Nano Silica with High Surface Area from Rice Husk as a Support for 12-Tungstophosphoric Acid: An Efficient Nano Catalyst in Some Organic Reactions

doi:10.1016/S1872-2067(11)60420-8

摘要/Abstract

摘要： Nano silica was prepared from rice husk with high surface area. X-ray diffraction (XRD) pattern showed that the amorphous form of silica was produced. Chemical composition of the nano silica was estimated by X-ray fluorescence spectroscopy and CHN analysis. The nano silica was used as a support for H₃PW₁₂O₄₀. The nano silica and nano silica supported H₃PW₁₂O₄₀were characterized by inductively coupled plasma, XRD, transmission electron microscopy (TEM), N₂ adsorption-desorption, and Fourier transform infrared spectroscopy. TEM images of nano silica as well as the supported catalyst displayed average size of 6 and 7 nm, respectively. The catalyst showed excellent activity in some important organic reactions including Biginelli, Hantzsch, Mannich, and Claisen-Schmidt reactions with good reusability. Catalytic activity of this nano catalyst is an improvement over the commercially available silica that is used to support H₃PW₁₂O₄₀.

关键词: amorphous silica, heteropolyacid, heterogeneous catalysis, nano catalyst, rice husk

Abstract: Nano silica was prepared from rice husk with high surface area. X-ray diffraction (XRD) pattern showed that the amorphous form of silica was produced. Chemical composition of the nano silica was estimated by X-ray fluorescence spectroscopy and CHN analysis. The nano silica was used as a support for H₃PW₁₂O₄₀. The nano silica and nano silica supported H₃PW₁₂O₄₀were characterized by inductively coupled plasma, XRD, transmission electron microscopy (TEM), N₂ adsorption-desorption, and Fourier transform infrared spectroscopy. TEM images of nano silica as well as the supported catalyst displayed average size of 6 and 7 nm, respectively. The catalyst showed excellent activity in some important organic reactions including Biginelli, Hantzsch, Mannich, and Claisen-Schmidt reactions with good reusability. Catalytic activity of this nano catalyst is an improvement over the commercially available silica that is used to support H₃PW₁₂O₄₀.

Key words: amorphous silica, heteropolyacid, heterogeneous catalysis, nano catalyst, rice husk

Ezzat RAFIEE, Shabnam SHAHEBRAHIMI. Nano Silica with High Surface Area from Rice Husk as a Support for 12-Tungstophosphoric Acid: An Efficient Nano Catalyst in Some Organic Reactions[J]. 催化学报, 2012, 33(8): 1326-1333.

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