Cerium (IV) sulfate：A highly efficient reusable heterogeneous catalyst for the one-pot synthesis of 2,3-dihydroquinazolin-4(1H)-ones under solvent-free conditions

doi:10.1016/S1872-2067(14)60041-3

催化学报 ›› 2014, Vol. 35 ›› Issue (7): 1054-1058.DOI: 10.1016/S1872-2067(14)60041-3

Cerium (IV) sulfate：A highly efficient reusable heterogeneous catalyst for the one-pot synthesis of 2,3-dihydroquinazolin-4(1H)-ones under solvent-free conditions

Abolghasem Davoodnia, Maryam Khashi, Niloofar Tavakoli-Hoseini

Department of Chemistry, Mashhad Branch, Islamic Azad University, Mashhad, Iran

收稿日期:2013-12-07 修回日期:2014-01-20 出版日期:2014-06-28 发布日期:2014-06-28
通讯作者: Abolghasem Davoodnia
基金资助:
This work was supported by Islamic Azad University, Mashhad Branch as research project (92429/302/64).

Cerium (IV) sulfate：A highly efficient reusable heterogeneous catalyst for the one-pot synthesis of 2,3-dihydroquinazolin-4(1H)-ones under solvent-free conditions

Abolghasem Davoodnia, Maryam Khashi, Niloofar Tavakoli-Hoseini

Department of Chemistry, Mashhad Branch, Islamic Azad University, Mashhad, Iran

Received:2013-12-07 Revised:2014-01-20 Online:2014-06-28 Published:2014-06-28
Supported by:
This work was supported by Islamic Azad University, Mashhad Branch as research project (92429/302/64).

摘要/Abstract

摘要：

Cerium (IV) sulfate tetrahydrate, Ce(SO₄)₂·4H₂O, is a novel inorganic solid acidic catalyst that efficiently catalyzes the synthesis of 2,3-dihydroquinazolin-4(1H)-ones via the one-pot three-component reaction of isatoic anhydride, aromatic aldehydes, and a nitrogen source (ammonium acetate, ammonium carbonate, ammonium chloride, or methylamine) under solvent-free conditions. The desired products are obtained in short reaction time with high yields. The catalyst is inexpensive and readily available and can be recovered conveniently and reused such that considerable catalytic activity can still be achieved after the fifth run. Easy work-up and avoiding the use of harmful organic solvents are other advantages of this simple procedure.

关键词: Cerium (IV) sulfate, 2,3-Dihydroquinazolin-4(1H)-ones, Heterogeneous catalysis, Solvent-free conditions

Abstract:

Key words: Cerium (IV) sulfate, 2,3-Dihydroquinazolin-4(1H)-ones, Heterogeneous catalysis, Solvent-free conditions

Abolghasem Davoodnia, Maryam Khashi, Niloofar Tavakoli-Hoseini. Cerium (IV) sulfate：A highly efficient reusable heterogeneous catalyst for the one-pot synthesis of 2,3-dihydroquinazolin-4(1H)-ones under solvent-free conditions[J]. 催化学报, 2014, 35(7): 1054-1058.

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Cerium (IV) sulfate：A highly efficient reusable heterogeneous catalyst for the one-pot synthesis of 2,3-dihydroquinazolin-4(1H)-ones under solvent-free conditions

Cerium (IV) sulfate：A highly efficient reusable heterogeneous catalyst for the one-pot synthesis of 2,3-dihydroquinazolin-4(1H)-ones under solvent-free conditions

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