Tetrabutylammonium hexatungstate [TBA]2[W6O19]: Novel and reusable heterogeneous catalyst for rapid solvent-free synthesis of polyhydroquinolines via unsymmetrical Hantzsch reaction

doi:10.1016/S1872-2067(12)60547-6

催化学报 ›› 2013, Vol. 34 ›› Issue (6): 1173-1178.DOI: 10.1016/S1872-2067(12)60547-6

Tetrabutylammonium hexatungstate [TBA]₂[W₆O₁₉]: Novel and reusable heterogeneous catalyst for rapid solvent-free synthesis of polyhydroquinolines via unsymmetrical Hantzsch reaction

Abolghasem DAVOODNIA, Maryam KHASHI, Niloofar TAVAKOLI-HOSEINI

Department of Chemistry, Mashhad Branch, Islamic Azad University, Mashhad, Iran

收稿日期:2012-12-29 修回日期:2013-01-29 出版日期:2013-06-07 发布日期:2013-06-09
通讯作者: Abolghasem DAVOODNIA
基金资助:
This work was supported by Islamic Azad University, Mashhad Branch, Iran.

Tetrabutylammonium hexatungstate [TBA]₂[W₆O₁₉]: Novel and reusable heterogeneous catalyst for rapid solvent-free synthesis of polyhydroquinolines via unsymmetrical Hantzsch reaction

Abolghasem DAVOODNIA, Maryam KHASHI, Niloofar TAVAKOLI-HOSEINI

Department of Chemistry, Mashhad Branch, Islamic Azad University, Mashhad, Iran

Received:2012-12-29 Revised:2013-01-29 Online:2013-06-07 Published:2013-06-09
Supported by:
This work was supported by Islamic Azad University, Mashhad Branch, Iran.

摘要/Abstract

摘要：

A novel, efficient, and environmentally friendly method for the synthesis of polyhydroquinoline derivatives by a one-pot, four-component unsymmetrical Hantzsch condensation of dimedone, aldehydes, ethyl acetoacetate, and ammonium acetate in the presence of a catalytic amount of tetrabutylammonium hexatungstate [TBA]₂[W₆O₁₉] under solvent-free conditions has been developed. The results showed that this heterogeneous catalyst has high catalytic activity and the desired products were obtained in good to high yields. Moreover, the catalyst was found to be reusable and considerable catalytic activity was still achieved after the fifth run.

关键词: Heterogeneous catalysis, Polyhydroquinolines, Tetrabutylammonium hexatungstate

Abstract:

Key words: Heterogeneous catalysis, Polyhydroquinolines, Tetrabutylammonium hexatungstate

Abolghasem DAVOODNIA, Maryam KHASHI, Niloofar TAVAKOLI-HOSEINI. Tetrabutylammonium hexatungstate [TBA]₂[W₆O₁₉]: Novel and reusable heterogeneous catalyst for rapid solvent-free synthesis of polyhydroquinolines via unsymmetrical Hantzsch reaction[J]. 催化学报, 2013, 34(6): 1173-1178.

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Tetrabutylammonium hexatungstate [TBA]₂[W₆O₁₉]: Novel and reusable heterogeneous catalyst for rapid solvent-free synthesis of polyhydroquinolines via unsymmetrical Hantzsch reaction

Tetrabutylammonium hexatungstate [TBA]₂[W₆O₁₉]: Novel and reusable heterogeneous catalyst for rapid solvent-free synthesis of polyhydroquinolines via unsymmetrical Hantzsch reaction

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