²/g, with the noble NPs (average size=2.8-4.5 nm) being uniformly dispersed on the surface of meso-Co₃O₄. Among all of the samples, 0.68 wt% Ag_0.75Au_1.14Pd/meso-Co₃O₄ showed the highest catalytic activity (T_50%=100℃ and T_90% =112℃ at a space velocity of 80000 mL (g^-1 h^-1). The partial deactivation of the 0.68 wt% Ag_0.75Au_1.14Pd/meso-Co₃O₄ sample due to water vapor or carbon dioxide introduction was reversible. It is concluded that the good catalytic performance of 0.68 wt% Ag_0.75Au_1.14Pd/meso-Co₃O₄ was associated with its highly dispersed Ag_0.75Au_1.14Pd alloy NPs, high adsorbed oxygen species concentration, good low-temperature reducibility, and strong interaction between Ag_0.75Au_1.14Pd alloy NPs and meso-Co₃O₄.

Key words: Volatile organic compound, Mesoporous cobalt oxide, Supported noble metal catalyst, AgAuPd alloy nanoparticle, Methanol oxidation

Jun Yang, Yuxi Liu, Jiguang Deng, Xingtian Zhao, Kunfeng Zhang, Zhuo Han, Hongxing Dai. AgAuPd/meso-Co₃O₄:High-performance catalysts for methanol oxidation[J]. Chinese Journal of Catalysis, 2019, 40(6): 837-848.

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URL: https://www.cjcatal.com/EN/10.1016/S1872-2067(18)63205-X

https://www.cjcatal.com/EN/Y2019/V40/I6/837

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AgAuPd/meso-Co₃O₄:High-performance catalysts for methanol oxidation

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