催化学报 ›› 2021, Vol. 42 ›› Issue (10): 1700-1711.DOI: 10.1016/S1872-2067(21)63831-7
Igor B. Krylova,b, Elena R. Lopat’evaa,b, Irina R. Subbotinaa, Gennady I. Nikishina, Bing Yuc, Alexander O. Terent’eva,b()
收稿日期:
2020-12-19
接受日期:
2021-04-14
出版日期:
2021-06-20
发布日期:
2021-06-20
通讯作者:
Alexander O. Terent’ev
作者简介:
*电话: +7-499-137-29-44; 传真: +7-499-135-53-28; 电子信箱:alterex@yandex.ruIgor B. Krylova,b, Elena R. Lopat’evaa,b, Irina R. Subbotinaa, Gennady I. Nikishina, Bing Yuc, Alexander O. Terent’eva,b()
Received:
2020-12-19
Accepted:
2021-04-14
Online:
2021-06-20
Published:
2021-06-20
Contact:
Alexander O. Terent’ev
摘要:
均相催化和多相催化通常被认为是独立甚至相互对立的学科. 本文提出了一种新型的用于分子氧选择性氧化烷基苯的杂多酸/均相混合催化体系. 该催化体系由N-羟基邻苯二甲酰亚胺(NHPI, 用于自由基链式反应的均相有机催化剂)和纳米TiO2(多相紫外光活性光氧化催化剂)两种组分组成. NHPI与TiO2的协同作用使光氧化活性从紫外光转移到可见光, 并产生邻苯二甲酰亚胺-N-氧基(PINO)自由基. NHPI/PINO催化的自由基链式反应能够在没有额外光输入的情况下进行, 从而从根本上提高能源效率. 通过控制NHPI/TiO2比率优化产物选择性, 进而使烷基芳烃优先形成过氧化氢或酮.
Igor B. Krylov, Elena R. Lopat’eva, Irina R. Subbotina, Gennady I. Nikishin, Bing Yu, Alexander O. Terent’ev. 多相/均相TiO2/N-羟酰亚胺混合体系中可见光诱导分子氧可控光催化氧化苄基反应[J]. 催化学报, 2021, 42(10): 1700-1711.
Igor B. Krylov, Elena R. Lopat’eva, Irina R. Subbotina, Gennady I. Nikishin, Bing Yu, Alexander O. Terent’ev. Mixed hetero-/homogeneous TiO2/N-hydroxyimide photocatalysis in visible-light-induced controllable benzylic oxidation by molecular oxygen[J]. Chinese Journal of Catalysis, 2021, 42(10): 1700-1711.
Consumed power (W) | Irradiance * (W/m2) | Relative irradiated power |
---|---|---|
10 | 1165 | 1 |
5 | 700 | 0.6 |
2.5 | 407 | 0.35 |
1 | 203 | 0.17 |
Table 1 Consumed and relative irradiated power values for Blue LEDs used in the present study.
Consumed power (W) | Irradiance * (W/m2) | Relative irradiated power |
---|---|---|
10 | 1165 | 1 |
5 | 700 | 0.6 |
2.5 | 407 | 0.35 |
1 | 203 | 0.17 |
Run | Deviation from general conditions a | X (%) | S2a (%) | S3a (%) | S4a (%) |
---|---|---|---|---|---|
1 | None | 40 | 39 | 5 | 48 |
(43) | (40) | (44) | |||
2 | TiO2 without NHPI | — | — | — | — |
3 | NHPI without TiO2 | <5 | 80 | — | — |
4 | TiO2 was filtered before irradiation | <5 | 76 | — | — |
5 | No irradiation (in dark) | <5 | 50 | — | — |
6 | Irradiation by 10 W violet LED (λmax = 405 nm) | 44 | 22 | 6 | 65 |
7 | Irradiation by 10 W UV LED (λmax = 373 nm) | 27 | 51 | 4 | 28 |
12 | 5 W blue LED | 39 | 44 | 3 | 45 |
(41) | (44) | (49) | |||
13 | 1 W blue LED | 31 | 55 | 3 | 32 |
14 | NHSI instead of NHPI | 21 | 8 | 9 | 28 |
15 | Cl4-NHPI instead of NHPI | 28 | 40 | 8 | 52 |
16 | NHNPI instead of NHPI | 26 | 3 | 11 | 53 |
17 | TiO2 anatase nanopowder | 25 | 62 | 4 | 21 |
18 | TiO2 P25 Aeroxide | 26 | 59 | 5 | 24 |
19 | C2H4Cl2 as solvent | 19 | 14 | 5 | 70 |
20 | PhCl as solvent | 13 | 6 | 8 | 85 |
(18) | (13) | (60) | |||
21 | MeNO2 as solvent | 57 | 12 | 9 | 75 |
22 | AcOH as solvent | (33) | (17) | (48) | |
23 | 40 °C | 55 | 15 | 4 | 66 |
(56) | (18) | (60) | |||
24 | 60 °C | 66 | 2 | 2 | 85 |
25 | Reaction under air | 32 | 29 | 4 | 59 |
26 | Reaction under argon | <5 | — | — | 87 |
27 | Reaction time 24 h | 65 | 4 | 2 | 85 |
Table 2 Influence of photocatalytic system composition, irradiation wavelength and power, temperature, and solvent nature on conversion of ethylbenzene 1a and selectivity of 2a-4a formation.
Run | Deviation from general conditions a | X (%) | S2a (%) | S3a (%) | S4a (%) |
---|---|---|---|---|---|
1 | None | 40 | 39 | 5 | 48 |
(43) | (40) | (44) | |||
2 | TiO2 without NHPI | — | — | — | — |
3 | NHPI without TiO2 | <5 | 80 | — | — |
4 | TiO2 was filtered before irradiation | <5 | 76 | — | — |
5 | No irradiation (in dark) | <5 | 50 | — | — |
6 | Irradiation by 10 W violet LED (λmax = 405 nm) | 44 | 22 | 6 | 65 |
7 | Irradiation by 10 W UV LED (λmax = 373 nm) | 27 | 51 | 4 | 28 |
12 | 5 W blue LED | 39 | 44 | 3 | 45 |
(41) | (44) | (49) | |||
13 | 1 W blue LED | 31 | 55 | 3 | 32 |
14 | NHSI instead of NHPI | 21 | 8 | 9 | 28 |
15 | Cl4-NHPI instead of NHPI | 28 | 40 | 8 | 52 |
16 | NHNPI instead of NHPI | 26 | 3 | 11 | 53 |
17 | TiO2 anatase nanopowder | 25 | 62 | 4 | 21 |
18 | TiO2 P25 Aeroxide | 26 | 59 | 5 | 24 |
19 | C2H4Cl2 as solvent | 19 | 14 | 5 | 70 |
20 | PhCl as solvent | 13 | 6 | 8 | 85 |
(18) | (13) | (60) | |||
21 | MeNO2 as solvent | 57 | 12 | 9 | 75 |
22 | AcOH as solvent | (33) | (17) | (48) | |
23 | 40 °C | 55 | 15 | 4 | 66 |
(56) | (18) | (60) | |||
24 | 60 °C | 66 | 2 | 2 | 85 |
25 | Reaction under air | 32 | 29 | 4 | 59 |
26 | Reaction under argon | <5 | — | — | 87 |
27 | Reaction time 24 h | 65 | 4 | 2 | 85 |
Run | NHPI (mol%) | TiO2 (mg) | X (%) | S2a (%) | S3a (%) | S4a (%) |
---|---|---|---|---|---|---|
1 | 10 | 10 | 40 | 39 | 5 | 48 |
2 | 10 | 5 | 36 | 54 | 5 | 35 |
3 | 10 | 2.5 | 31 | 67 | 3 | 23 |
4 b | 10 | 2.5 | 13 | 90 | — | 2 |
5 c | 10 | 2.5 | 18 | 79 | — | 16 |
6 d | 10 | 2.5 | 37 | 55 | 5 | 37 |
7 e | 40 | 2.5 | 32 | 76 | — | 15 |
8 e | 10 | 10 | 30 | 34 | 6 | 49 |
(31) | (39) | (53) | ||||
9 | 5 | 10 | 28 | 28 | 6 | 62 |
10 | 2.5 | 10 | 24 | 14 | 6 | 67 |
11 | 10 | 20 | 43 | 23 | 4 | 67 |
12 | 10 | 40 | 44 | 19 | 5 | 71 |
Table 3 Optimization of NHPI : TiO2 : ethylbenzene ratio and reaction time for the synthesis of hydroperoxide 2a by oxidation of ethylbenzene 1a with molecular oxygen a.
Run | NHPI (mol%) | TiO2 (mg) | X (%) | S2a (%) | S3a (%) | S4a (%) |
---|---|---|---|---|---|---|
1 | 10 | 10 | 40 | 39 | 5 | 48 |
2 | 10 | 5 | 36 | 54 | 5 | 35 |
3 | 10 | 2.5 | 31 | 67 | 3 | 23 |
4 b | 10 | 2.5 | 13 | 90 | — | 2 |
5 c | 10 | 2.5 | 18 | 79 | — | 16 |
6 d | 10 | 2.5 | 37 | 55 | 5 | 37 |
7 e | 40 | 2.5 | 32 | 76 | — | 15 |
8 e | 10 | 10 | 30 | 34 | 6 | 49 |
(31) | (39) | (53) | ||||
9 | 5 | 10 | 28 | 28 | 6 | 62 |
10 | 2.5 | 10 | 24 | 14 | 6 | 67 |
11 | 10 | 20 | 43 | 23 | 4 | 67 |
12 | 10 | 40 | 44 | 19 | 5 | 71 |
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