等离子体共振协同S-scheme电荷转移促进W18O49/Cd0.5Zn0.5S高效光催化产氢

doi:10.1016/S1872-2067(20)63783-4

催化学报 ›› 2022, Vol. 43 ›› Issue (2): 234-245.DOI: 10.1016/S1872-2067(20)63783-4

等离子体共振协同S-scheme电荷转移促进W₁₈O₄₉/Cd_0.5Zn_0.5S高效光催化产氢

薛文华^a, 孙红莉^a, 胡晓云^b, 白雪^a, 樊君^a, 刘恩周^a^,^*

^a西北大学化工学院, 西安市特种能源材料重点实验室, 陕西西安 710069
^b西北大学物理学院, 陕西西安 710069

收稿日期:2021-01-29 接受日期:2021-02-22 出版日期:2022-02-18 发布日期:2021-02-22
通讯作者: 刘恩周
基金资助:
国家自然科学基金(21676213);国家自然科学基金(22078261);国家自然科学基金(11974276);中国博士后科学基金(2016M600809);陕西省自然科学基础研究计划(2020JM-422);陕西省自然科学基础研究计划(2018JM5020)

UV-VIS-NIR-induced extraordinary H₂ evolution over W₁₈O₄₉/Cd_0.5Zn_0.5S: Surface plasmon effect coupled with S-scheme charge transfer

Wenhua Xue^a, Hongli Sun^a, Xiaoyun Hu^b, Xue Bai^a, Jun Fan^a, Enzhou Liu^a^,^*

^aXi’ an Key Laboratory of Special Energy Materials, School of Chemical Engineering, Northwest University, Xi’an 710069, Shaanxi, China
^bSchool of Physics, Northwest University, Xi’an 710069, Shaanxi, China

Received:2021-01-29 Accepted:2021-02-22 Online:2022-02-18 Published:2021-02-22
Contact: Enzhou Liu
Supported by:
This work was supported by the National Natural Science Foundation of China(21676213);This work was supported by the National Natural Science Foundation of China(22078261);This work was supported by the National Natural Science Foundation of China(11974276);the China Postdoctoral Science Foundation(2016M600809);Natural Science Basic Research Plan in Shaanxi Province of China(2020JM-422);Natural Science Basic Research Plan in Shaanxi Province of China(2018JM5020)

摘要/Abstract

摘要：

硫化锌镉(Cd_1-_xZn_xS, 0 < x < 1)固溶体作为一种可见光响应光催化剂, 因能带结构可调和光解水产氢活性优异而备受关注. 如何进一步拓展Cd_1-_xZn_xS太阳光响应范围, 提高光生电子与空穴利用效率是当前的研究热点. 本文采用溶剂热法分别制备了Cd_0.5Zn_0.5S纳米棒和W₁₈O₄₉纳米颗粒, 然后借助超声辅助静电自组装策略成功获得具有紫外-可见-近红外光响应的W₁₈O₄₉/Cd_0.5Zn_0.5S异质结. 分析表明, W₁₈O₄₉晶格氧空位周围过量自由电荷的集体振荡, 引起强烈的局域表面等离子体共振(LSPR)吸收现象, 使其对500~800 nm范围的光产生明显吸收, 使体系具有紫外至近红外光响应能力; 而且W₁₈O₄₉作为一种氧化型半导体材料, 可与还原型 Cd_0.5Zn_0.5S半导体之间形成S-scheme异质结, 在内建电场、能带弯曲和静电相互作用下有效促进了光生电子和空穴的分离, 并能保留强的氧化还原能力.
对比实验发现, 常温下以Na₂S/Na₂SO₃为牺牲剂, 全光谱照射下, 20%-W₁₈O₄₉/Cd_0.5Zn_0.5S的产氢速率可达147.7 mmol·g ^-1·h ^-1, 是Cd_0.5Zn_0.5S纳米棒单体的2.1倍; 可见光下, 复合样品的产氢活性约为Cd_0.5Zn_0.5S单体的1.89倍; 近红外光下, Cd_0.5Zn_0.5S单体无产氢活性, 而异质结的产氢速率约为0.2 mmol·g ^-1·h ^-1. 进一步对样品波长依赖性研究发现, 当365、400、450 nm的入射光仅能引起W₁₈O₄₉和Cd_0.5Zn_0.5S的带间激发时, 它们的复合样品比Cd_0.5Zn_0.5S表现出更优异的产氢活性; 当λ = 550、600、650 nm以及>800 nm的入射光仅能引起W₁₈O₄₉的LSPR效应时, Cd_0.5Zn_0.5S单体无活性, 而W₁₈O₄₉/Cd_0.5Zn_0.5S仍具有较高的催化性能、但随着波长的增大产氢速率逐渐降低, 与复合样品瞬态光电流强度的变化趋势吻合良好. 以上结果表明, W₁₈O₄₉与Cd_0.5Zn_0.5S二者形成的S-scheme界面异质结有效抑制了光生载流子的表面复合, 且当入射光不足以引起带间激发时, W₁₈O₄₉的LSPR效应产生的“热电子”可有效注入到Cd_0.5Zn_0.5S, 从而引起表面催化反应.
进一步研究发现, 当将反应温度从25提高到60 °C时, 20%-W₁₈O₄₉/Cd_0.5Zn_0.5S在全光谱下的产氢速率可提高到306.1 mmol·g ^-1·h ^-1, 表明温度对光催化产氢过程具有不可忽视的影响, 可通过增强表面反应速率显著提高产氢活性. 总之, 本文通过一种简便方法获得了具有紫外-可见-近红外响应的S型W₁₈O₄₉/Cd_0.5Zn_0.5S异质结光催化剂, 详细对比了不同波段下样品的光电特性及催化活性, 最终在S-scheme电荷转移机制和LSPR“热电子”注入过程的协同作用下, 复合样品活性比Cd_0.5Zn_0.5S单体有了明显提高.

关键词: S型异质结, 氢气, 等离子体材料, W₁₈O₄₉, 硫化锌镉

Abstract:

In this work, a novel plasmon-assisted UV-vis-NIR-driven W₁₈O₄₉/Cd_0.5Zn_0.5S heterostructure photocatalyst was obtained by a facile ultrasonic-assisted electrostatic self-assembly strategy. The hybrid exhibits extraordinary H₂ evolution activity of 147.7 mmol∙g ^-1∙h ^-1 at room temperature due to the efficient charge separation and expanded light absorption. Our investigation shows that the unique Step-scheme (S-scheme) charge transfer and the ‘hot electron’ injection are both responsible for the extraordinary H₂ evolution process, depending on the wavelength of the incident light. Moreover, by accelerating the surface reaction kinetics, the activity can be further elevated to 306.1 mmol∙g ^-1∙h ^-1, accompanied by a high apparent quantum yield of 45.3% at 365 ± 7.5 nm. This work provides us a potential strategy for the highly efficient conversion of the solar energy by elaborately combining a nonstoichiometric ratio plasmonic material with an appropriate active photocatalyst.

Key words: S-scheme, Hydrogen, Plasmonic material, W₁₈O₄₉, Cd_0.5Zn_0.5S

薛文华, 孙红莉, 胡晓云, 白雪, 樊君, 刘恩周. 等离子体共振协同S-scheme电荷转移促进W₁₈O₄₉/Cd_0.5Zn_0.5S高效光催化产氢[J]. 催化学报, 2022, 43(2): 234-245.

Wenhua Xue, Hongli Sun, Xiaoyun Hu, Xue Bai, Jun Fan, Enzhou Liu. UV-VIS-NIR-induced extraordinary H₂ evolution over W₁₈O₄₉/Cd_0.5Zn_0.5S: Surface plasmon effect coupled with S-scheme charge transfer[J]. Chinese Journal of Catalysis, 2022, 43(2): 234-245.

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链接本文: https://www.cjcatal.com/CN/10.1016/S1872-2067(20)63783-4

https://www.cjcatal.com/CN/Y2022/V43/I2/234

图/表 13

Scheme 1. Schematic diagram of light intensity test.

Scheme 2. Schematic diagram of light intensity test.

Fig. 1. (a) Zeta potential test of Cd0.5Zn0.5S and W18O49; (b) XRD patterns of the samples.

Fig. 2. (a) HAADF-STEM image of 20%-W18O49/Cd0.5Zn0.5S; (b,c) bright field image of 20%-W18O49/Cd0.5Zn0.5S; (d?i) EDS elemental mapping profiles.

Fig. 3. (a) UV-vis-NIR absorption spectra; (b) High resolution XPS spectra of W; (c) ESR spectrum of W18O49 before calcination; (d) Raman spectra (excited at 514 nm).

Fig. 4. (a) Calculated band gaps of Cd0.5Zn0.5S according to Kubelka-Munk plot conversion; Mott-Schottky (M-S) curves (b,c) and UPS spectra (d) of W18O49 and Cd0.5Zn0.5S.

Fig. 5. H2 evolution of the samples under UV-VIS-NIR (a) and visible light (b) at 25 °C; (c) H2 evolution of the samples under NIR; (d) wavelength-dependent H2 evolution of 20%-W18O49/Cd0.5Zn0.5S at 25 °C.

Fig. 6. (a) Comparison of H2 evolution performance of the samples over various conditions; (b) Wavelength-dependent H2 evolution of 20%-W18O49/Cd0.5Zn0.5S at 60 °C.

Fig. 7. Wavelength-dependent transient photocurrent density of 20%-W18O49/Cd0.5Zn0.5S (a) and W18O49 (b).

Fig. 8. Transient I-t curves (a), open-circuit voltage (b), EIS spectra (the inset is the Nyquist arc) (c), and linear sweep voltammetry (d) under UV light.

Fig. 9. Steady-state (a), and transient photoluminescence (excited at 380 nm) (b) of Cd0.5Zn0.5S and 20%-W18O49/Cd0.5Zn0.5S.

Fig. 10. Schematic diagram of the charge separation.

Fig. 11. DMPO-·O2- signals of 20%-W18O49/Cd0.5Zn0.5S (a) and Cd0.5Zn0.5S (b).

参考文献

[1]	Q. Wang, K. Domen, Chem. Rev., 2020,120, 919-985.
[2]	R. Shen, J. Xie, Q. Xiang, X. Chen, J. Jiang, X. Li, Chin. J. Catal., 2019,40, 240-288.
[3]	X. Li, J. Yu, M. Jaroniec, X. Chen, Chem. Rev., 2019,119, 3962-4279.
[4]	R. Shen, Y. Ding, S. Li, P. Zhang, Q. Xiang, Y. Hau Ng, Xin Li, Chin. J. Catal., 2021,42, 25-36.
[5]	R. Shen, D. Ren, Y. Ding, Y. Guan, Y. Hau Ng, P. Zhang, X. Li, Sci. China Mater., 2020,63, 2153-2188.
[6]	Z. Liang, R. Shen, Y.-H. Ng, P. Zhang, Q. Xiang, Xin Li, J. Mater. Sci. Technol., 2020, 56, 89-121.
[7]	P. Kuang, M. Sayed, J. Fan, B. Cheng, J. Yu, Adv. Energy Mater., 2020,10, 1903802.
[8]	Y. Lu, Y. Li, Y. Wang, J. Zhang, Appl. Catal. B, 2020,272, 118979.
[9]	N. Li, H. Fan, Y. Dai, J. Kong, L. Ge, Appl. Surf. Sci., 2020,508, 145200.
[10]	X. Xu, F. Luo, W. Tang, J. Hu, H. Zeng, Y. Zhou, Adv. Funct. Mater., 2018,28, 1804055.
[11]	Z. Zhang, J. Huang, Y. Fang, M. Zhang, K. Liu, B. Dong, Adv. Mater., 2017,29, 1606688.
[12]	H. Cheng, T. Kamegawa, K, Mori, H. Yamashita, Angew. Chem. Int. Ed., 2014,53, 2910-2914.
[13]	S. Xie, H. Zhang, G. Liu, X. Wu, J. Lin, Q. Zhang, Y. Wang, Chin. J. Catal., 2020,41, 1125-1131.
[14]	J. Peng, J. Shen, X. Yu, H. Tang, Zulfiqar, Q. Liu, Chin. J. Catal., 2021,42, 87-96.
[15]	C. Cao, Z. Zhao, Y. Zhang, S. Peng, J. Phys. D, 2020,53, 265103.
[16]	X. Xie, R. Wang, E. Liu, J. Fan, B. Chen, X. Hu, Int. J. Hydrogen Energy, 2019,44, 32042-32053.
[17]	N. Lu, Z. Zhang, Y. Wang, B. Liu, L. Guo, L. Wang, J. Huang, K. Liu, B. Dong, Appl. Catal. B, 2018,233, 19-25.
[18]	C. Feng, L. Tang, Y. Deng, J. Wang, W. Tang, Y. Liu, Z. Chen, J. Yu, J. Wang, Q. Liang, Chem. Eng. J., 2020,389, 124474.
[19]	Y. Liu, Z. Zhang, Y. Fang, B. Liu, J. Huang, F. Miao, Y. Bao, B. Dong, Appl. Catal. B, 2019,252, 164-173.
[20]	J. Wang, G. Wang, B. Cheng, J. Yu, J. Fan, Chin. J. Catal., 2021,42, 56-68.
[21]	N. Zhang, A. Jalil, D. Wu, S. Chen, Y. Liu, C. Gao, W. Ye, Z. Qi, H. Ju, C. Wang, X. Wu, L. Song, J. Zhu, Y. Xiong, J. Am. Chem. Soc., 2018,140, 9434-9443.
[22]	S. Linic, U. Aslam, C. Boerigter, M. Morabito, Nat. Mater., 2015,14, 567-576.
[23]	Y. Xia, B. Cheng, J. Fan, J. Yu, G. Liu, Sci. China Mater., 2020,63, 552-565.
[24]	Y. Chen, S. Zhao, X. Wang, Q. Peng, R. Lin, Y. Wang, R. Shen, X. Cao, L. Zhang, G. Zhou, J. Li, A. Xia, Y. Li, J. Am. Chem. Soc., 2016,138, 4286-4289.
[25]	R. Gao, B. Cheng, J. Fan, J. Yu, W. Ho, Chin. J. Catal., 2021,42, 15-24.
[26]	Z. Wei, M. Xu, J. Liu, W. Guo, Z. Jiang, W. Shangguan, Chin. J. Catal., 2020,41, 103-113.
[27]	J. Luo, Z. Lin, Y. Zhao, S. Jiang, S. Song, Chin. J. Catal., 2020,41, 122-130.
[28]	T. Di, L. Zhang, B. Cheng, J. Yu, J. Fan, J. Mater. Sci. Technol., 2020,56, 170-178.
[29]	X. Xiang, B. Zhu, B. Cheng, J. Yu, H. Lv, Small, 2020,16, 2001024.
[30]	M. Xiong, J. Yan, B. Chai, G. Fan, G. Song, J. Mater. Sci. Technol., 2020,56, 179-188.
[31]	Z. Wang, C. Li, K. Domen, Chem. Soc. Rev., 2019,48, 2109-2125.
[32]	M. Qureshi, K. Takanabe, Chem. Mater., 2016,29, 158-167.
[33]	T. Takata, J. Jiang, Y. Sakata, M. Nakabayashi, N. Shibata, V. Nandal, K. Seki, T. Hisatomi, K. Domen, Nature, 2020,581, 411-414.
[34]	B. Weng, M. Qi, C. Han, Z. Tang, Y. Xu, ACS Catal., 2019, 9, 4642-4687.
[35]	C. Guo, S. Yin, M. Yan, M. Kobayashi, M. Kakihana, T. Sato, Inorg. Chem., 2012,51, 4763-4771.
[36]	S.-H. Lee, H. M. Cheong, C. E. Tracy, A. Mascarenhas, D. K. Benson, S. K. Deb, Electrochim. Acta, 1999,44, 3111-3115.
[37]	M. Yan, G. Li, C. Guo, W. Guo, D. Ding, S. Zhang, S. Liu, Nanoscale, 2016,8, 17828-17835.
[38]	K. Zhang, J. Liu, L. Wang, B. Jin, X. Yang, S. Zhang, J. H. Park, J. Am. Chem. Soc., 2020,142, 8641-8648.
[39]	W. Xue, W. Chang, X. Hu, J. Fan, E. Liu, Chin. J. Catal., 2021,42, 152-163.
[40]	N. Li, Y. Ding, J. Wu, Z. Zhao, X. Li, Y. Zheng, M. Huang, X. Tao, ACS Appl. Mater. Interfaces, 2019,11, 22297-22306.
[41]	F. Xu, K. Meng, B. Cheng, S. Wang, J. Xu, J. Yu, Nat. Commun., 2020,11, 4613.
[42]	W. Chang, W. Xue, E. Liu, J. Fan, B. Zhao, Chem. Eng. J., 2019,362, 392-401.
[43]	R. Shen, L. Zhang, X. Chen, M. Jaroniec, N. Li, X. Li, Appl. Catal. B, 2020,266, 118619.
[44]	W. Xue, W. Chang, X. Hu, J. Fan, X. Bai, E. Liu, J. Colloid Interf. Sci., 2020,576, 203-216.
[45]	Q. Xu, L. Zhang, B. Cheng, J. Fan, J. Yu, Chem, 2020,6, 1543-1559.
[46]	P. Xia, S. Cao, B. Zhu, M. Liu, M. Shi, J. Yu, Y. Zhang, Angew. Chem. Int. Ed., 2020,59, 5218-5225.
[47]	D. Qin, Y. Xia, Q. Li, C. Yang, Y. Qin, K. Lv, J. Mater. Sci. Technol., 2020,56, 206-215.
[48]	Z. Wang, Y. Chen, L. Zhang, B. Cheng, J. Yu, J. Fan, J. Mater. Sci. Technol., 2020,56, 143-150.
[49]	H. Ge, F. Xu, B. Cheng, J. Yu, W. Ho, ChemCatChem, 2019,11, 6301-6309.
[50]	F. He, B. Zhu, B. Cheng, J. Yu, W. Ho, W. Macyk, Appl. Catal. B, 2020,272, 119006.
[51]	F. Mei, Z. Li, K. Dai, J. Zhang, C. Liang, Chin. J. Catal., 2020,41, 41-49.
[52]	H.-B. Huang, Z.-B. Fang, K. Yu, J. Lü, R. Cao, J. Mater. Chem. A, 2020,8, 3882-3891.
[53]	Y. Zhao, C. Shao, Z. Lin, S. Jiang, S. Song, Small, 2020,16, 2000944.
[54]	X. Yue, S. Yi, R. Wang, Z. Zhang, S. Qiu, Appl. Catal. B, 2018,224, 17-26.
[55]	Y.-C. Pu, W.-T. Chen, M.-J. Fang, Y.-L. Chen, K.-A. Tsai, W.-H. Lin, Y.-J. Hsu, J. Mater. Chem. A, 2018,6, 17503-17513.
[56]	Y.-C. Chen, Y.-S. Huang, H. Huang, P.-J. Su, T.-P. Perng, L.-J. Chen, Nano Energy, 2020,67, 104225.
[57]	Y. Li, M. Wen, Y. Wang, G. Tian, C. Wang, J. Zhao, Angew. Chem. Int. Ed., 2021,60, 910-916.
[58]	M. Zhou, J. Li, Z. Ye, C. Ma, H. Wang, P. Huo, W. Shi, Y. Yan, ACS Appl. Mater. Interfaces, 2015,7, 28231-28243.
[59]	D. Ren, Z. Liang, Y. Ng, P. Zhang, Q. Xiang, X. Li, Chem. Eng. J., 2020,390, 124496.
[60]	S. Du, X. Lin, C. Li, G. Li, B. Zheng, Y. Liu, H. Xu, P. Fang,C, Chem. Eng. J., 2020,389, 124431.
[61]	W. Yu, S. Zhang, J. Chen, P. Xia, M. Richter, L. Chen, W. Xu, J. Jin, S. Chen, T. Pen, J. Mater. Chem. A, 2018,6, 15668-15674.
[62]	J. Fu, Q. Xu, J. Low, C. Jiang, J. Yu, Appl. Catal. B, 2019,243, 556-565.
[63]	H. Huang, H. Yuan, K. Janssen, G. Solís-Fernández, Y. Wang, C. Tan, D. Jonckheere, E. Debroye, J. Long, J. Hendrix, J. Hofkens, J. A. Steele, M. B. J. Roeffaers, ACS Energy Lett., 2018,3, 755-759.
[64]	F. He, A. Meng, B. Cheng, W. Ho, J. Yu, Chin. J. Catal., 2020,41, 9-20.
[65]	L. Liu, T. Hu, K. Dai, J. Zhang, C. Liang., Chin. J. Catal., 2021,42, 46-55.
[66]	D. Ren, W. Zhang, Y. Ding, R. Shen, Z. Jiang, X. Lu, X. Li, Solar RRL, 2020,4, 1900423.

等离子体共振协同S-scheme电荷转移促进W₁₈O₄₉/Cd_0.5Zn_0.5S高效光催化产氢

UV-VIS-NIR-induced extraordinary H₂ evolution over W₁₈O₄₉/Cd_0.5Zn_0.5S: Surface plasmon effect coupled with S-scheme charge transfer

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