MOCVD法制备Pd@ZIF-8催化剂及其催化Suzuki反应性能

doi:10.1016/S1872-2067(14)60292-8

催化学报 ›› 2015, Vol. 36 ›› Issue (4): 588-594.DOI: 10.1016/S1872-2067(14)60292-8

MOCVD法制备Pd@ZIF-8催化剂及其催化Suzuki反应性能

张明明, 高雅, 李闯, 梁长海

大连理工大学化工学院先进材料和催化工程实验室, 辽宁大连 116024

收稿日期:2014-11-10 修回日期:2014-12-29 出版日期:2015-03-23 发布日期:2015-03-23
通讯作者: Changhai Liang
基金资助:
国家自然科学基金(21073023); 中央高校基本科研业务费专项资金(DUT13RC(3)41); 中国博士后科学基金(2013M541220).

Chemical vapor deposition of Pd(C₃H₅)(C₅H₅) for the synthesis of reusable Pd@ZIF-8 catalysts for the Suzuki coupling reaction

Mingming Zhang, Ya Gao, Chuang Li, Changhai Liang

Laboratory of Advanced Materials and Catalytic Engineering, School of Chemical Engineering, Dalian University of Technology, Dalian 116024, Liaoning, China

Received:2014-11-10 Revised:2014-12-29 Online:2015-03-23 Published:2015-03-23
Supported by:
This work was supported by the National Natural Science Foundation of China (21073023), the Fundamental Research Funds for the Central Universities (DUT13RC(3)41), and the Postdoctoral Science Foundation of China (2013M541220).

摘要/Abstract

摘要：

以金属有机骨架化合物ZIF-8为载体, Pd(C₃H₅)(C₅H₅)为金属有机前体, 采用金属有机气相沉积方法在室温下制备了Pd@ZIF-8催化剂. Pd纳米粒子在ZIF-8载体上均匀分布, 粒子尺寸约为1.5-3.5 nm. Pd@ZIF-8在温和条件下对多种卤代芳烃和苯硼酸的偶联反应均具有良好的活性. ZIF-8优异的化学稳定性不仅保证了其在制备过程中结构的完整, 而且赋予了催化剂优异的循环使用性能. 反应后Pd@ZIF-8材料的晶体结构、孔结构以及粒子分布均未发生明显的变化.

关键词: 钯, ZIF-8, 金属有机气相沉积, Suzuki偶联反应

Abstract:

A zeolite-imidazolium-framework-supported Pd-based heterogeneous catalyst (Pd@ZIF-8) was prepared by a metal-organic chemical vapor deposition method under mild conditions using Pd(C₃H₅)(C₅H₅) as the Pd precursor. N₂ adsorption and pore size distribution data showed that ZIF-8 and Pd@ZIF-8 both possessed high surface areas. Transmission electron microscopy images showed that Pd nanoparticles with sizes of about 1.5-3.5 nm were homogeneously dispersed on the ZIF-8 support in Pd@ZIF-8. The Pd@ZIF-8 catalyst showed good activity in Suzuki coupling reactions with several different kinds of aryl halides. It could be reused at least six times without dramatic loss of activity or decomposition of the ZIF-8 structure.

Key words: Palladium, ZIF-8, Metal-organic chemical vapor deposition, Suzuki coupling reaction

张明明, 高雅, 李闯, 梁长海. MOCVD法制备Pd@ZIF-8催化剂及其催化Suzuki反应性能[J]. 催化学报, 2015, 36(4): 588-594.

Mingming Zhang, Ya Gao, Chuang Li, Changhai Liang. Chemical vapor deposition of Pd(C₃H₅)(C₅H₅) for the synthesis of reusable Pd@ZIF-8 catalysts for the Suzuki coupling reaction[J]. Chinese Journal of Catalysis, 2015, 36(4): 588-594.

×
扫码分享

导出引用管理器 EndNote|Ris|BibTeX

链接本文: https://www.cjcatal.com/CN/10.1016/S1872-2067(14)60292-8

https://www.cjcatal.com/CN/Y2015/V36/I4/588

参考文献

[1] Wang Z Q, Cohen S M. Chem Soc Rev, 2009, 38: 1315
[2] Park K S, Ni Z, Cote A P, Choi J Y, Huang R D, Uribe-Romo F J, Chae H K, O'Keeffe M, Yaghi O M. Proc Natl Acad Sci USA, 2006, 103: 10186
[3] Phan A, Doonan C J, Uribe-Romo F J, Knobler C B, O'Keeffe M, Yaghi O M. Acc Chem Res, 2010, 43: 58
[4] Morris R E, Wheatley P S. Angew Chem Int Ed, 2008, 47: 4966
[5] Li K H, Olson D H, Seidel J, Emge T J, Gong H W, Zeng H P, Li J. J Am Chem Soc, 2009, 131: 10368
[6] Jiang H L, Liu B, Akita T, Haruta M, Sakurai H, Xu Q. J Am Chem Soc, 2009, 131：11302
[7] Tran U P N, Le K K A, Phan N T S. ACS Catal, 2011, 1: 120
[8] Yin L, Liebscher J. Chem Rev, 2007, 107: 133
[9] Garrett C E, Prasad K. Adv Synth Catal, 2004, 6: 89
[10] Welch C J, Albaneze-Walker J, Leonard W R, Biba M, Dasilva J, Henderson D, Laing B, Mathre D J, Spencer S, Bu X, Wang T. Org Process Res Dev, 2005, 9: 198
[11] Zhao F, Bhanage B M, Shirai M, Arai M. Chem Eur J, 2000, 6: 843
[12] Hagivara H, Shimizu Y, Hoshi T, Suzuki T, Ando M, Okubo K, Yokoyama C. Tetrahedra Lett, 2001, 42: 4349
[13] Toebes M L, van Dillen J A, de Jong K P. J Mol Catal A, 2001, 173: 75
[14] Mehnert C P, Weaver D W, Ying J Y. J Am Chem Soc, 1998, 120: 12289
[15] Djakocitch L, Koehler K. J Am Chem Soc, 2001, 123: 5990
[16] Djakocitch L, Koehler K. J Mol Catal A, 1999, 142: 275
[17] Biffis A, Zecca M, Basato M. Eur J Inorg Chem, 2011: 1131
[18] Wagner M, Köhler K, Djakovitch L, Weinkauf S, Hagen V, Muhler M. Top Catal, 2003, 13: 319
[19] Köhler K, Wagner M, Djakovitch L. Catal Today, 2001, 66: 105
[20] Li J, Mau A W H, Strauss C R. Chem Commun, 1997: 1275
[21] Zhang M M, Jiang M M, Liang C H. Chin J Catal (张明明, 江曼曼, 梁长海. 催化学报), 2013, 34: 2161
[22] Zhang M M, Guan J C, Zhang B S, Su D S, William C T, Liang C H. Catal Lett, 2012, 142: 313
[23] Chen L, Rangan S, Li J, Jiang H, Li Y. Green Chem, 2014, 16: 3978
[24] Fei H, Cohen S M. Chem Commun, 2014, 50: 4810
[25] Aijaz A, Xu Q. J Phys Chem Lett, 2014, 5: 1400
[26] Dent W T, Long R, Wilkinson A J. J Chem Soc, 1964: 1585
[27] Shaw B L. Proc Chem Soc, 1960, 247
[28] Pan Y Y, Yuan B Z, Li Y W, He D H. Chem Commun, 2010, 46: 2280
[29] El-Shall M S, Abdelsayed V, Khder A E R S, Hassan H M A, El-Kaderi H M, Reich T E. J Mater Chem, 2009, 19: 7625
[30] Jiang H L, Akita T, Ishida T, Haruta M, Xu Q. J Am Chem Soc, 2011, 133: 1304
[31] Ishida T, Kawakita N, Akita T, Haruta M. Gold Bull, 2009, 42: 267
[32] Esken D, Turner S, Lebedev O I, van Tendeloo G, Fischer R A. Chem Mater, 2010, 22: 6393
[33] Opelt S, Türk S, Dietzsch E, Henschel A, Kaskel S, Klemm E. Catal Commun, 2008, 9: 1286
[34] Sabo M, Henschel A, Fröede H, Klemm E, Kaskel S. J Mater Chem, 2007, 17: 3827
[35] Hermes S, Schröder M K, Schmid R, Khodeir L, Muhler M, Tissler A, Fischer R W, Fischer R A. Angew Chem Int Ed, 2005, 44: 6237
[36] Schröder F, Esken D, Cokoja M, van den Berg M W E, Lebedev O I, van Tendeloo G, Walaszek B, Buntkowsky G, Limbach H H, Chaudret B, Fischer R A. J Am Chem Soc, 2008, 130: 6119

MOCVD法制备Pd@ZIF-8催化剂及其催化Suzuki反应性能

Chemical vapor deposition of Pd(C₃H₅)(C₅H₅) for the synthesis of reusable Pd@ZIF-8 catalysts for the Suzuki coupling reaction

PDF

可视化

被引次数

摘要/Abstract

引用本文

使用本文

扫码分享

参考文献

相关文章 15

编辑推荐

Metrics

[1]	夏思源, 李奇远, 张仕楠, 许冬, 林秀, 孙露菡, 许景三, 陈接胜, 李国栋, 李新昊. Pd纳米立方体异质结尺寸依赖的电子界面效应对苯酚加氢反应的促进作用[J]. 催化学报, 2023, 49(6): 180-187.
[2]	李倩, 刘䶮, 李灿. 钯催化不对称烯丙基化/去对称化反应合成无保护基的2-喹啉酮骨架环状氨基酸[J]. 催化学报, 2023, 47(4): 222-228.
[3]	王海凤, 王凡, 李小鹏, 肖琪, 罗维, 许景三. 光照条件下AuPd合金纳米颗粒上原位形成缺电子Pd位点促进高效的光催化Heck反应[J]. 催化学报, 2023, 46(3): 72-83.
[4]	翁雪霏, 杨双莉, 丁丁, 陈明树, 万惠霖. 宽波段原位红外吸收光谱在Pd/SiO₂和Cu/SiO₂催化剂上CO氧化中的应用[J]. 催化学报, 2022, 43(8): 2001-2009.
[5]	谢林峰, 刘轩, 黄凡洋, 梁嘉顺, 刘健云, 王谭源, 杨利明, 曹瑞国, 李箐. 通过金属间化合物PdBi纳米片调控Pd基催化剂电催化CO₂还原为甲酸盐[J]. 催化学报, 2022, 43(7): 1680-1686.
[6]	王凯, 林祥丰, 李倩, 刘䶮, 李灿. 钯(0)/铜(I)协同催化脱羧不对称4+2环加成反应合成四环香豆素[J]. 催化学报, 2022, 43(7): 1812-1817.
[7]	魏呵呵, 黎晓阳, 邓铂瀚, 郎嘉良, 黄雅, 华星宇, 乔奕达, 葛炳辉, 戈钧, 伍晖. Pd单原子/团簇高效催化铃木偶联反应[J]. 催化学报, 2022, 43(4): 1058-1065.
[8]	李振宇, 淮丽媛, 郝盼盼, 赵玺, 王永钊, 张炳森, 谌春林, 张建. 碳纳米管负载钯基催化剂催化氧化2,5-呋喃二甲醇合成2,5-呋喃二甲酸[J]. 催化学报, 2022, 43(3): 793-801.
[9]	张文彪, 石杨豪, 杨洋, 谭静雯, 高庆生. 电催化糠醛加氢反应中钯纳米晶的晶面效应[J]. 催化学报, 2022, 43(12): 3116-3125.
[10]	朱莉, 林翌阳, 刘康, Emiliano Cortés, 李红梅, 胡俊华, Akira Yamaguchi, 刘小良, Masahiro Miyauchi, 傅俊伟, 刘敏. CuPd催化剂调节中间反应能垒提高电催化CO₂生成二碳产物的选择性[J]. 催化学报, 2021, 42(9): 1500-1508.
[11]	王凯, 王彬力, 刘相慧, 樊红军, 刘龑, 李灿. 钯催化烯基苯并噁嗪酮基于内球型机理的线性和不对称烯丙基烷基化反应[J]. 催化学报, 2021, 42(7): 1227-1237.
[12]	李晶, 孙翔, 段永正, 贾冬梅, 李跃金, 王建国. 部分氧化碳化硅提高钯催化氧还原反应性能[J]. 催化学报, 2021, 42(6): 963-970.
[13]	赵东越, 杨岳溪, 高中楠, 尹萌欣, 田野, 张静, 姜政, 于晓波, 李新刚. 贫燃/富燃循环气氛下原位活化Pd负载钙钛矿催化剂促进NO_x还原消除[J]. 催化学报, 2021, 42(5): 795-807.
[14]	朱鹏飞, 尹晓荷, 高新华, 董国辉, 徐景坤, 王传义. ZIF-8衍生的具有可控氧空位的ZnO对光催化去除NO的增强及毒性NO₂形成的抑制[J]. 催化学报, 2021, 42(1): 175-183.
[15]	李顺林, 王丽丽, 吴萌萌, 孙雅飞, 朱小娟, 万颖. 利用实验测量的Pd表面d带电荷密度描述喹啉催化加氢活性[J]. 催化学报, 2020, 41(9): 1337-1347.

MOCVD法制备Pd@ZIF-8催化剂及其催化Suzuki反应性能

Chemical vapor deposition of Pd(C3H5)(C5H5) for the synthesis of reusable Pd@ZIF-8 catalysts for the Suzuki coupling reaction

PDF

可视化

被引次数

摘要/Abstract

引用本文

使用本文

扫码分享

参考文献

相关文章 15

编辑推荐

Metrics

Chemical vapor deposition of Pd(C₃H₅)(C₅H₅) for the synthesis of reusable Pd@ZIF-8 catalysts for the Suzuki coupling reaction