A Zeolite Imidazolate Framework ZIF-8 Catalyst for Friedel-Crafts Acylation

doi:10.1016/S1872-2067(11)60368-9

摘要/Abstract

摘要： A zeolite imidazolate framework, ZIF-8, was synthesized and characterized by dynamic laser light scattering, X-ray powder diffraction, scanning electron microscopy, transmission electron microscopy, thermogravimetric analysis, Fourier transform infrared, atomic absorption spectrophotometry, and nitrogen adsorption measurements. The ZIF-8 was highly crystalline and porous with a surface area of over 1600 m²/g. Friedel-Crafts acylation of anisole and benzoyl chloride proceeded well in the presence of ZIF-8 (2–6 mol%) without the need for an inert atmosphere. The reaction afforded a selectivity of 93%–95% to the p-isomer. The solid catalyst can be separated from the reaction mixture by simple centrifugation and reused without significant degradation in catalytic activity. There was no leaching of active acid species into the reaction solution.

关键词: imidazolate framework, zeolite imidazolate framework ZIF-8, Friedel-Crafts acylation, porous material, catalysis

Abstract: A zeolite imidazolate framework, ZIF-8, was synthesized and characterized by dynamic laser light scattering, X-ray powder diffraction, scanning electron microscopy, transmission electron microscopy, thermogravimetric analysis, Fourier transform infrared, atomic absorption spectrophotometry, and nitrogen adsorption measurements. The ZIF-8 was highly crystalline and porous with a surface area of over 1600 m²/g. Friedel-Crafts acylation of anisole and benzoyl chloride proceeded well in the presence of ZIF-8 (2–6 mol%) without the need for an inert atmosphere. The reaction afforded a selectivity of 93%–95% to the p-isomer. The solid catalyst can be separated from the reaction mixture by simple centrifugation and reused without significant degradation in catalytic activity. There was no leaching of active acid species into the reaction solution.

Key words: imidazolate framework, zeolite imidazolate framework ZIF-8, Friedel-Crafts acylation, porous material, catalysis

Lien T. L. NGUYEN, Ky K. A. LE, Nam T. S. PHAN*. A Zeolite Imidazolate Framework ZIF-8 Catalyst for Friedel-Crafts Acylation[J]. 催化学报, 2012, 33(4): 688-696.

Lien T. L. NGUYEN, Ky K. A. LE, Nam T. S. PHAN*. A Zeolite Imidazolate Framework ZIF-8 Catalyst for Friedel-Crafts Acylation[J]. Chinese Journal of Catalysis, 2012, 33(4): 688-696.

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